Ultrastable Covalent Triazine Organic Framework Based on Anthracene Moiety as Platform for High-Performance Carbon Dioxide Adsorption and Supercapacitors
Conductive and porous nitrogen-rich materials have great potential as supercapacitor electrode materials. The exceptional efficiency of such compounds, however, is dependent on their larger surface area and the level of nitrogen doping. To address these issues, we synthesized a porous covalent triaz...
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| Veröffentlicht in: | International journal of molecular sciences 2022-03, Vol.23 (6), p.3174 |
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| creator | Mohamed, Mohamed Gamal Sharma, Santosh U Liu, Ni-Yun Mansoure, Tharwat Hassan Samy, Maha Mohamed Chaganti, Swetha V Chang, Yu-Lung Lee, Jyh-Tsung Kuo, Shiao-Wei |
| description | Conductive and porous nitrogen-rich materials have great potential as supercapacitor electrode materials. The exceptional efficiency of such compounds, however, is dependent on their larger surface area and the level of nitrogen doping. To address these issues, we synthesized a porous covalent triazine framework (An-CTFs) based on 9,10-dicyanoanthracene (An-CN) units through an ionothermal reaction in the presence of different molar ratios of molten zinc chloride (ZnCl
) at 400 and 500 °C, yielding An-CTF-10-400, An-CTF-20-400, An-CTF-10-500, and An-CTF-20-500 microporous materials. According to N
adsorption-desorption analyses (BET), these An-CTFs produced exceptionally high specific surface areas ranging from 406-751 m
·g
. Furthermore, An-CTF-10-500 had a capacitance of 589 F·g
, remarkable cycle stability up to 5000 cycles, up to 95% capacity retention, and strong CO
adsorption capacity up to 5.65 mmol·g
at 273 K. As a result, our An-CTFs are a good alternative for both electrochemical energy storage and CO
uptake. |
| doi_str_mv | 10.3390/ijms23063174 |
| format | Article |
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) at 400 and 500 °C, yielding An-CTF-10-400, An-CTF-20-400, An-CTF-10-500, and An-CTF-20-500 microporous materials. According to N
adsorption-desorption analyses (BET), these An-CTFs produced exceptionally high specific surface areas ranging from 406-751 m
·g
. Furthermore, An-CTF-10-500 had a capacitance of 589 F·g
, remarkable cycle stability up to 5000 cycles, up to 95% capacity retention, and strong CO
adsorption capacity up to 5.65 mmol·g
at 273 K. As a result, our An-CTFs are a good alternative for both electrochemical energy storage and CO
uptake.</description><identifier>ISSN: 1422-0067</identifier><identifier>ISSN: 1661-6596</identifier><identifier>EISSN: 1422-0067</identifier><identifier>DOI: 10.3390/ijms23063174</identifier><identifier>PMID: 35328595</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Adsorption ; Anthracene ; Anthracenes ; Capacitance ; Carbon dioxide ; Carbon Dioxide - chemistry ; Charged particles ; Decomposition ; Electrode materials ; Electrodes ; Electrolytes ; Energy storage ; Graphene ; Investigations ; Metal-Organic Frameworks ; Microscopy ; Morphology ; Nitrogen ; Nitrogen - chemistry ; Porous materials ; Spectrum analysis ; Supercapacitors ; Surface chemistry ; Triazine ; Triazines - chemistry ; Zinc chloride</subject><ispartof>International journal of molecular sciences, 2022-03, Vol.23 (6), p.3174</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2022 by the authors. 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-9ca13240cc8816d1ed89433e2ab84ef27130074beec743f70741cbd901fab7e33</citedby><cites>FETCH-LOGICAL-c342t-9ca13240cc8816d1ed89433e2ab84ef27130074beec743f70741cbd901fab7e33</cites><orcidid>0000-0002-5848-0196 ; 0000-0003-0301-8372 ; 0000-0002-4306-7171</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8951433/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8951433/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35328595$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mohamed, Mohamed Gamal</creatorcontrib><creatorcontrib>Sharma, Santosh U</creatorcontrib><creatorcontrib>Liu, Ni-Yun</creatorcontrib><creatorcontrib>Mansoure, Tharwat Hassan</creatorcontrib><creatorcontrib>Samy, Maha Mohamed</creatorcontrib><creatorcontrib>Chaganti, Swetha V</creatorcontrib><creatorcontrib>Chang, Yu-Lung</creatorcontrib><creatorcontrib>Lee, Jyh-Tsung</creatorcontrib><creatorcontrib>Kuo, Shiao-Wei</creatorcontrib><title>Ultrastable Covalent Triazine Organic Framework Based on Anthracene Moiety as Platform for High-Performance Carbon Dioxide Adsorption and Supercapacitors</title><title>International journal of molecular sciences</title><addtitle>Int J Mol Sci</addtitle><description>Conductive and porous nitrogen-rich materials have great potential as supercapacitor electrode materials. The exceptional efficiency of such compounds, however, is dependent on their larger surface area and the level of nitrogen doping. To address these issues, we synthesized a porous covalent triazine framework (An-CTFs) based on 9,10-dicyanoanthracene (An-CN) units through an ionothermal reaction in the presence of different molar ratios of molten zinc chloride (ZnCl
