Design and Development of Enhanced Antimicrobial Breathable Biodegradable Polymeric Films for Food Packaging Applications
The principle of breathable food packaging is to provide the optimal number of pores to transfer a sufficient amount of fresh air into the packaging headspace. In this work, antimicrobial microporous eco-friendly polymeric membranes were developed for food packaging. Polylactic acid (PLA) and polyca...
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description | The principle of breathable food packaging is to provide the optimal number of pores to transfer a sufficient amount of fresh air into the packaging headspace. In this work, antimicrobial microporous eco-friendly polymeric membranes were developed for food packaging. Polylactic acid (PLA) and polycaprolactone (PCL) were chosen as the main packaging polymers for their biodegradability. To develop the microporous films, sodium chloride (NaCl) and polyethylene oxide (PEO) were used as porogenic agents and the membranes were prepared using solvent-casting techniques. The results showed that films with of 50% NaCl and 10% PEO by mass achieved the highest air permeability and oxygen transmission rate (O2TR) with PLA. Meanwhile, blends of 20% PLA and 80% PCL by mass showed the highest air permeability and O2TR at 100% NaCl composition. The microporous membranes were also coated with cinnamaldehyde, a natural antimicrobial ingredient, to avoid the transportation of pathogens through the membranes into the packaged foods. In vitro analysis showed that the biodegradable membranes were not only environmentally friendly but also allowed for maximum food protection through the transportation of sterile fresh air, making them ideal for food packaging applications. |
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In this work, antimicrobial microporous eco-friendly polymeric membranes were developed for food packaging. Polylactic acid (PLA) and polycaprolactone (PCL) were chosen as the main packaging polymers for their biodegradability. To develop the microporous films, sodium chloride (NaCl) and polyethylene oxide (PEO) were used as porogenic agents and the membranes were prepared using solvent-casting techniques. The results showed that films with of 50% NaCl and 10% PEO by mass achieved the highest air permeability and oxygen transmission rate (O2TR) with PLA. Meanwhile, blends of 20% PLA and 80% PCL by mass showed the highest air permeability and O2TR at 100% NaCl composition. The microporous membranes were also coated with cinnamaldehyde, a natural antimicrobial ingredient, to avoid the transportation of pathogens through the membranes into the packaged foods. In vitro analysis showed that the biodegradable membranes were not only environmentally friendly but also allowed for maximum food protection through the transportation of sterile fresh air, making them ideal for food packaging applications.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13203527</identifier><identifier>PMID: 34685286</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Antiinfectives and antibacterials ; Antimicrobial agents ; Biodegradability ; Chloride ; Cinnamaldehyde ; Food packaging ; Food preservation ; Mechanical properties ; Membranes ; Methods ; Molecular weight ; Permeability ; Polycaprolactone ; Polyethylene ; Polyethylene oxide ; Polylactic acid ; Polymer films ; Polymers ; Sodium ; Sodium chloride ; Solvents ; Transportation</subject><ispartof>Polymers, 2021-10, Vol.13 (20), p.3527</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-e2d9b980a12bf3ec6ed1b728b79a88d4134d8b91b40da1eca10431ba145513743</citedby><cites>FETCH-LOGICAL-c392t-e2d9b980a12bf3ec6ed1b728b79a88d4134d8b91b40da1eca10431ba145513743</cites><orcidid>0000-0001-9905-3863 ; 0000-0002-6807-2110</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8541126/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8541126/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids></links><search><creatorcontrib>Abd Al-Ghani, Mona M.</creatorcontrib><creatorcontrib>Azzam, Rasha A.</creatorcontrib><creatorcontrib>Madkour, Tarek M.</creatorcontrib><title>Design and Development of Enhanced Antimicrobial Breathable Biodegradable Polymeric Films for Food Packaging Applications</title><title>Polymers</title><description>The principle of breathable food packaging is to provide the optimal number of pores to transfer a sufficient amount of fresh air into the packaging headspace. In this work, antimicrobial microporous eco-friendly polymeric membranes were developed for food packaging. Polylactic acid (PLA) and polycaprolactone (PCL) were chosen as the main packaging polymers for their biodegradability. To develop the microporous films, sodium chloride (NaCl) and polyethylene oxide (PEO) were used as porogenic agents and the membranes were prepared using solvent-casting techniques. The results showed that films with of 50% NaCl and 10% PEO by mass achieved the highest air permeability and oxygen transmission rate (O2TR) with PLA. Meanwhile, blends of 20% PLA and 80% PCL by mass showed the highest air permeability and O2TR at 100% NaCl composition. The microporous membranes were also coated with cinnamaldehyde, a natural antimicrobial ingredient, to avoid the transportation of pathogens through the membranes into the packaged foods. In vitro analysis showed that the biodegradable membranes were not only environmentally friendly but also allowed for maximum food protection through the transportation of sterile fresh air, making them ideal for food packaging applications.