Corrosion Inhibition of Mild Steel and 304 Stainless Steel in 1 M Hydrochloric Acid Solution by Tea Tree Extract and Its Main Constituents
Tea tree extract, containing antioxidant constituents α-terpineol, terpinen-4-ol, and α-terpinene, has a wide range of applications in the cosmetic, food, and pharmaceutical industries. In this study, tea tree extract showed an anticorrosive effect under 1 M HCl solution on mild steel (MS) and 304 s...
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| description | Tea tree extract, containing antioxidant constituents α-terpineol, terpinen-4-ol, and α-terpinene, has a wide range of applications in the cosmetic, food, and pharmaceutical industries. In this study, tea tree extract showed an anticorrosive effect under 1 M HCl solution on mild steel (MS) and 304 stainless steel (STS). Uniform corrosion for MS and pitting corrosion for STS at 298 K were retarded, with inhibition efficiencies of 77% and 86%, respectively. The inhibition of uniform and pitting corrosion was confirmed by scanning electron microscopy and laser scanning confocal microscopy in terms of surface roughness and pitting morphologies. The most effective constituent contributing to the inhibitory performance of tea tree extract was revealed to be α-terpineol, with an inhibition efficiency of 83%. The adsorption of tea tree extract was confirmed by surface characterization analysis using Fourier transform infrared spectroscopy, Raman spectroscopy, and Electrochemical impedance spectroscopy. Interestingly, G- and D-peaks of Raman spectra were detected from the inhibited steels, and this finding is the first example in the corrosion inhibition field. The anticorrosion mechanism can be explained by the formation of organic-Fe complexes on the corroded steel surface via electron donor and acceptor interactions in the presence of an oxygen atom of the hydroxyl group or ether of organic inhibitors. |
| doi_str_mv | 10.3390/ma14175016 |
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In this study, tea tree extract showed an anticorrosive effect under 1 M HCl solution on mild steel (MS) and 304 stainless steel (STS). Uniform corrosion for MS and pitting corrosion for STS at 298 K were retarded, with inhibition efficiencies of 77% and 86%, respectively. The inhibition of uniform and pitting corrosion was confirmed by scanning electron microscopy and laser scanning confocal microscopy in terms of surface roughness and pitting morphologies. The most effective constituent contributing to the inhibitory performance of tea tree extract was revealed to be α-terpineol, with an inhibition efficiency of 83%. The adsorption of tea tree extract was confirmed by surface characterization analysis using Fourier transform infrared spectroscopy, Raman spectroscopy, and Electrochemical impedance spectroscopy. Interestingly, G- and D-peaks of Raman spectra were detected from the inhibited steels, and this finding is the first example in the corrosion inhibition field. The anticorrosion mechanism can be explained by the formation of organic-Fe complexes on the corroded steel surface via electron donor and acceptor interactions in the presence of an oxygen atom of the hydroxyl group or ether of organic inhibitors.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14175016</identifier><identifier>PMID: 34501108</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Antioxidants ; Austenitic stainless steels ; Chromatography ; Constituents ; Corrosion ; Corrosion inhibitors ; Corrosion mechanisms ; Corrosion prevention ; Efficiency ; Electrochemical impedance spectroscopy ; Electrodes ; Electrolytes ; Fourier transforms ; Hydrochloric acid ; Hydroxyl groups ; Infrared analysis ; Infrared spectroscopy ; Lasers ; Low carbon steels ; Mass spectrometry ; Microscopy ; Morphology ; Phytochemicals ; Pitting (corrosion) ; Raman spectra ; Raman spectroscopy ; Scientific imaging ; Stainless steel ; Sulfur ; Surface properties ; Surface roughness ; Terpineol ; Trees ; Uniform attack (corrosion)</subject><ispartof>Materials, 2021-09, Vol.14 (17), p.5016</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-bf0531b524a1806ca8545b68ea78b6d63ce0a5f1291010f5e3d9c06e8907b4a3</citedby><cites>FETCH-LOGICAL-c406t-bf0531b524a1806ca8545b68ea78b6d63ce0a5f1291010f5e3d9c06e8907b4a3</cites><orcidid>0000-0002-8165-6276</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433979/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433979/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34501108$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Jae-Yeon</creatorcontrib><creatorcontrib>Shin, Inji</creatorcontrib><creatorcontrib>Byeon, Jai-Won</creatorcontrib><title>Corrosion Inhibition of Mild Steel and 304 Stainless Steel in 1 M Hydrochloric Acid Solution by Tea Tree Extract and Its Main Constituents</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>Tea tree extract, containing antioxidant constituents α-terpineol, terpinen-4-ol, and α-terpinene, has a wide range of applications in the cosmetic, food, and pharmaceutical industries. In this study, tea tree extract showed an anticorrosive effect under 1 M HCl solution on mild steel (MS) and 304 stainless steel (STS). Uniform corrosion for MS and pitting corrosion for STS at 298 K were retarded, with inhibition efficiencies of 77% and 86%, respectively. The inhibition of uniform and pitting corrosion was confirmed by scanning electron microscopy and laser scanning confocal microscopy in terms of surface roughness and pitting morphologies. The most effective constituent contributing to the inhibitory performance of tea tree extract was revealed to be α-terpineol, with an inhibition efficiency of 83%. The adsorption of tea tree extract was confirmed by surface characterization analysis using Fourier transform infrared spectroscopy, Raman spectroscopy, and Electrochemical impedance spectroscopy. Interestingly, G- and D-peaks of Raman spectra were detected from the inhibited steels, and this finding is the first example in the corrosion inhibition field. The anticorrosion mechanism can be explained by the formation of organic-Fe complexes on the corroded steel surface via electron donor and acceptor interactions in the presence of an oxygen atom of the hydroxyl group or ether of organic inhibitors.</description><subject>Antioxidants</subject><subject>Austenitic stainless steels</subject><subject>Chromatography</subject><subject>Constituents</subject><subject>Corrosion</subject><subject>Corrosion inhibitors</subject><subject>Corrosion mechanisms</subject><subject>Corrosion prevention</subject><subject>Efficiency</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Fourier transforms</subject><subject>Hydrochloric acid</subject><subject>Hydroxyl groups</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Lasers</subject><subject>Low carbon steels</subject><subject>Mass spectrometry</subject><subject>Microscopy</subject><subject>Morphology</subject><subject>Phytochemicals</subject><subject>Pitting (corrosion)</subject><subject>Raman spectra</subject><subject>Raman spectroscopy</subject><subject>Scientific imaging</subject><subject>Stainless steel</subject><subject>Sulfur</subject><subject>Surface properties</subject><subject>Surface roughness</subject><subject>Terpineol</subject><subject>Trees</subject><subject>Uniform attack (corrosion)</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkUFvFCEUgInR2Kb24g8wJF6MySpvgJnhYtJsqt2kGw_unTDMG5eGhQpM4_4Ff7V0u9YqFx7wvY8Hj5DXwD5wrtjHnQEBnWTQPiOnoFS7ACXE8yfxCTnP-YbVwTn0jXpJTrioCcD6U_JrGVOK2cVAV2HrBlfuwzjRtfMj_VYQPTVhpJyJujIueMz5uO8CBbqmV_sxRbv1MTlLL6yradHPB8-wpxs0dJMQ6eXPkowtB9uqZLquMrqMIRdXZgwlvyIvJuMznh_nM7L5fLlZXi2uv35ZLS-uF1awtiyGiUkOg2yEgZ611vRSyKHt0XT90I4tt8iMnKBRwIBNEvmoLGuxV6wbhOFn5NOD9nYedjjaenUyXt8mtzNpr6Nx-t-T4Lb6e7zTvagf3qkqeHcUpPhjxlz0zmWL3puAcc66kR2opmm6rqJv_0Nv4pxCfd2BqjqQvFLvHyhbO5ETTo_FANP3TdZ_m1zhN0_Lf0T_tJT_Bt4xoUg</recordid><startdate>20210902</startdate><enddate>20210902</enddate><creator>Kim, Jae-Yeon</creator><creator>Shin, Inji</creator><creator>Byeon, Jai-Won</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-8165-6276</orcidid></search><sort><creationdate>20210902</creationdate><title>Corrosion Inhibition of Mild Steel and 304 Stainless Steel in 1 M Hydrochloric Acid Solution by Tea Tree Extract and Its Main Constituents</title><author>Kim, Jae-Yeon ; Shin, Inji ; Byeon, Jai-Won</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-bf0531b524a1806ca8545b68ea78b6d63ce0a5f1291010f5e3d9c06e8907b4a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Antioxidants</topic><topic>Austenitic stainless steels</topic><topic>Chromatography</topic><topic>Constituents</topic><topic>Corrosion</topic><topic>Corrosion inhibitors</topic><topic>Corrosion mechanisms</topic><topic>Corrosion prevention</topic><topic>Efficiency</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Fourier transforms</topic><topic>Hydrochloric acid</topic><topic>Hydroxyl groups</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Lasers</topic><topic>Low carbon steels</topic><topic>Mass spectrometry</topic><topic>Microscopy</topic><topic>Morphology</topic><topic>Phytochemicals</topic><topic>Pitting (corrosion)</topic><topic>Raman spectra</topic><topic>Raman spectroscopy</topic><topic>Scientific imaging</topic><topic>Stainless steel</topic><topic>Sulfur</topic><topic>Surface properties</topic><topic>Surface roughness</topic><topic>Terpineol</topic><topic>Trees</topic><topic>Uniform attack (corrosion)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Jae-Yeon</creatorcontrib><creatorcontrib>Shin, Inji</creatorcontrib><creatorcontrib>Byeon, Jai-Won</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Jae-Yeon</au><au>Shin, Inji</au><au>Byeon, Jai-Won</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrosion Inhibition of Mild Steel and 304 Stainless Steel in 1 M Hydrochloric Acid Solution by Tea Tree Extract and Its Main Constituents</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2021-09-02</date><risdate>2021</risdate><volume>14</volume><issue>17</issue><spage>5016</spage><pages>5016-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>Tea tree extract, containing antioxidant constituents α-terpineol, terpinen-4-ol, and α-terpinene, has a wide range of applications in the cosmetic, food, and pharmaceutical industries. In this study, tea tree extract showed an anticorrosive effect under 1 M HCl solution on mild steel (MS) and 304 stainless steel (STS). Uniform corrosion for MS and pitting corrosion for STS at 298 K were retarded, with inhibition efficiencies of 77% and 86%, respectively. The inhibition of uniform and pitting corrosion was confirmed by scanning electron microscopy and laser scanning confocal microscopy in terms of surface roughness and pitting morphologies. The most effective constituent contributing to the inhibitory performance of tea tree extract was revealed to be α-terpineol, with an inhibition efficiency of 83%. The adsorption of tea tree extract was confirmed by surface characterization analysis using Fourier transform infrared spectroscopy, Raman spectroscopy, and Electrochemical impedance spectroscopy. Interestingly, G- and D-peaks of Raman spectra were detected from the inhibited steels, and this finding is the first example in the corrosion inhibition field. The anticorrosion mechanism can be explained by the formation of organic-Fe complexes on the corroded steel surface via electron donor and acceptor interactions in the presence of an oxygen atom of the hydroxyl group or ether of organic inhibitors.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>34501108</pmid><doi>10.3390/ma14175016</doi><orcidid>https://orcid.org/0000-0002-8165-6276</orcidid><oa>free_for_read</oa></addata></record> |
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| source | PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | Antioxidants Austenitic stainless steels Chromatography Constituents Corrosion Corrosion inhibitors Corrosion mechanisms Corrosion prevention Efficiency Electrochemical impedance spectroscopy Electrodes Electrolytes Fourier transforms Hydrochloric acid Hydroxyl groups Infrared analysis Infrared spectroscopy Lasers Low carbon steels Mass spectrometry Microscopy Morphology Phytochemicals Pitting (corrosion) Raman spectra Raman spectroscopy Scientific imaging Stainless steel Sulfur Surface properties Surface roughness Terpineol Trees Uniform attack (corrosion) |
| title | Corrosion Inhibition of Mild Steel and 304 Stainless Steel in 1 M Hydrochloric Acid Solution by Tea Tree Extract and Its Main Constituents |
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