From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions
Glass-ceramics with the composition B2O3-Bi2O3-SrF2 were synthesized by the conventional melt-quenching technique and subsequent crystallization of the parental glasses. The temperature at which the ceramization was carried out was selected based on differential scanning calorimetry (DSC) analysis....
Gespeichert in:
| Veröffentlicht in: | Materials 2021-08, Vol.14 (16), p.4490 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 16 |
| container_start_page | 4490 |
| container_title | Materials |
| container_volume | 14 |
| creator | Milewska, Karolina Maciejewski, Michał Synak, Anna Łapiński, Marcin Mielewczyk-Gryń, Aleksandra Sadowski, Wojciech Kościelska, Barbara |
| description | Glass-ceramics with the composition B2O3-Bi2O3-SrF2 were synthesized by the conventional melt-quenching technique and subsequent crystallization of the parental glasses. The temperature at which the ceramization was carried out was selected based on differential scanning calorimetry (DSC) analysis. The structure of the studied materials and the formation of SrF2 nanocrystals were confirmed by the Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques. It was found that the amount of strontium fluoride introduced into the parental borate-bismuth glass has a significant impact on the growth of SrF2 nanocrystals. In particular, the influence of the crystalline SrF2 phase on luminescence intensity and kinetics was studied using Eu2O3-doped samples. An increase in luminescence intensity was observed in the samples in which SrF2 nanocrystals were formed. This is most likely related to the fact that some of the Eu3+ ions were (after annealing of the glass) located in the crystalline structure of strontium fluoride. This was confirmed both by the luminescence lifetime obtained based on the luminescence decay curves and the calculated Judd–Ofelt parameters, Ω2 and Ω4. The results achieved confirm that the glasses and glass-ceramics described in this work could be considered as a new phosphor for light-emitting diodes (LEDs). |
| doi_str_mv | 10.3390/ma14164490 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8401422</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2565372204</sourcerecordid><originalsourceid>FETCH-LOGICAL-c313t-2315ed496351db1cac99de89f4dfcfbe2cc12f69f9011c3e46d2c6d897f2dc693</originalsourceid><addsrcrecordid>eNpdUdtKAzEQDaJYUV_8goAvoqwmmTRtXgStVoWCgvoc0lxsZHdTk13Fv3eXFm_zMHNgzpy5IXRAySmAJGeVppwKziXZQDtUSlFQyfnmLzxA-zm_ks4A6JjJbTQAzjkQCjsoTFOs8GOTWtO0yeEm4llbhdpl4-oGP6S4dKkJLuPo8SW7h-Iy9P4xTRm-KXXOWNd2hYqJS7oKJuOrrsrij9As8HULJ_gu1nkPbXldZre_jrvoeXr9NLktZvc3d5OLWWGAQlMwoENnuRQwpHZOjTZSWjeWnltv_NwxYyjzQnpJKDXguLDMCDuWI8-sERJ20flKd9nOK2f7NZIu1TKFSqdPFXVQfzN1WKiX-K7GnFDOWCdwtBZI8a11uVFV6K5Rlrp2sc2KDYUgQED2vQ7_UV9jm-puvZ41hBFjhHes4xXLpJhzcv57GEpU_0T180T4Al4AjCw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2565372204</pqid></control><display><type>article</type><title>From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Milewska, Karolina ; Maciejewski, Michał ; Synak, Anna ; Łapiński, Marcin ; Mielewczyk-Gryń, Aleksandra ; Sadowski, Wojciech ; Kościelska, Barbara</creator><creatorcontrib>Milewska, Karolina ; Maciejewski, Michał ; Synak, Anna ; Łapiński, Marcin ; Mielewczyk-Gryń, Aleksandra ; Sadowski, Wojciech ; Kościelska, Barbara</creatorcontrib><description>Glass-ceramics with the composition B2O3-Bi2O3-SrF2 were synthesized by the conventional melt-quenching technique and subsequent crystallization of the parental glasses. The temperature at which the ceramization was carried out was selected based on differential scanning calorimetry (DSC) analysis. The structure of the studied materials and the formation of SrF2 nanocrystals were confirmed by the Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques. It was found that the amount of strontium fluoride introduced into the parental borate-bismuth glass has a significant impact on the growth of SrF2 nanocrystals. In particular, the influence of the crystalline SrF2 phase on luminescence intensity and kinetics was studied using Eu2O3-doped samples. An increase in luminescence intensity was observed in the samples in which SrF2 nanocrystals were formed. This is most likely related to the fact that some of the Eu3+ ions were (after annealing of the glass) located in the crystalline structure of strontium fluoride. This was confirmed both by the luminescence lifetime obtained based on the luminescence decay curves and the calculated Judd–Ofelt parameters, Ω2 and Ω4. The results achieved confirm that the glasses and glass-ceramics described in this work could be considered as a new phosphor for light-emitting diodes (LEDs).