</description><subject>Antiinfectives and antibacterials</subject><subject>Antimicrobial agents</subject><subject>Biodegradability</subject><subject>Chloride</subject><subject>Cinnamaldehyde</subject><subject>Food packaging</subject><subject>Food preservation</subject><subject>Mechanical properties</subject><subject>Membranes</subject><subject>Methods</subject><subject>Molecular weight</subject><subject>Permeability</subject><subject>Polycaprolactone</subject><subject>Polyethylene</subject><subject>Polyethylene oxide</subject><subject>Polylactic acid</subject><subject>Polymer films</subject><subject>Polymers</subject><subject>Sodium</subject><subject>Sodium chloride</subject><subject>Solvents</subject><subject>Transportation</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdUU1v1DAQtRCIVqVH7pa4cAn4K4lzQdp-LCBVogc4R2N7knVx7GBnK-2_b7atEGUuM6N5enpvHiHvOfskZcc-zykcJi4Fk7VoX5FTwVpZKdmw1__MJ-S8lDu2lqqbhrdvyYlUja6Fbk7J4QqLHyOF6OgV3mNI84RxoWmg13EH0aKjm7j4yducjIdALzLCsgMTkF745HDM4B6326MYzN7SrQ9ToUPKdJuSo7dgf8Po40g38xy8hcWnWN6RNwOEgufP_Yz82l7_vPxW3fz4-v1yc1NZ2YmlQuE602kGXJhBom3QcdMKbdoOtHaKS-W06bhRzAFHC5wpyQ1wVddctkqekS9PvPPeTOjs6i5D6OfsJ8iHPoHvX16i3_Vjuu91rTgXzUrw8Zkgpz97LEs_-WIxBIiY9qUXtVatlkKLFfrhP-hd2ue42ntE1Zy33VFR9YRaX1pKxuGvGM76Y679i1zlA7Ublqs</recordid><startdate>20211014</startdate><enddate>20211014</enddate><creator>Abd Al-Ghani, Mona M.</creator><creator>Azzam, Rasha A.</creator><creator>Madkour, Tarek M.</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-9905-3863</orcidid><orcidid>https://orcid.org/0000-0002-6807-2110</orcidid></search><sort><creationdate>20211014</creationdate><title>Design and Development of Enhanced Antimicrobial Breathable Biodegradable Polymeric Films for Food Packaging Applications</title><author>Abd Al-Ghani, Mona M. ; Azzam, Rasha A. ; Madkour, Tarek M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-e2d9b980a12bf3ec6ed1b728b79a88d4134d8b91b40da1eca10431ba145513743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Antiinfectives and antibacterials</topic><topic>Antimicrobial agents</topic><topic>Biodegradability</topic><topic>Chloride</topic><topic>Cinnamaldehyde</topic><topic>Food packaging</topic><topic>Food preservation</topic><topic>Mechanical properties</topic><topic>Membranes</topic><topic>Methods</topic><topic>Molecular weight</topic><topic>Permeability</topic><topic>Polycaprolactone</topic><topic>Polyethylene</topic><topic>Polyethylene oxide</topic><topic>Polylactic acid</topic><topic>Polymer films</topic><topic>Polymers</topic><topic>Sodium</topic><topic>Sodium chloride</topic><topic>Solvents</topic><topic>Transportation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abd Al-Ghani, Mona M.</creatorcontrib><creatorcontrib>Azzam, Rasha A.</creatorcontrib><creatorcontrib>Madkour, Tarek M.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abd Al-Ghani, Mona M.</au><au>Azzam, Rasha A.</au><au>Madkour, Tarek M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design and Development of Enhanced Antimicrobial Breathable Biodegradable Polymeric Films for Food Packaging Applications</atitle><jtitle>Polymers</jtitle><date>2021-10-14</date><risdate>2021</risdate><volume>13</volume><issue>20</issue><spage>3527</spage><pages>3527-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>The principle of breathable food packaging is to provide the optimal number of pores to transfer a sufficient amount of fresh air into the packaging headspace. In this work, antimicrobial microporous eco-friendly polymeric membranes were developed for food packaging. Polylactic acid (PLA) and polycaprolactone (PCL) were chosen as the main packaging polymers for their biodegradability. To develop the microporous films, sodium chloride (NaCl) and polyethylene oxide (PEO) were used as porogenic agents and the membranes were prepared using solvent-casting techniques. The results showed that films with of 50% NaCl and 10% PEO by mass achieved the highest air permeability and oxygen transmission rate (O2TR) with PLA. Meanwhile, blends of 20% PLA and 80% PCL by mass showed the highest air permeability and O2TR at 100% NaCl composition. The microporous membranes were also coated with cinnamaldehyde, a natural antimicrobial ingredient, to avoid the transportation of pathogens through the membranes into the packaged foods. 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subjects | Antiinfectives and antibacterials Antimicrobial agents Biodegradability Chloride Cinnamaldehyde Food packaging Food preservation Mechanical properties Membranes Methods Molecular weight Permeability Polycaprolactone Polyethylene Polyethylene oxide Polylactic acid Polymer films Polymers Sodium Sodium chloride Solvents Transportation |
title | Design and Development of Enhanced Antimicrobial Breathable Biodegradable Polymeric Films for Food Packaging Applications |
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