Two Birds with One Stone: Preparation of 4, 4-Diaminodiphenylmethane Functionalized GO@SiO2 with Mechanical Reinforcement and UV Shielding Properties and Its Application in Thermoplastic Polyurethane
This study prepared 4,4-diaminodiphenylmethane (DDM)-functionalized graphene oxide (GO)@silica dioxide (SiO2) nano-composites through amidation reaction and low-temperature precipitation. The resulting modified GO, that was DDM-GO@SiO2. The study found that DDM-GO@SiO2 showed good dispersion and com...
Gespeichert in:
| Veröffentlicht in: | Polymers 2021-12, Vol.13 (23), p.4220, Article 4220 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 23 |
| container_start_page | 4220 |
| container_title | Polymers |
| container_volume | 13 |
| creator | Ding, Guoxin Tai, Hongxu Chen, Chuanxin Sun, Chenfeng Tang, Zhongfeng |
| description | This study prepared 4,4-diaminodiphenylmethane (DDM)-functionalized graphene oxide (GO)@silica dioxide (SiO2) nano-composites through amidation reaction and low-temperature precipitation. The resulting modified GO, that was DDM-GO@SiO2. The study found that DDM-GO@SiO2 showed good dispersion and compatibility with thermoplastic polyurethane (TPU) substrates. Compared with pure TPU, the tensile strength of the TPU composites increased by 41% to 94.6 MPa at only 0.5 wt% DDM-GO@SiO2. In addition, even when a small amount of DDM-GO@SiO2 was added, the UV absorption of TPU composites increased significantly, TPU composites can achieve a UV shielding efficiency of 95.21% in the UV-A region. These results show that this type of material holds great promise for the preparation of functional coatings and film materials with high strength and weather resistance. |
| doi_str_mv | 10.3390/polym13234220 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8659490</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2608122316</sourcerecordid><originalsourceid>FETCH-LOGICAL-c392t-ada3dc201fa9b57cb15d9c12be127a8c0271383447f17fdf6d63d82cc6e59d7d3</originalsourceid><addsrcrecordid>eNqNkk9v1DAQxSMEolXpkbslLkgQ8J8kTjggykJLpaKt2JZr5LUnjSvHDrbDavmCfC28m6qinPDFlub3nmdGL8ueE_yGsQa_HZ3ZDoRRVlCKH2WHFHOWF6zCj_96H2THIdzidIqyqgh_mh2woq4Zp-ww-321ceij9iqgjY49WlpAq-gsvEOXHkbhRdTOIteh4jUq8k9aDNo6pcce7NYMEHuRFKeTlTtOGP0LFDpbfljpJZ0dv4JMjJbCoG-gbee8hAFsRMIqdP0drXoNRml7kz50I_ioIexr5zGgk3E0SbrvQVt01YMf3GhEiFqiyzT95OcWnmVPOmECHN_dR9n16eerxZf8Ynl2vji5yCVraMyFEkxJikknmnXJ5ZqUqpGEroFQLmqJKSesZkXBO8I71VWqYqqmUlZQNoordpS9n33HaT2AkmkQL0w7ej0Iv22d0O3DitV9e-N-tnVVNkWDk8HLOwPvfkwQYjvoIMGYNISbQksrXJeMl3yHvvgHvXWTT0ueKUIpI1Wi8pmS3oXgobtvhuB2l5L2QUoSX8_8BtauC1KDlXCvSSnhrOA1qXaBIQsd98tfuMnGJH31_1L2B6C71Bs</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2608122316</pqid></control><display><type>article</type><title>Two Birds with One Stone: Preparation of 4, 4-Diaminodiphenylmethane Functionalized GO@SiO2 with Mechanical Reinforcement and UV Shielding Properties and Its Application in Thermoplastic Polyurethane</title><source>PubMed Central Open Access</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Ding, Guoxin ; Tai, Hongxu ; Chen, Chuanxin ; Sun, Chenfeng ; Tang, Zhongfeng</creator><creatorcontrib>Ding, Guoxin ; Tai, Hongxu ; Chen, Chuanxin ; Sun, Chenfeng ; Tang, Zhongfeng</creatorcontrib><description>This study prepared 4,4-diaminodiphenylmethane (DDM)-functionalized graphene oxide (GO)@silica dioxide (SiO2) nano-composites through amidation reaction and low-temperature precipitation. The resulting modified GO, that was DDM-GO@SiO2. The study found that DDM-GO@SiO2 showed good dispersion and compatibility with thermoplastic polyurethane (TPU) substrates. Compared with pure TPU, the tensile strength of the TPU composites increased by 41% to 94.6 MPa at only 0.5 wt% DDM-GO@SiO2. In addition, even when a small amount of DDM-GO@SiO2 was added, the UV absorption of TPU composites increased significantly, TPU composites can achieve a UV shielding efficiency of 95.21% in the UV-A region. These results show that this type of material holds great promise for the preparation of functional coatings and film materials with high strength and weather resistance.