</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14164490</identifier><identifier>PMID: 34443013</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Annealing ; Bismuth oxides ; Bismuth trioxide ; Boron ; Boron oxides ; Crystal structure ; Crystallinity ; Crystallization ; Europium ; Europium compounds ; Fluorides ; Fourier transforms ; Glass ceramics ; Infrared spectroscopy ; Light emitting diodes ; Luminescence ; Nanocrystals ; Optical properties ; Optics ; Phosphors ; Photoelectrons ; Spectrum analysis ; Strontium ; Strontium fluorides ; Temperature ; X ray photoelectron spectroscopy</subject><ispartof>Materials, 2021-08, Vol.14 (16), p.4490</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c313t-2315ed496351db1cac99de89f4dfcfbe2cc12f69f9011c3e46d2c6d897f2dc693</citedby><cites>FETCH-LOGICAL-c313t-2315ed496351db1cac99de89f4dfcfbe2cc12f69f9011c3e46d2c6d897f2dc693</cites><orcidid>0000-0001-8264-7833 ; 0000-0001-6795-3840 ; 0000-0003-0676-5082 ; 0000-0001-7087-8677 ; 0000-0002-3283-2886 ; 0000-0002-9352-9581</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8401422/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8401422/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids></links><search><creatorcontrib>Milewska, Karolina</creatorcontrib><creatorcontrib>Maciejewski, Michał</creatorcontrib><creatorcontrib>Synak, Anna</creatorcontrib><creatorcontrib>Łapiński, Marcin</creatorcontrib><creatorcontrib>Mielewczyk-Gryń, Aleksandra</creatorcontrib><creatorcontrib>Sadowski, Wojciech</creatorcontrib><creatorcontrib>Kościelska, Barbara</creatorcontrib><title>From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions</title><title>Materials</title><description>Glass-ceramics with the composition B2O3-Bi2O3-SrF2 were synthesized by the conventional melt-quenching technique and subsequent crystallization of the parental glasses. The temperature at which the ceramization was carried out was selected based on differential scanning calorimetry (DSC) analysis. The structure of the studied materials and the formation of SrF2 nanocrystals were confirmed by the Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques. It was found that the amount of strontium fluoride introduced into the parental borate-bismuth glass has a significant impact on the growth of SrF2 nanocrystals. In particular, the influence of the crystalline SrF2 phase on luminescence intensity and kinetics was studied using Eu2O3-doped samples. An increase in luminescence intensity was observed in the samples in which SrF2 nanocrystals were formed. This is most likely related to the fact that some of the Eu3+ ions were (after annealing of the glass) located in the crystalline structure of strontium fluoride. This was confirmed both by the luminescence lifetime obtained based on the luminescence decay curves and the calculated Judd–Ofelt parameters, Ω2 and Ω4. The results achieved confirm that the glasses and glass-ceramics described in this work could be considered as a new phosphor for light-emitting diodes (LEDs).</description><subject>Annealing</subject><subject>Bismuth oxides</subject><subject>Bismuth trioxide</subject><subject>Boron</subject><subject>Boron oxides</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Crystallization</subject><subject>Europium</subject><subject>Europium compounds</subject><subject>Fluorides</subject><subject>Fourier transforms</subject><subject>Glass ceramics</subject><subject>Infrared spectroscopy</subject><subject>Light emitting diodes</subject><subject>Luminescence</subject><subject>Nanocrystals</subject><subject>Optical properties</subject><subject>Optics</subject><subject>Phosphors</subject><subject>Photoelectrons</subject><subject>Spectrum analysis</subject><subject>Strontium</subject><subject>Strontium fluorides</subject><subject>Temperature</subject><subject>X ray photoelectron spectroscopy</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdUdtKAzEQDaJYUV_8goAvoqwmmTRtXgStVoWCgvoc0lxsZHdTk13Fv3eXFm_zMHNgzpy5IXRAySmAJGeVppwKziXZQDtUSlFQyfnmLzxA-zm_ks4A6JjJbTQAzjkQCjsoTFOs8GOTWtO0yeEm4llbhdpl4-oGP6S4dKkJLuPo8SW7h-Iy9P4xTRm-KXXOWNd2hYqJS7oKJuOrrsrij9As8HULJ_gu1nkPbXldZre_jrvoeXr9NLktZvc3d5OLWWGAQlMwoENnuRQwpHZOjTZSWjeWnltv_NwxYyjzQnpJKDXguLDMCDuWI8-sERJ20flKd9nOK2f7NZIu1TKFSqdPFXVQfzN1WKiX-K7GnFDOWCdwtBZI8a11uVFV6K5Rlrp2sc2KDYUgQED2vQ7_UV9jm-puvZ41hBFjhHes4xXLpJhzcv57GEpU_0T180T4Al4AjCw</recordid><startdate>20210810</startdate><enddate>20210810</enddate><creator>Milewska, Karolina</creator><creator>Maciejewski, Michał</creator><creator>Synak, Anna</creator><creator>Łapiński, Marcin</creator><creator>Mielewczyk-Gryń, Aleksandra</creator><creator>Sadowski, Wojciech</creator><creator>Kościelska, Barbara</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-8264-7833</orcidid><orcidid>https://orcid.org/0000-0001-6795-3840</orcidid><orcidid>https://orcid.org/0000-0003-0676-5082</orcidid><orcidid>https://orcid.org/0000-0001-7087-8677</orcidid><orcidid>https://orcid.org/0000-0002-3283-2886</orcidid><orcidid>https://orcid.org/0000-0002-9352-9581</orcidid></search><sort><creationdate>20210810</creationdate><title>From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions</title><author>Milewska, Karolina ; Maciejewski, Michał ; Synak, Anna ; Łapiński, Marcin ; Mielewczyk-Gryń, Aleksandra ; Sadowski, Wojciech ; Kościelska, Barbara</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c313t-2315ed496351db1cac99de89f4dfcfbe2cc12f69f9011c3e46d2c6d897f2dc693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Annealing</topic><topic>Bismuth oxides</topic><topic>Bismuth trioxide</topic><topic>Boron</topic><topic>Boron oxides</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Crystallization</topic><topic>Europium</topic><topic>Europium compounds</topic><topic>Fluorides</topic><topic>Fourier transforms</topic><topic>Glass ceramics</topic><topic>Infrared spectroscopy</topic><topic>Light emitting diodes</topic><topic>Luminescence</topic><topic>Nanocrystals</topic><topic>Optical properties</topic><topic>Optics</topic><topic>Phosphors</topic><topic>Photoelectrons</topic><topic>Spectrum analysis</topic><topic>Strontium</topic><topic>Strontium fluorides</topic><topic>Temperature</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Milewska, Karolina</creatorcontrib><creatorcontrib>Maciejewski, Michał</creatorcontrib><creatorcontrib>Synak, Anna</creatorcontrib><creatorcontrib>Łapiński, Marcin</creatorcontrib><creatorcontrib>Mielewczyk-Gryń, Aleksandra</creatorcontrib><creatorcontrib>Sadowski, Wojciech</creatorcontrib><creatorcontrib>Kościelska, Barbara</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Milewska, Karolina</au><au>Maciejewski, Michał</au><au>Synak, Anna</au><au>Łapiński, Marcin</au><au>Mielewczyk-Gryń, Aleksandra</au><au>Sadowski, Wojciech</au><au>Kościelska, Barbara</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions</atitle><jtitle>Materials</jtitle><date>2021-08-10</date><risdate>2021</risdate><volume>14</volume><issue>16</issue><spage>4490</spage><pages>4490-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>Glass-ceramics with the composition B2O3-Bi2O3-SrF2 were synthesized by the conventional melt-quenching technique and subsequent crystallization of the parental glasses. The temperature at which the ceramization was carried out was selected based on differential scanning calorimetry (DSC) analysis. The structure of the studied materials and the formation of SrF2 nanocrystals were confirmed by the Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques. It was found that the amount of strontium fluoride introduced into the parental borate-bismuth glass has a significant impact on the growth of SrF2 nanocrystals. In particular, the influence of the crystalline SrF2 phase on luminescence intensity and kinetics was studied using Eu2O3-doped samples. An increase in luminescence intensity was observed in the samples in which SrF2 nanocrystals were formed. This is most likely related to the fact that some of the Eu3+ ions were (after annealing of the glass) located in the crystalline structure of strontium fluoride. This was confirmed both by the luminescence lifetime obtained based on the luminescence decay curves and the calculated Judd–Ofelt parameters, Ω2 and Ω4. The results achieved confirm that the glasses and glass-ceramics described in this work could be considered as a new phosphor for light-emitting diodes (LEDs).</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>34443013</pmid><doi>10.3390/ma14164490</doi><orcidid>https://orcid.org/0000-0001-8264-7833</orcidid><orcidid>https://orcid.org/0000-0001-6795-3840</orcidid><orcidid>https://orcid.org/0000-0003-0676-5082</orcidid><orcidid>https://orcid.org/0000-0001-7087-8677</orcidid><orcidid>https://orcid.org/0000-0002-3283-2886</orcidid><orcidid>https://orcid.org/0000-0002-9352-9581</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1996-1944 |
| ispartof | Materials, 2021-08, Vol.14 (16), p.4490 |
| issn | 1996-1944 1996-1944 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8401422 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Annealing Bismuth oxides Bismuth trioxide Boron Boron oxides Crystal structure Crystallinity Crystallization Europium Europium compounds Fluorides Fourier transforms Glass ceramics Infrared spectroscopy Light emitting diodes Luminescence Nanocrystals Optical properties Optics Phosphors Photoelectrons Spectrum analysis Strontium Strontium fluorides Temperature X ray photoelectron spectroscopy |
| title | From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T01%3A18%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=From%20Structure%20to%20Luminescent%20Properties%20of%20B2O3-Bi2O3-SrF2%20Glass%20and%20Glass-Ceramics%20Doped%20with%20Eu3+%20Ions&rft.jtitle=Materials&rft.au=Milewska,%20Karolina&rft.date=2021-08-10&rft.volume=14&rft.issue=16&rft.spage=4490&rft.pages=4490-&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/10.3390/ma14164490&rft_dat=%3Cproquest_pubme%3E2565372204%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2565372204&rft_id=info:pmid/34443013&rfr_iscdi=true |