) at 400 and 500 °C, yielding An-CTF-10-400, An-CTF-20-400, An-CTF-10-500, and An-CTF-20-500 microporous materials. According to N
adsorption-desorption analyses (BET), these An-CTFs produced exceptionally high specific surface areas ranging from 406-751 m
·g
. Furthermore, An-CTF-10-500 had a capacitance of 589 F·g
, remarkable cycle stability up to 5000 cycles, up to 95% capacity retention, and strong CO
adsorption capacity up to 5.65 mmol·g
at 273 K. As a result, our An-CTFs are a good alternative for both electrochemical energy storage and CO
uptake.</description><subject>Adsorption</subject><subject>Anthracene</subject><subject>Anthracenes</subject><subject>Capacitance</subject><subject>Carbon dioxide</subject><subject>Carbon Dioxide - chemistry</subject><subject>Charged particles</subject><subject>Decomposition</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Energy storage</subject><subject>Graphene</subject><subject>Investigations</subject><subject>Metal-Organic Frameworks</subject><subject>Microscopy</subject><subject>Morphology</subject><subject>Nitrogen</subject><subject>Nitrogen - chemistry</subject><subject>Porous materials</subject><subject>Spectrum analysis</subject><subject>Supercapacitors</subject><subject>Surface chemistry</subject><subject>Triazine</subject><subject>Triazines - chemistry</subject><subject>Zinc chloride</subject><issn>1422-0067</issn><issn>1661-6596</issn><issn>1422-0067</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNpdkUtv1DAUhSNERUthxxpZYsOCUL_y2iANA6WVilqJdm3dODczHhI72E6h_JP-23rUUg3d2FfXn8_18cmyN4x-FKKhR2YzBi5oKVgln2UHTHKeU1pWz3fq_exlCBtKueBF8yLbF4XgddEUB9nt1RA9hAjtgGTprmFAG8mlN_DXWCTnfgXWaHLsYcTfzv8knyFgR5wlCxvXHjQm6rszGG8IBHIxQOydH0layIlZrfML9NsGWJ30wbfp5hfj_pgOyaILzk_RpBbYjvyYJ_QaJtAmOh9eZXs9DAFfP-yH2dXx18vlSX52_u10uTjLtZA85o0GJrikWtc1KzuGXd1IIZBDW0vsecUEpZVsEXUlRV-lmum2ayjroa1QiMPs073uNLcjdslQ-pBBTd6M4G-UA6P-P7FmrVbuWtVNwdKkJPD-QcC7XzOGqEYTNA4DWHRzULyUklIhWJnQd0_QjZu9Tfa2FJdNSpEl6sM9pb0LwWP_-BhG1TZztZt5wt_uGniE_4Us7gDB56sj</recordid><startdate>20220315</startdate><enddate>20220315</enddate><creator>Mohamed, Mohamed Gamal</creator><creator>Sharma, Santosh U</creator><creator>Liu, Ni-Yun</creator><creator>Mansoure, Tharwat Hassan</creator><creator>Samy, Maha Mohamed</creator><creator>Chaganti, Swetha V</creator><creator>Chang, Yu-Lung</creator><creator>Lee, Jyh-Tsung</creator><creator>Kuo, Shiao-Wei</creator><general>MDPI AG</general><general>MDPI</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>MBDVC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5848-0196</orcidid><orcidid>https://orcid.org/0000-0003-0301-8372</orcidid><orcidid>https://orcid.org/0000-0002-4306-7171</orcidid></search><sort><creationdate>20220315</creationdate><title>Ultrastable Covalent Triazine Organic Framework Based on Anthracene Moiety as Platform for High-Performance Carbon Dioxide Adsorption and Supercapacitors</title><author>Mohamed, Mohamed Gamal ; 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The exceptional efficiency of such compounds, however, is dependent on their larger surface area and the level of nitrogen doping. To address these issues, we synthesized a porous covalent triazine framework (An-CTFs) based on 9,10-dicyanoanthracene (An-CN) units through an ionothermal reaction in the presence of different molar ratios of molten zinc chloride (ZnCl
) at 400 and 500 °C, yielding An-CTF-10-400, An-CTF-20-400, An-CTF-10-500, and An-CTF-20-500 microporous materials. According to N
adsorption-desorption analyses (BET), these An-CTFs produced exceptionally high specific surface areas ranging from 406-751 m
·g
. Furthermore, An-CTF-10-500 had a capacitance of 589 F·g
, remarkable cycle stability up to 5000 cycles, up to 95% capacity retention, and strong CO
adsorption capacity up to 5.65 mmol·g
at 273 K. As a result, our An-CTFs are a good alternative for both electrochemical energy storage and CO
uptake.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>35328595</pmid><doi>10.3390/ijms23063174</doi><orcidid>https://orcid.org/0000-0002-5848-0196</orcidid><orcidid>https://orcid.org/0000-0003-0301-8372</orcidid><orcidid>https://orcid.org/0000-0002-4306-7171</orcidid><oa>free_for_read</oa></addata></record> |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; MEDLINE; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central |
| subjects | Adsorption Anthracene Anthracenes Capacitance Carbon dioxide Carbon Dioxide - chemistry Charged particles Decomposition Electrode materials Electrodes Electrolytes Energy storage Graphene Investigations Metal-Organic Frameworks Microscopy Morphology Nitrogen Nitrogen - chemistry Porous materials Spectrum analysis Supercapacitors Surface chemistry Triazine Triazines - chemistry Zinc chloride |
| title | Ultrastable Covalent Triazine Organic Framework Based on Anthracene Moiety as Platform for High-Performance Carbon Dioxide Adsorption and Supercapacitors |
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