Post‐Synthetic Modification Unlocks a 2D‐to‐3D Switch in MOF Breathing Response: A Single‐Crystal‐Diffraction Mapping Study

Post‐synthetic modification (PSM) of the interpenetrated diamondoid metal–organic framework (Me2NH2)[In(BDC‐NH2)2] (BDC‐NH2=aminobenzenedicarboxylate) SHF‐61 proceeds quantitatively in a single‐crystal‐to‐single‐crystal manner to yield the acetamide derivative (Me2NH2)[In(BDC‐NHC(O)Me)2] SHF‐62. Con...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-08, Vol.60 (33), p.17920-17924
Hauptverfasser:	Carrington, Elliot J., Dodsworth, Stephen F., Meurs, Sandra, Warren, Mark R., Brammer, Lee
Format:	Artikel
Sprache:	eng
Schlagworte:	anisotropy breathing mode Communication Communications Crystals Decoupling Diameters Diamonds Diffraction Metal-organic frameworks post-synthetic modification single crystals Superhigh frequencies Three dimensional motion
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