Visible‐Light‐Induced Homolysis of Earth‐Abundant Metal‐Substrate Complexes: A Complementary Activation Strategy in Photoredox Catalysis

The mainstream applications of visible‐light photoredox catalysis predominately involve outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious metal RuII or IrIII complexes or of organic dyes with low photostability. Earth‐abundant metal‐based MnLn‐type (M=metal,...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-09, Vol.60 (39), p.21100-21115
Hauptverfasser:	Abderrazak, Youssef, Bhattacharyya, Aditya, Reiser, Oliver
Format:	Artikel
Sprache:	eng
Schlagworte:	3d transition metals Catalysis Coordination compounds dissociative ligand-to-metal charge transfer Electron transfer Energy transfer inner-sphere electron transfer Metals Minireview Minireviews Photocatalysis Photocatalysts Photoredox catalysis Substrates visible-light-induced homolysis
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