Iron-Catalyzed Contrasteric Functionalization of Allenic C(sp2)–H Bonds: Synthesis of α‑Aminoalkyl 1,1-Disubstituted Allenes

An iron-catalyzed C–H functionalization of simple monosubstituted allenes is reported. An efficient protocol for this process was made possible by the use of a newly developed electron-rich and sterically hindered cationic cyclopentadienyliron dicarbonyl complex as the catalyst and N-sulfonyl hemiam...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-09, Vol.143 (37), p.14998-15004
Hauptverfasser:	Wang, Yidong, Scrivener, Sarah G, Zuo, Xiao-Dong, Wang, Ruihan, Palermo, Philip N, Murphy, Ethan, Durham, Austin C, Wang, Yi-Ming
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkadienes - chemical synthesis Alkadienes - chemistry Catalysis Hydrocarbons - chemical synthesis Hydrocarbons - chemistry Hydrogen Bonding Iron - chemistry Models, Molecular Molecular Structure
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