Physicochemical and Sorptive Properties of a Phosphorylated Mercerized Cotton Fabric
A process of phosphorylation for a mercerized cotton kersey fabric was investigated. After wet oxidation, the phosphorus content in each sample was determined by spectrophotometric analysis. The range was 0.179 to 0.950 mmol g–1. A significant decrease in the tensile strength of samples resulted fro...
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| Veröffentlicht in: | Polymers 2021-10, Vol.13 (21), p.3756 |
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| creator | Solovov, Roman Perevoznikova, Anfisa Seliverstov, Alexander Shapagin, Alexey Fedoseev, Alexandr Milyutin, Vitaly Ershov, Boris |
| description | A process of phosphorylation for a mercerized cotton kersey fabric was investigated. After wet oxidation, the phosphorus content in each sample was determined by spectrophotometric analysis. The range was 0.179 to 0.950 mmol g–1. A significant decrease in the tensile strength of samples resulted from an increase of phosphoric acid concentration in the phosphorylating solution. The mercerization has a positive impact on the process of phosphorylation, as the phosphorus content was found to be three times higher in the samples that underwent mercerization. The sorption properties of phosphorylated cotton fabric were studied using the Cu2+ sorption process as a reference. The value of the static exchange capacity for the phosphorylated fabric was determined to reach its maximum when the concentration of the H3PO4 in the phosphorylating solution was 1.40 M, and was found to be 1.48 ± 0.11 mmol g–1 with the phosphorus content equal to 0.898 ± 0.090 mmol g–1. The sorption of Cu2+ by a single phosphorus-containing group occurred for samples with phosphorus content not exceeding 0.80 mmol g–1. The preliminary studies of micro-quantities of 241Am, 233U, and 239Pu radionuclide sorption from aqueous solutions with phosphorylated textile demonstrated the high efficiency. |
| doi_str_mv | 10.3390/polym13213756 |
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After wet oxidation, the phosphorus content in each sample was determined by spectrophotometric analysis. The range was 0.179 to 0.950 mmol g–1. A significant decrease in the tensile strength of samples resulted from an increase of phosphoric acid concentration in the phosphorylating solution. The mercerization has a positive impact on the process of phosphorylation, as the phosphorus content was found to be three times higher in the samples that underwent mercerization. The sorption properties of phosphorylated cotton fabric were studied using the Cu2+ sorption process as a reference. The value of the static exchange capacity for the phosphorylated fabric was determined to reach its maximum when the concentration of the H3PO4 in the phosphorylating solution was 1.40 M, and was found to be 1.48 ± 0.11 mmol g–1 with the phosphorus content equal to 0.898 ± 0.090 mmol g–1. The sorption of Cu2+ by a single phosphorus-containing group occurred for samples with phosphorus content not exceeding 0.80 mmol g–1. The preliminary studies of micro-quantities of 241Am, 233U, and 239Pu radionuclide sorption from aqueous solutions with phosphorylated textile demonstrated the high efficiency.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13213756</identifier><identifier>PMID: 34771314</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Aqueous solutions ; Cellulose ; Cold ; Copper ; Cotton ; Cotton fabrics ; Mercerization ; Metals ; Molybdenum ; Phosphoric acid ; Phosphorus ; Phosphorus content ; Phosphorylation ; Radioisotopes ; Reagents ; Sorption ; Spectrophotometry ; Tensile strength ; Wet oxidation</subject><ispartof>Polymers, 2021-10, Vol.13 (21), p.3756</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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After wet oxidation, the phosphorus content in each sample was determined by spectrophotometric analysis. The range was 0.179 to 0.950 mmol g–1. A significant decrease in the tensile strength of samples resulted from an increase of phosphoric acid concentration in the phosphorylating solution. The mercerization has a positive impact on the process of phosphorylation, as the phosphorus content was found to be three times higher in the samples that underwent mercerization. The sorption properties of phosphorylated cotton fabric were studied using the Cu2+ sorption process as a reference. The value of the static exchange capacity for the phosphorylated fabric was determined to reach its maximum when the concentration of the H3PO4 in the phosphorylating solution was 1.40 M, and was found to be 1.48 ± 0.11 mmol g–1 with the phosphorus content equal to 0.898 ± 0.090 mmol g–1. The sorption of Cu2+ by a single phosphorus-containing group occurred for samples with phosphorus content not exceeding 0.80 mmol g–1. The preliminary studies of micro-quantities of 241Am, 233U, and 239Pu radionuclide sorption from aqueous solutions with phosphorylated textile demonstrated the high efficiency.