1,5-Hydrogen Atom Transfer/Surzur–Tanner Rearrangement: A Radical Cascade Approach for the Synthesis of 1,6-Dioxaspiro[4.5]decane and 6,8-Dioxabicyclo[3.2.1]octane Scaffolds in Carbohydrate Systems

The 1,5-HAT–1,2-(ester)­alkyl radical migration (Surzur–Tanner rearrangement) radical/polar sequence triggered by alkoxyl radicals has been studied on a series of C-glycosyl substrates with 3-C-(α,β-d,l-glycopyranosyl)­1-propanol and C-(α-d,l-glycopyranosyl)­methanol structures prepared from chiral...

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Veröffentlicht in:	Journal of organic chemistry 2021-11, Vol.86 (21), p.14508-14552
Hauptverfasser:	León, Elisa I, Martín, Ángeles, Montes, Adrián S, Pérez-Martín, Inés, del Sol Rodríguez, María, Suárez, Ernesto
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes Carbohydrates Hydrogen Octanes
Online-Zugang:	Volltext
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