Thermodynamic feasibility of shipboard conversion of marine plastics to blue diesel for self-powered ocean cleanup

Collecting and removing ocean plastics can mitigate their environmental impacts; however, ocean cleanup will be a complex and energy-intensive operation that has not been fully evaluated. This work examines the thermodynamic feasibility and subsequent implications of hydrothermally converting this w...

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Veröffentlicht in:Proceedings of the National Academy of Sciences - PNAS 2021-11, Vol.118 (46), p.1-8
Hauptverfasser: Belden, Elizabeth R., Kazantzis, Nikolaos K., Reddy, Christopher M., Kite-Powell, Hauke, Timko, Michael T., Italiani, Eduardo, Herschbach, Dudley R.
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container_end_page 8
container_issue 46
container_start_page 1
container_title Proceedings of the National Academy of Sciences - PNAS
container_volume 118
creator Belden, Elizabeth R.
Kazantzis, Nikolaos K.
Reddy, Christopher M.
Kite-Powell, Hauke
Timko, Michael T.
Italiani, Eduardo
Herschbach, Dudley R.
description Collecting and removing ocean plastics can mitigate their environmental impacts; however, ocean cleanup will be a complex and energy-intensive operation that has not been fully evaluated. This work examines the thermodynamic feasibility and subsequent implications of hydrothermally converting this waste into a fuel to enable self-powered cleanup. A comprehensive probabilistic exergy analysis demonstrates that hydrothermal liquefaction has potential to generate sufficient energy to power both the process and the ship performing the cleanup. Self-powered cleanup reduces the number of roundtrips to port of a waste-laden ship, eliminating the need for fossil fuel use for most plastic concentrations. Several cleanup scenarios are modeled for the Great Pacific Garbage Patch (GPGP), corresponding to 230 t to 11,500 t of plastic removed yearly; the range corresponds to uncertainty in the surface concentration of plastics in the GPGP. Estimated cleanup times depends mainly on the number of booms that can be deployed in the GPGP without sacrificing collection efficiency. Self-powered cleanup may be a viable approach for removal of plastics from the ocean, and gaps in our understanding of GPGP characteristics should be addressed to reduce uncertainty.
doi_str_mv 10.1073/pnas.2107250118
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subjects Diesel fuels
Environmental impact
Environmental Monitoring - methods
Exergy
Feasibility
Feasibility Studies
Fossil fuels
Garbage
Liquefaction
Marine pollution
Oceans and Seas
Physical Sciences
Plastic pollution
Plastics
Plastics - chemistry
Thermodynamics
Uncertainty
Waste Products - analysis
title Thermodynamic feasibility of shipboard conversion of marine plastics to blue diesel for self-powered ocean cleanup
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