Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane
The paper presents a comparative study of the activity of magnetite (Fe3O4) and copper and cobalt ferrites with the structure of a cubic spinel synthesized by combustion of glycine-nitrate precursors in the reactions of ammonia borane (NH3BH3) hydrolysis and hydrothermolysis. It was shown that the u...
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| Veröffentlicht in: | Materials 2021-09, Vol.14 (18), p.5422 |
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| creator | Komova, Oksana V. Simagina, Valentina I. Pochtar, Alena A. Bulavchenko, Olga A. Ishchenko, Arcady V. Odegova, Galina V. Gorlova, Anna M. Ozerova, Anna M. Lipatnikova, Inna L. Tayban, Elena S. Mukha, Svetlana A. Netskina, Olga V. |
| description | The paper presents a comparative study of the activity of magnetite (Fe3O4) and copper and cobalt ferrites with the structure of a cubic spinel synthesized by combustion of glycine-nitrate precursors in the reactions of ammonia borane (NH3BH3) hydrolysis and hydrothermolysis. It was shown that the use of copper ferrite in the studied reactions of NH3BH3 dehydrogenation has the advantages of a high catalytic activity and the absence of an induction period in the H2 generation curve due to the activating action of copper on the reduction of iron. Two methods have been proposed to improve catalytic activity of Fe3O4-based systems: (1) replacement of a portion of Fe2+ cations in the spinel by active cations including Cu2+ and (2) preparation of highly dispersed multiphase oxide systems, involving oxide of copper. |
| doi_str_mv | 10.3390/ma14185422 |
| format | Article |
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It was shown that the use of copper ferrite in the studied reactions of NH3BH3 dehydrogenation has the advantages of a high catalytic activity and the absence of an induction period in the H2 generation curve due to the activating action of copper on the reduction of iron. Two methods have been proposed to improve catalytic activity of Fe3O4-based systems: (1) replacement of a portion of Fe2+ cations in the spinel by active cations including Cu2+ and (2) preparation of highly dispersed multiphase oxide systems, involving oxide of copper.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14185422</identifier><identifier>PMID: 34576646</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Ammonia ; Boranes ; Catalytic activity ; Cations ; Cobalt ; Cobalt ferrites ; Comparative studies ; Copper ferrite ; Dehydrogenation ; Glycine ; Hydrogen ; Hydrogen production ; Hydrolysis ; Iron oxides ; Metals ; Spinel</subject><ispartof>Materials, 2021-09, Vol.14 (18), p.5422</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-634d72c4cf94450ec80f264f97e7247f5b2e5d892cf2b5731f709401e87e18073</citedby><cites>FETCH-LOGICAL-c383t-634d72c4cf94450ec80f264f97e7247f5b2e5d892cf2b5731f709401e87e18073</cites><orcidid>0000-0001-7607-2025 ; 0000-0002-9478-1236 ; 0000-0002-4747-6714 ; 0000-0002-4071-2016 ; 0000-0002-2323-7372</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8468860/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8468860/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids></links><search><creatorcontrib>Komova, Oksana V.</creatorcontrib><creatorcontrib>Simagina, Valentina I.</creatorcontrib><creatorcontrib>Pochtar, Alena A.</creatorcontrib><creatorcontrib>Bulavchenko, Olga A.</creatorcontrib><creatorcontrib>Ishchenko, Arcady V.</creatorcontrib><creatorcontrib>Odegova, Galina V.</creatorcontrib><creatorcontrib>Gorlova, Anna M.</creatorcontrib><creatorcontrib>Ozerova, Anna M.</creatorcontrib><creatorcontrib>Lipatnikova, Inna L.</creatorcontrib><creatorcontrib>Tayban, Elena S.</creatorcontrib><creatorcontrib>Mukha, Svetlana A.</creatorcontrib><creatorcontrib>Netskina, Olga V.</creatorcontrib><title>Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane</title><title>Materials</title><description>The paper presents a comparative study of the activity of magnetite (Fe3O4) and copper and cobalt ferrites with the structure of a cubic spinel synthesized by combustion of glycine-nitrate precursors in the reactions of ammonia borane (NH3BH3) hydrolysis and hydrothermolysis. 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Two methods have been proposed to improve catalytic activity of Fe3O4-based systems: (1) replacement of a portion of Fe2+ cations in the spinel by active cations including Cu2+ and (2) preparation of highly dispersed multiphase oxide systems, involving oxide of copper.