Key Mechanistic Features of the Silver(I)-Mediated Deconstructive Fluorination of Cyclic Amines: Multistate Reactivity versus Single-Electron Transfer

Density functional calculations have provided evidence that a Ag­(I)-mediated deconstructive fluorination of N-benzoylated cyclic amines (LH) with Selectfluor [(F–TEDA)­(BF4)2] begins with an association of the reactants to form a singlet state adduct {[(LH)–Ag]–[F–TEDA]2+}. The subsequent formation...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-03, Vol.143 (10), p.3889-3900
Hauptverfasser:	Roque, Jose B, Sarpong, Richmond, Musaev, Djamaladdin G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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