Ground electronic state description of thiourea coordination in homoleptic Zn2+, Ni2+ and Co2+ complexes using sulfur K‐edge X‐ray absorption spectroscopy

Sulfur K‐edge X‐ray absorption spectroscopy (XAS) was employed to experimentally characterize the coordinative bond between the thiourea (TU) or thiocarbamide ligand and transition metal (TM) ions Zn2+, Co2+ and Ni2+ in distorted tetrahedral and octahedral homoleptic coordination environments. Compa...

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Veröffentlicht in:	Journal of synchrotron radiation 2021-11, Vol.28 (6), p.1825-1838
Hauptverfasser:	Queen, Matt S., Jalilehvand, Farideh, Szilagyi, Robert K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectroscopy Bonding Cobalt Coordination Density functional theory Dipoles Electron states Empirical analysis ground electronic state Holes (electron deficiencies) Ligands metal–ligand bond covalency molecular orbital composition Nickel RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY Research Papers S-donor ligand Spectrum analysis Sulfur sulfur K-edge XANES Thioureas transition dipole integral Transition metals versatile S-donor ligand
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