Nickel-Containing Perovskites, PrNi0.4Fe0.6O3–δ and PrNi0.4Co0.6O3–δ, as Potential Electrodes for Protonic Ceramic Electrochemical Cells
Protonic ceramic fuel cells (PCFCs) offer a convenient means of converting chemical energy into electricity with high performance and efficiency at low- and intermediate-temperature ranges. However, in order to ensure good life-time stability of PCFCs, it is necessary to ensure rational chemical des...
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| Veröffentlicht in: | Materials 2022-03, Vol.15 (6), p.2166 |
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| creator | Tarutin, Artem Kasyanova, Anna Vdovin, Gennady Lyagaeva, Julia Medvedev, Dmitry |
| description | Protonic ceramic fuel cells (PCFCs) offer a convenient means of converting chemical energy into electricity with high performance and efficiency at low- and intermediate-temperature ranges. However, in order to ensure good life-time stability of PCFCs, it is necessary to ensure rational chemical design in functional materials. Within the present work, we propose new Ni-based perovskite phases of PrNi0.4M0.6O3–δ (where M = Co, Fe) for potential utilization in protonic ceramic electrochemical cells. Along with their successful synthesis, functional properties of the PrNi0.4M0.6O3–δ materials, such as chemical compatibility with a number of oxygen-ionic and proton-conducting electrolytes, thermal expansion behavior, electrical conductivity, and electrochemical behavior, were comprehensively studied. According to the obtained data, the Co-containing nickelate exhibits excellent conductivity and polarization behavior; on the other hand, it demonstrates a high reactivity with all studied electrolytes along with elevated thermal expansion coefficients. Conversely, while the iron-based nickelate had superior chemical and thermal compatibility, its transport characteristics were 2–5 times worse. Although, PrNi0.4Co0.6O3–δ and PrNi0.4Fe0.6O3–δ represent some disadvantages, this work provides a promising pathway for further improvement of Ni-based perovskite electrodes. |
| doi_str_mv | 10.3390/ma15062166 |
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However, in order to ensure good life-time stability of PCFCs, it is necessary to ensure rational chemical design in functional materials. Within the present work, we propose new Ni-based perovskite phases of PrNi0.4M0.6O3–δ (where M = Co, Fe) for potential utilization in protonic ceramic electrochemical cells. Along with their successful synthesis, functional properties of the PrNi0.4M0.6O3–δ materials, such as chemical compatibility with a number of oxygen-ionic and proton-conducting electrolytes, thermal expansion behavior, electrical conductivity, and electrochemical behavior, were comprehensively studied. According to the obtained data, the Co-containing nickelate exhibits excellent conductivity and polarization behavior; on the other hand, it demonstrates a high reactivity with all studied electrolytes along with elevated thermal expansion coefficients. Conversely, while the iron-based nickelate had superior chemical and thermal compatibility, its transport characteristics were 2–5 times worse. Although, PrNi0.4Co0.6O3–δ and PrNi0.4Fe0.6O3–δ represent some disadvantages, this work provides a promising pathway for further improvement of Ni-based perovskite electrodes.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma15062166</identifier><identifier>PMID: 35329618</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Ceramics ; Chemical compatibility ; Chemical energy ; Climate change ; Composite materials ; Cooling ; Electrical resistivity ; Electrochemical analysis ; Electrochemical cells ; Electrode polarization ; Electrodes ; Electrolytes ; Electrolytic cells ; Fuel cells ; Functional materials ; Hydrogen ; Iron ; Nickel ; Nitrates ; Perovskites ; Software ; Thermal expansion ; Transport properties</subject><ispartof>Materials, 2022-03, Vol.15 (6), p.2166</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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Conversely, while the iron-based nickelate had superior chemical and thermal compatibility, its transport characteristics were 2–5 times worse. 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Conversely, while the iron-based nickelate had superior chemical and thermal compatibility, its transport characteristics were 2–5 times worse. Although, PrNi0.4Co0.6O3–δ and PrNi0.4Fe0.6O3–δ represent some disadvantages, this work provides a promising pathway for further improvement of Ni-based perovskite electrodes.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>35329618</pmid><doi>10.3390/ma15062166</doi><orcidid>https://orcid.org/0000-0003-1660-6712</orcidid><orcidid>https://orcid.org/0000-0001-5636-6499</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Ceramics Chemical compatibility Chemical energy Climate change Composite materials Cooling Electrical resistivity Electrochemical analysis Electrochemical cells Electrode polarization Electrodes Electrolytes Electrolytic cells Fuel cells Functional materials Hydrogen Iron Nickel Nitrates Perovskites Software Thermal expansion Transport properties |
| title | Nickel-Containing Perovskites, PrNi0.4Fe0.6O3–δ and PrNi0.4Co0.6O3–δ, as Potential Electrodes for Protonic Ceramic Electrochemical Cells |
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