</description><subject>Aqueous solutions</subject><subject>Cellulose</subject><subject>Cold</subject><subject>Copper</subject><subject>Cotton</subject><subject>Cotton fabrics</subject><subject>Mercerization</subject><subject>Metals</subject><subject>Molybdenum</subject><subject>Phosphoric acid</subject><subject>Phosphorus</subject><subject>Phosphorus content</subject><subject>Phosphorylation</subject><subject>Radioisotopes</subject><subject>Reagents</subject><subject>Sorption</subject><subject>Spectrophotometry</subject><subject>Tensile strength</subject><subject>Wet oxidation</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkc9LwzAUx4MoTuaO3gtevFSTJmmSiyDDqTBx4DyHLH2zGW1Tk24w_3o7NsT5Lu_B-7yfX4SuCL6lVOG71lfbmtCMUMHzE3SRYUFTRnN8-iceoFGMK9wb43lOxDkaUCYEoYRdoPms3EZnvS2hdtZUiWmK5N2HtnMbSGbBtxA6BzHxy8Qks9LHtvRhW5kOiuQVgoXgvvtw7LvON8nELIKzl-hsaaoIo4Mfoo_J43z8nE7fnl7GD9PUUpV1qRGMEEIpk9IwaS3BVEizFLwgEgBUVmAiDRBLCy65zYRRuMj7Isj7OsbpEN3v-7brRQ2FhaYLptJtcLUJW-2N08eZxpX602-05FLSfvIQ3RwaBP-1htjp2kULVWUa8OuoM64EU1wp2aPX_9CVX4emP29H5f1vFdtR6Z6ywccYYPm7DMF6J5k-koz-AB4FiMk</recordid><startdate>20211030</startdate><enddate>20211030</enddate><creator>Solovov, Roman</creator><creator>Perevoznikova, Anfisa</creator><creator>Seliverstov, Alexander</creator><creator>Shapagin, Alexey</creator><creator>Fedoseev, Alexandr</creator><creator>Milyutin, Vitaly</creator><creator>Ershov, Boris</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-8866-0710</orcidid><orcidid>https://orcid.org/0000-0001-7023-2980</orcidid><orcidid>https://orcid.org/0000-0003-2452-0783</orcidid><orcidid>https://orcid.org/0000-0002-3253-1127</orcidid></search><sort><creationdate>20211030</creationdate><title>Physicochemical and Sorptive Properties of a Phosphorylated Mercerized Cotton Fabric</title><author>Solovov, Roman ; 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After wet oxidation, the phosphorus content in each sample was determined by spectrophotometric analysis. The range was 0.179 to 0.950 mmol g–1. A significant decrease in the tensile strength of samples resulted from an increase of phosphoric acid concentration in the phosphorylating solution. The mercerization has a positive impact on the process of phosphorylation, as the phosphorus content was found to be three times higher in the samples that underwent mercerization. The sorption properties of phosphorylated cotton fabric were studied using the Cu2+ sorption process as a reference. The value of the static exchange capacity for the phosphorylated fabric was determined to reach its maximum when the concentration of the H3PO4 in the phosphorylating solution was 1.40 M, and was found to be 1.48 ± 0.11 mmol g–1 with the phosphorus content equal to 0.898 ± 0.090 mmol g–1. The sorption of Cu2+ by a single phosphorus-containing group occurred for samples with phosphorus content not exceeding 0.80 mmol g–1. The preliminary studies of micro-quantities of 241Am, 233U, and 239Pu radionuclide sorption from aqueous solutions with phosphorylated textile demonstrated the high efficiency.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>34771314</pmid><doi>10.3390/polym13213756</doi><orcidid>https://orcid.org/0000-0002-8866-0710</orcidid><orcidid>https://orcid.org/0000-0001-7023-2980</orcidid><orcidid>https://orcid.org/0000-0003-2452-0783</orcidid><orcidid>https://orcid.org/0000-0002-3253-1127</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Aqueous solutions Cellulose Cold Copper Cotton Cotton fabrics Mercerization Metals Molybdenum Phosphoric acid Phosphorus Phosphorus content Phosphorylation Radioisotopes Reagents Sorption Spectrophotometry Tensile strength Wet oxidation |
| title | Physicochemical and Sorptive Properties of a Phosphorylated Mercerized Cotton Fabric |
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