Global syndromes induced by changes in solutes of the world’s large rivers

Solute-induced river syndromes have grown in intensity in recent years. Here we investigate seven such river syndromes (salinization, mineralization, desalinization, acidification, alkalization, hardening, and softening) associated with global trends in major solutes (Ca 2+ , Mg 2+ , Na + , K + , SO 4 2− , Cl − , HCO 3 − ) and dissolved silica in the world’s large rivers (basin areas ≥ 1000 km 2 ). A comprehensive dataset from 600 gauge stations in 149 large rivers reveals nine binary patterns of co-varying trends in runoff and solute concentration. Solute-induced river syndromes are associated with remarkable increases in total dissolved solids (68%), chloride (81%), sodium (86%) and sulfate (142%) fluxes from rivers to oceans worldwide. The syndromes are most prevalent in temperate regions (30~50°N and 30~40°S based on the available data) where severe rock weathering and active human interferences such as urbanization and agricultural irrigation are concentrated. This study highlights the urgency to protect river health from extreme changes in solute contents. Rivers are increasingly plagued by “syndromes”, i.e. salinization, mineralization, desalinization, acidification, alkalization, hardening and softening. A global look at river biogeochemistry reveals dramatically increased flux estimates and anthropogenic drivers of syndromes.