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13234220</identifier><identifier>PMID: 34883723</identifier><language>eng</language><publisher>BASEL: Mdpi</publisher><subject>Chemical precipitation ; Epoxy resins ; Graphene ; Hydrochloric acid ; Low temperature ; Mechanical properties ; Methylene dianiline ; Nanocomposites ; Nanoparticles ; Physical Sciences ; Polymer Science ; Polymers ; Polyurethane resins ; Potassium ; Scanning electron microscopy ; Science & Technology ; Shielding ; Silica ; Silicon dioxide ; Spectrum analysis ; Substrates ; Tensile strength ; Urethane thermoplastic elastomers</subject><ispartof>Polymers, 2021-12, Vol.13 (23), p.4220, Article 4220</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>2</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000734781600001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c392t-ada3dc201fa9b57cb15d9c12be127a8c0271383447f17fdf6d63d82cc6e59d7d3</citedby><cites>FETCH-LOGICAL-c392t-ada3dc201fa9b57cb15d9c12be127a8c0271383447f17fdf6d63d82cc6e59d7d3</cites><orcidid>0000-0001-7288-0586</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659490/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659490/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids></links><search><creatorcontrib>Ding, Guoxin</creatorcontrib><creatorcontrib>Tai, Hongxu</creatorcontrib><creatorcontrib>Chen, Chuanxin</creatorcontrib><creatorcontrib>Sun, Chenfeng</creatorcontrib><creatorcontrib>Tang, Zhongfeng</creatorcontrib><title>Two Birds with One Stone: Preparation of 4, 4-Diaminodiphenylmethane Functionalized GO@SiO2 with Mechanical Reinforcement and UV Shielding Properties and Its Application in Thermoplastic Polyurethane</title><title>Polymers</title><addtitle>POLYMERS-BASEL</addtitle><description>This study prepared 4,4-diaminodiphenylmethane (DDM)-functionalized graphene oxide (GO)@silica dioxide (SiO2) nano-composites through amidation reaction and low-temperature precipitation. The resulting modified GO, that was DDM-GO@SiO2. The study found that DDM-GO@SiO2 showed good dispersion and compatibility with thermoplastic polyurethane (TPU) substrates. Compared with pure TPU, the tensile strength of the TPU composites increased by 41% to 94.6 MPa at only 0.5 wt% DDM-GO@SiO2. In addition, even when a small amount of DDM-GO@SiO2 was added, the UV absorption of TPU composites increased significantly, TPU composites can achieve a UV shielding efficiency of 95.21% in the UV-A region. These results show that this type of material holds great promise for the preparation of functional coatings and film materials with high strength and weather resistance.</description><subject>Chemical precipitation</subject><subject>Epoxy resins</subject><subject>Graphene</subject><subject>Hydrochloric acid</subject><subject>Low temperature</subject><subject>Mechanical properties</subject><subject>Methylene dianiline</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Physical Sciences</subject><subject>Polymer Science</subject><subject>Polymers</subject><subject>Polyurethane resins</subject><subject>Potassium</subject><subject>Scanning electron microscopy</subject><subject>Science & Technology</subject><subject>Shielding</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Spectrum analysis</subject><subject>Substrates</subject><subject>Tensile strength</subject><subject>Urethane thermoplastic elastomers</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkk9v1DAQxSMEolXpkbslLkgQ8J8kTjggykJLpaKt2JZr5LUnjSvHDrbDavmCfC28m6qinPDFlub3nmdGL8ueE_yGsQa_HZ3ZDoRRVlCKH2WHFHOWF6zCj_96H2THIdzidIqyqgh_mh2woq4Zp-ww-321ceij9iqgjY49WlpAq-gsvEOXHkbhRdTOIteh4jUq8k9aDNo6pcce7NYMEHuRFKeTlTtOGP0LFDpbfljpJZ0dv4JMjJbCoG-gbee8hAFsRMIqdP0drXoNRml7kz50I_ioIexr5zGgk3E0SbrvQVt01YMf3GhEiFqiyzT95OcWnmVPOmECHN_dR9n16eerxZf8Ynl2vji5yCVraMyFEkxJikknmnXJ5ZqUqpGEroFQLmqJKSesZkXBO8I71VWqYqqmUlZQNoordpS9n33HaT2AkmkQL0w7ej0Iv22d0O3DitV9e-N-tnVVNkWDk8HLOwPvfkwQYjvoIMGYNISbQksrXJeMl3yHvvgHvXWTT0ueKUIpI1Wi8pmS3oXgobtvhuB2l5L2QUoSX8_8BtauC1KDlXCvSSnhrOA1qXaBIQsd98tfuMnGJH31_1L2B6C71Bs</recordid><startdate>20211201</startdate><enddate>20211201</enddate><creator>Ding, Guoxin</creator><creator>Tai, Hongxu</creator><creator>Chen, Chuanxin</creator><creator>Sun, Chenfeng</creator><creator>Tang, Zhongfeng</creator><general>Mdpi</general><general>MDPI AG</general><general>MDPI</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-7288-0586</orcidid></search><sort><creationdate>20211201</creationdate><title>Two Birds with One Stone: Preparation of 4, 4-Diaminodiphenylmethane Functionalized GO@SiO2 with Mechanical Reinforcement and UV Shielding Properties and Its Application in Thermoplastic Polyurethane</title><author>Ding, Guoxin ; Tai, Hongxu ; Chen, Chuanxin ; Sun, Chenfeng ; Tang, Zhongfeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-ada3dc201fa9b57cb15d9c12be127a8c0271383447f17fdf6d63d82cc6e59d7d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical precipitation</topic><topic>Epoxy resins</topic><topic>Graphene</topic><topic>Hydrochloric acid</topic><topic>Low temperature</topic><topic>Mechanical properties</topic><topic>Methylene dianiline</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Physical Sciences</topic><topic>Polymer Science</topic><topic>Polymers</topic><topic>Polyurethane resins</topic><topic>Potassium</topic><topic>Scanning electron microscopy</topic><topic>Science & Technology</topic><topic>Shielding</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Spectrum analysis</topic><topic>Substrates</topic><topic>Tensile strength</topic><topic>Urethane thermoplastic elastomers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ding, Guoxin</creatorcontrib><creatorcontrib>Tai, Hongxu</creatorcontrib><creatorcontrib>Chen, Chuanxin</creatorcontrib><creatorcontrib>Sun, Chenfeng</creatorcontrib><creatorcontrib>Tang, Zhongfeng</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ding, Guoxin</au><au>Tai, Hongxu</au><au>Chen, Chuanxin</au><au>Sun, Chenfeng</au><au>Tang, Zhongfeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Two Birds with One Stone: Preparation of 4, 4-Diaminodiphenylmethane Functionalized GO@SiO2 with Mechanical Reinforcement and UV Shielding Properties and Its Application in Thermoplastic Polyurethane</atitle><jtitle>Polymers</jtitle><stitle>POLYMERS-BASEL</stitle><date>2021-12-01</date><risdate>2021</risdate><volume>13</volume><issue>23</issue><spage>4220</spage><pages>4220-</pages><artnum>4220</artnum><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>This study prepared 4,4-diaminodiphenylmethane (DDM)-functionalized graphene oxide (GO)@silica dioxide (SiO2) nano-composites through amidation reaction and low-temperature precipitation. The resulting modified GO, that was DDM-GO@SiO2. The study found that DDM-GO@SiO2 showed good dispersion and compatibility with thermoplastic polyurethane (TPU) substrates. Compared with pure TPU, the tensile strength of the TPU composites increased by 41% to 94.6 MPa at only 0.5 wt% DDM-GO@SiO2. In addition, even when a small amount of DDM-GO@SiO2 was added, the UV absorption of TPU composites increased significantly, TPU composites can achieve a UV shielding efficiency of 95.21% in the UV-A region. These results show that this type of material holds great promise for the preparation of functional coatings and film materials with high strength and weather resistance.</abstract><cop>BASEL</cop><pub>Mdpi</pub><pmid>34883723</pmid><doi>10.3390/polym13234220</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-7288-0586</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2073-4360 |
| ispartof | Polymers, 2021-12, Vol.13 (23), p.4220, Article 4220 |
| issn | 2073-4360 2073-4360 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8659490 |
| source | PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Chemical precipitation Epoxy resins Graphene Hydrochloric acid Low temperature Mechanical properties Methylene dianiline Nanocomposites Nanoparticles Physical Sciences Polymer Science Polymers Polyurethane resins Potassium Scanning electron microscopy Science & Technology Shielding Silica Silicon dioxide Spectrum analysis Substrates Tensile strength Urethane thermoplastic elastomers |
| title | Two Birds with One Stone: Preparation of 4, 4-Diaminodiphenylmethane Functionalized GO@SiO2 with Mechanical Reinforcement and UV Shielding Properties and Its Application in Thermoplastic Polyurethane |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T21%3A51%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Two%20Birds%20with%20One%20Stone:%20Preparation%20of%204,%204-Diaminodiphenylmethane%20Functionalized%20GO@SiO2%20with%20Mechanical%20Reinforcement%20and%20UV%20Shielding%20Properties%20and%20Its%20Application%20in%20Thermoplastic%20Polyurethane&rft.jtitle=Polymers&rft.au=Ding,%20Guoxin&rft.date=2021-12-01&rft.volume=13&rft.issue=23&rft.spage=4220&rft.pages=4220-&rft.artnum=4220&rft.issn=2073-4360&rft.eissn=2073-4360&rft_id=info:doi/10.3390/polym13234220&rft_dat=%3Cproquest_cross%3E2608122316%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2608122316&rft_id=info:pmid/34883723&rfr_iscdi=true |