Transmetalation Reactions Triggered by Electron Transfer between Organocopper Complexes

[Cu­(bipy)­(C6F5)] reacts with most aryl iodides to form heterobiphenyls by cross-coupling, but when Rf–I is used (Rf = 3,5-dicholoro-2,4,6-trifluorophenyl), homocoupling products are also formed. Kinetic studies suggest that, for the homocoupling reaction, a mechanism based on transmetalation from...

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Veröffentlicht in:	Inorganic chemistry 2021-08, Vol.60 (15), p.11633-11639
Hauptverfasser:	Lozano-Lavilla, Olmo, Gómez-Orellana, Pablo, Lledós, Agustí, Casares, Juan A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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