Effect of SRB and Applied Potential on Stress Corrosion Behavior of X80 Steel in High-pH Soil Simulated Solution

The effect of SRB and applied potential on the stress corrosion sensitivity of X80 pipeline steel was analyzed in high-pH soil simulated solution under different conditions using a slow strain rate tensile test, electrochemical test, and electronic microanalysis. The experimental results showed that...

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Veröffentlicht in:Materials 2021-11, Vol.14 (22), p.6981
Hauptverfasser: Xu, Congmin, Gao, Haoran, Zhu, Wensheng, Wang, Wenyuan, Sun, Can, Chen, Yueqing
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creator Xu, Congmin
Gao, Haoran
Zhu, Wensheng
Wang, Wenyuan
Sun, Can
Chen, Yueqing
description The effect of SRB and applied potential on the stress corrosion sensitivity of X80 pipeline steel was analyzed in high-pH soil simulated solution under different conditions using a slow strain rate tensile test, electrochemical test, and electronic microanalysis. The experimental results showed that X80 pipeline steel has a certain degree of SCC sensitivity in high-pH simulated solution, and the crack growth mode was trans-granular stress corrosion cracking. In a sterile environment, the SCC mechanism of X80 steel was a mixture mechanism of anode dissolution and hydrogen embrittlement at −850 mV potential, while X80 steel had the lowest SCC sensitivity due to the weak effect of AD and HE; after Sulfate Reducing Bacteria (SRB) were inoculated, the SCC mechanism of X80 steel was an AD–membrane rupture mechanism at −850 mV potential. The synergistic effect of Cl− and SRB formed an oxygen concentration cell and an acidification microenvironment in the pitting corrosion pit, and this promoted the formation of pitting corrosion which induced crack nucleation, thus significantly improving the SCC sensitivity of X80 steel. The strong cathodic polarization promoted the local corrosion caused by SRB metabolism in the presence of bacteria, whereby the SCC sensitivity in the presence of bacteria was higher than that in sterile conditions under strong cathodic potential.
doi_str_mv 10.3390/ma14226981
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The experimental results showed that X80 pipeline steel has a certain degree of SCC sensitivity in high-pH simulated solution, and the crack growth mode was trans-granular stress corrosion cracking. In a sterile environment, the SCC mechanism of X80 steel was a mixture mechanism of anode dissolution and hydrogen embrittlement at −850 mV potential, while X80 steel had the lowest SCC sensitivity due to the weak effect of AD and HE; after Sulfate Reducing Bacteria (SRB) were inoculated, the SCC mechanism of X80 steel was an AD–membrane rupture mechanism at −850 mV potential. The synergistic effect of Cl− and SRB formed an oxygen concentration cell and an acidification microenvironment in the pitting corrosion pit, and this promoted the formation of pitting corrosion which induced crack nucleation, thus significantly improving the SCC sensitivity of X80 steel. The strong cathodic polarization promoted the local corrosion caused by SRB metabolism in the presence of bacteria, whereby the SCC sensitivity in the presence of bacteria was higher than that in sterile conditions under strong cathodic potential.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14226981</identifier><identifier>PMID: 34832381</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Acidification ; Anodic dissolution ; Bacteria ; Cathodic polarization ; Cathodic protection ; Concentration cell corrosion ; Corrosion ; Corrosion effects ; Corrosion mechanisms ; Corrosion potential ; Crack initiation ; Crack propagation ; Dissolution ; Electrode polarization ; Electrodes ; Experiments ; Failure analysis ; Fracture mechanics ; High strength low alloy steels ; Hydrogen ; Hydrogen embrittlement ; Mechanical properties ; Microorganisms ; Nucleation ; Pitting (corrosion) ; Simulation ; Slow strain rate ; Soils ; Steel ; Stress corrosion cracking ; Structural steels ; Sulfate reduction ; Synergistic effect ; Tensile strength ; Tensile tests</subject><ispartof>Materials, 2021-11, Vol.14 (22), p.6981</ispartof><rights>2021 by the authors. 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The experimental results showed that X80 pipeline steel has a certain degree of SCC sensitivity in high-pH simulated solution, and the crack growth mode was trans-granular stress corrosion cracking. In a sterile environment, the SCC mechanism of X80 steel was a mixture mechanism of anode dissolution and hydrogen embrittlement at −850 mV potential, while X80 steel had the lowest SCC sensitivity due to the weak effect of AD and HE; after Sulfate Reducing Bacteria (SRB) were inoculated, the SCC mechanism of X80 steel was an AD–membrane rupture mechanism at −850 mV potential. The synergistic effect of Cl− and SRB formed an oxygen concentration cell and an acidification microenvironment in the pitting corrosion pit, and this promoted the formation of pitting corrosion which induced crack nucleation, thus significantly improving the SCC sensitivity of X80 steel. The strong cathodic polarization promoted the local corrosion caused by SRB metabolism in the presence of bacteria, whereby the SCC sensitivity in the presence of bacteria was higher than that in sterile conditions under strong cathodic potential.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>34832381</pmid><doi>10.3390/ma14226981</doi><oa>free_for_read</oa></addata></record>
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subjects Acidification
Anodic dissolution
Bacteria
Cathodic polarization
Cathodic protection
Concentration cell corrosion
Corrosion
Corrosion effects
Corrosion mechanisms
Corrosion potential
Crack initiation
Crack propagation
Dissolution
Electrode polarization
Electrodes
Experiments
Failure analysis
Fracture mechanics
High strength low alloy steels
Hydrogen
Hydrogen embrittlement
Mechanical properties
Microorganisms
Nucleation
Pitting (corrosion)
Simulation
Slow strain rate
Soils
Steel
Stress corrosion cracking
Structural steels
Sulfate reduction
Synergistic effect
Tensile strength
Tensile tests
title Effect of SRB and Applied Potential on Stress Corrosion Behavior of X80 Steel in High-pH Soil Simulated Solution
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