Mesophase Pitch-Based Carbon Fibers: Accelerated Stabilization of Pitch Fibers under Effective Plasma Irradiation-Assisted Modification
Stabilization is the most complicated and time-consuming step in the manufacture of carbon fibers (CFs), which is important to prepare CFs with high performance. Accelerated stabilization was successfully demonstrated under effective plasma irradiation-assisted modification (PIM) of mesophase pitch...
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| Veröffentlicht in: | Materials 2021-10, Vol.14 (21), p.6382 |
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| creator | Peng, Yuanshuo Tan, Ruixuan Liu, Yue Yang, Jianxiao Li, Yanfeng Li, Jun Fan, Zheqiong Shi, Kui |
| description | Stabilization is the most complicated and time-consuming step in the manufacture of carbon fibers (CFs), which is important to prepare CFs with high performance. Accelerated stabilization was successfully demonstrated under effective plasma irradiation-assisted modification (PIM) of mesophase pitch fibers (PFs). The results showed that the PIM treatment could obviously introduce more oxygen-containing groups into PFs, which was remarkably efficient in shortening the stabilization time of PFs with a faster stabilization heating rate, as well as in preparing the corresponding CFs with higher performance. The obtained graphitized fiber (GF-5) from the PF-5 under PIM treatment of 5 min presented a higher tensile strength of 2.21 GPa, a higher tensile modulus of 502 GPa, and a higher thermal conductivity of 920 W/m·K compared to other GFs. Therefore, the accelerated stabilization of PFs by PIM treatment is an efficient strategy for developing low-cost pitch-based CFs with high performance. |
| doi_str_mv | 10.3390/ma14216382 |
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Accelerated stabilization was successfully demonstrated under effective plasma irradiation-assisted modification (PIM) of mesophase pitch fibers (PFs). The results showed that the PIM treatment could obviously introduce more oxygen-containing groups into PFs, which was remarkably efficient in shortening the stabilization time of PFs with a faster stabilization heating rate, as well as in preparing the corresponding CFs with higher performance. The obtained graphitized fiber (GF-5) from the PF-5 under PIM treatment of 5 min presented a higher tensile strength of 2.21 GPa, a higher tensile modulus of 502 GPa, and a higher thermal conductivity of 920 W/m·K compared to other GFs. Therefore, the accelerated stabilization of PFs by PIM treatment is an efficient strategy for developing low-cost pitch-based CFs with high performance.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14216382</identifier><identifier>PMID: 34771907</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Carbon fibers ; Catalytic cracking ; Fourier transforms ; Graphitization ; Heating rate ; Irradiation ; Mechanical properties ; Mesophase ; Modulus of elasticity ; Nitrogen ; Plasma ; Stabilization ; Tensile strength ; Thermal conductivity</subject><ispartof>Materials, 2021-10, Vol.14 (21), p.6382</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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Therefore, the accelerated stabilization of PFs by PIM treatment is an efficient strategy for developing low-cost pitch-based CFs with high performance.</description><subject>Carbon fibers</subject><subject>Catalytic cracking</subject><subject>Fourier transforms</subject><subject>Graphitization</subject><subject>Heating rate</subject><subject>Irradiation</subject><subject>Mechanical properties</subject><subject>Mesophase</subject><subject>Modulus of elasticity</subject><subject>Nitrogen</subject><subject>Plasma</subject><subject>Stabilization</subject><subject>Tensile strength</subject><subject>Thermal conductivity</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkdtq3DAQQEVoSEKyL_kCQ19KwalkybLVh8J2yQ0SUmjyLEa3rIJtbSU70PxAfjvaC71ELxpmzhxGGoROCT6jVOAvPRBWEU7bag8dESF4SQRjH_6JD9EspSecD6WkrcQBOqSsaYjAzRF6vbUprJaQbPHDj3pZfs-hKRYQVRiKC69sTF-Luda2sxHGXPo5gvKdf4HRZyK4bd8OLabB2FicO2f16J-ztIPUQ3EdIxi_aSnnKfm0Nt0G453Xm-wJ2nfQJTvb3cfo4eL8fnFV3txdXi_mN6VmTIwlr4jGYJx1CjBnzmJbGQa8dY1pcc0abUirFGlcDZgS5SpMWsqxUIJxjg09Rt-23tWkemu0HcYInVxF30P8LQN4-X9l8Ev5GJ5lW7c15TQLPu0EMfyabBpl71P-nQ4GG6Ykq1o0TGSwyejHd-hTmOKQn7emeB5XUJypz1tKx5BStO7PMATL9Yrl3xXTN9KVmWI</recordid><startdate>20211025</startdate><enddate>20211025</enddate><creator>Peng, Yuanshuo</creator><creator>Tan, Ruixuan</creator><creator>Liu, Yue</creator><creator>Yang, Jianxiao</creator><creator>Li, Yanfeng</creator><creator>Li, Jun</creator><creator>Fan, Zheqiong</creator><creator>Shi, Kui</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5612-5035</orcidid></search><sort><creationdate>20211025</creationdate><title>Mesophase Pitch-Based Carbon Fibers: Accelerated Stabilization of Pitch Fibers under Effective Plasma Irradiation-Assisted Modification</title><author>Peng, Yuanshuo ; 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Accelerated stabilization was successfully demonstrated under effective plasma irradiation-assisted modification (PIM) of mesophase pitch fibers (PFs). The results showed that the PIM treatment could obviously introduce more oxygen-containing groups into PFs, which was remarkably efficient in shortening the stabilization time of PFs with a faster stabilization heating rate, as well as in preparing the corresponding CFs with higher performance. The obtained graphitized fiber (GF-5) from the PF-5 under PIM treatment of 5 min presented a higher tensile strength of 2.21 GPa, a higher tensile modulus of 502 GPa, and a higher thermal conductivity of 920 W/m·K compared to other GFs. 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| subjects | Carbon fibers Catalytic cracking Fourier transforms Graphitization Heating rate Irradiation Mechanical properties Mesophase Modulus of elasticity Nitrogen Plasma Stabilization Tensile strength Thermal conductivity |
| title | Mesophase Pitch-Based Carbon Fibers: Accelerated Stabilization of Pitch Fibers under Effective Plasma Irradiation-Assisted Modification |
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