</description><subject>Ammonia</subject><subject>Boranes</subject><subject>Catalytic activity</subject><subject>Cations</subject><subject>Cobalt</subject><subject>Cobalt ferrites</subject><subject>Comparative studies</subject><subject>Copper ferrite</subject><subject>Dehydrogenation</subject><subject>Glycine</subject><subject>Hydrogen</subject><subject>Hydrogen production</subject><subject>Hydrolysis</subject><subject>Iron oxides</subject><subject>Metals</subject><subject>Spinel</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkUlLxDAUx4MoKurFTxDwIkI1W5vkImhxA8GDeg6ZNHGibTImrTDf3sgMbu_yth9_3gLAIUanlEp0NmjMsKgZIRtgF0vZVFgytvkr3gEHOb-iYpRiQeQ22KGs5k3Dml3w1upR98vRG3hp5_rDxwSjg3cphqqNYdQ--PAC22lWiMeFD7aHPsBxbuHtskuxX2afoQ7dKi31NKyLReZiGGLwGl7GpIPdB1tO99kerP0eeL6-empvq_uHm7v24r4yVNCxaijrODHMuDJ8jawRyJGGOcktJ4y7ekZs3QlJjCOzmlPsOJIMYSu4xQJxugfOV7qLaTbYztgwJt2rRfKDTksVtVd_O8HP1Uv8UII1QjSoCByvBVJ8n2we1eCzsX1flohTVqTmnDHJMSno0T_0NU4plPW-qHJiSgkt1MmKMinmnKz7HgYj9fVG9fNG-gnRro4k</recordid><startdate>20210919</startdate><enddate>20210919</enddate><creator>Komova, Oksana V.</creator><creator>Simagina, Valentina I.</creator><creator>Pochtar, Alena A.</creator><creator>Bulavchenko, Olga A.</creator><creator>Ishchenko, Arcady V.</creator><creator>Odegova, Galina V.</creator><creator>Gorlova, Anna M.</creator><creator>Ozerova, Anna M.</creator><creator>Lipatnikova, Inna L.</creator><creator>Tayban, Elena S.</creator><creator>Mukha, Svetlana A.</creator><creator>Netskina, Olga V.</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-7607-2025</orcidid><orcidid>https://orcid.org/0000-0002-9478-1236</orcidid><orcidid>https://orcid.org/0000-0002-4747-6714</orcidid><orcidid>https://orcid.org/0000-0002-4071-2016</orcidid><orcidid>https://orcid.org/0000-0002-2323-7372</orcidid></search><sort><creationdate>20210919</creationdate><title>Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane</title><author>Komova, Oksana V. ; Simagina, Valentina I. ; Pochtar, Alena A. ; Bulavchenko, Olga A. ; Ishchenko, Arcady V. ; Odegova, Galina V. ; Gorlova, Anna M. ; Ozerova, Anna M. ; Lipatnikova, Inna L. ; Tayban, Elena S. ; Mukha, Svetlana A. ; Netskina, Olga V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-634d72c4cf94450ec80f264f97e7247f5b2e5d892cf2b5731f709401e87e18073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Ammonia</topic><topic>Boranes</topic><topic>Catalytic activity</topic><topic>Cations</topic><topic>Cobalt</topic><topic>Cobalt ferrites</topic><topic>Comparative studies</topic><topic>Copper ferrite</topic><topic>Dehydrogenation</topic><topic>Glycine</topic><topic>Hydrogen</topic><topic>Hydrogen production</topic><topic>Hydrolysis</topic><topic>Iron oxides</topic><topic>Metals</topic><topic>Spinel</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Komova, Oksana V.</creatorcontrib><creatorcontrib>Simagina, Valentina I.</creatorcontrib><creatorcontrib>Pochtar, Alena A.</creatorcontrib><creatorcontrib>Bulavchenko, Olga A.</creatorcontrib><creatorcontrib>Ishchenko, Arcady V.</creatorcontrib><creatorcontrib>Odegova, Galina V.</creatorcontrib><creatorcontrib>Gorlova, Anna M.</creatorcontrib><creatorcontrib>Ozerova, Anna M.</creatorcontrib><creatorcontrib>Lipatnikova, Inna L.</creatorcontrib><creatorcontrib>Tayban, Elena S.</creatorcontrib><creatorcontrib>Mukha, Svetlana A.</creatorcontrib><creatorcontrib>Netskina, Olga V.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Komova, Oksana V.</au><au>Simagina, Valentina I.</au><au>Pochtar, Alena A.</au><au>Bulavchenko, Olga A.</au><au>Ishchenko, Arcady V.</au><au>Odegova, Galina V.</au><au>Gorlova, Anna M.</au><au>Ozerova, Anna M.</au><au>Lipatnikova, Inna L.</au><au>Tayban, Elena S.</au><au>Mukha, Svetlana A.</au><au>Netskina, Olga V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane</atitle><jtitle>Materials</jtitle><date>2021-09-19</date><risdate>2021</risdate><volume>14</volume><issue>18</issue><spage>5422</spage><pages>5422-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>The paper presents a comparative study of the activity of magnetite (Fe3O4) and copper and cobalt ferrites with the structure of a cubic spinel synthesized by combustion of glycine-nitrate precursors in the reactions of ammonia borane (NH3BH3) hydrolysis and hydrothermolysis. It was shown that the use of copper ferrite in the studied reactions of NH3BH3 dehydrogenation has the advantages of a high catalytic activity and the absence of an induction period in the H2 generation curve due to the activating action of copper on the reduction of iron. Two methods have been proposed to improve catalytic activity of Fe3O4-based systems: (1) replacement of a portion of Fe2+ cations in the spinel by active cations including Cu2+ and (2) preparation of highly dispersed multiphase oxide systems, involving oxide of copper.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>34576646</pmid><doi>10.3390/ma14185422</doi><orcidid>https://orcid.org/0000-0001-7607-2025</orcidid><orcidid>https://orcid.org/0000-0002-9478-1236</orcidid><orcidid>https://orcid.org/0000-0002-4747-6714</orcidid><orcidid>https://orcid.org/0000-0002-4071-2016</orcidid><orcidid>https://orcid.org/0000-0002-2323-7372</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Ammonia Boranes Catalytic activity Cations Cobalt Cobalt ferrites Comparative studies Copper ferrite Dehydrogenation Glycine Hydrogen Hydrogen production Hydrolysis Iron oxides Metals Spinel |
| title | Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane |
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