Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation

Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation

The selectivity of 4-(Decyloxy) benzoic acid (DBA) liquid crystal in surface adsorption region (303.2–328.2 K) and thermodynamic region (423.2 – 433.2 K) was investigated by inverse gas chromatography at infinite dilution (IGC-ID). The selectivity parameters of the structural isomer series named but...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Turkish journal of chemistry 2021-01, Vol.45 (3), p.845-857
Hauptverfasser: IŞIK, Birol, ÇAKAR, Fatih, CANKURTARAN, Hüsnü, CANKURTARAN, Özlem
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 857
container_issue 3
container_start_page 845
container_title Turkish journal of chemistry
container_volume 45
creator IŞIK, Birol
ÇAKAR, Fatih
CANKURTARAN, Hüsnü
CANKURTARAN, Özlem
description The selectivity of 4-(Decyloxy) benzoic acid (DBA) liquid crystal in surface adsorption region (303.2–328.2 K) and thermodynamic region (423.2 – 433.2 K) was investigated by inverse gas chromatography at infinite dilution (IGC-ID). The selectivity parameters of the structural isomer series named butyl acetate, butyl alcohol, and amyl alcohol series were calculated for the DBA using IGC-ID technique. Additionally, the surface properties including dispersive surface energy (gS D), free energy (DGA S), enthalpy (DHA S), and acidity-basicity constants were calculated with net retention volumes obtained from IGC-ID experiment results. When the DHA S and DGA S are constants, DBA surface was found to be an acidic character (KD/KA @ 0.89).
doi_str_mv 10.3906/kim-2101-13
format Article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8326467</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2561486640</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-33688118feb9143dcfbe68f13310025a8d0d2b2f48be834ed9f299685293b7493</originalsourceid><addsrcrecordid>eNpVUU1r3DAQFaWh2SQ99Q_ouKU4kSxZK18CJd-wkEtyFrI8atTallcfIRv646NtQmhgmBl4j_dmeAh9o-SYtUSc_HFjVVNCK8o-oQVlhFWi9M__7fvoIMbfhNC21Be0zziTjVzRBfp78aiHrJPzE_YWpwfAMQerDeA5-BlCchB3CK-W52C2g3_afscdTM_eGayN6_HgNrkME7Yx6QHrqccuRZwjYDfhmEI2KYeCuOhHCDjCrMM_xyO0Z_UQ4evbPET3lxd3Z9fV-vbq5uznujKskaliTEhJqbTQtZSz3tgOhLSUMUpI3WjZk77uastlB5Jx6Ftbt62QTd2ybsVbdohOX3Xn3I3QG5hSuUfNwY06bJXXTn1EJvegfvlHJVktuFgVgeWbQPCbDDGp0UUDw6An8DmquhGUSyE4KdQfr1QTfIwB7LsNJWqXlyp5qV1eqjzwAsWgiYA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2561486640</pqid></control><display><type>article</type><title>Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>TÜBİTAK Scientific Journals</source><source>PubMed Central Open Access</source><creator>IŞIK, Birol ; ÇAKAR, Fatih ; CANKURTARAN, Hüsnü ; CANKURTARAN, Özlem</creator><creatorcontrib>IŞIK, Birol ; ÇAKAR, Fatih ; CANKURTARAN, Hüsnü ; CANKURTARAN, Özlem</creatorcontrib><description>The selectivity of 4-(Decyloxy) benzoic acid (DBA) liquid crystal in surface adsorption region (303.2–328.2 K) and thermodynamic region (423.2 – 433.2 K) was investigated by inverse gas chromatography at infinite dilution (IGC-ID). The selectivity parameters of the structural isomer series named butyl acetate, butyl alcohol, and amyl alcohol series were calculated for the DBA using IGC-ID technique. Additionally, the surface properties including dispersive surface energy (gS D), free energy (DGA S), enthalpy (DHA S), and acidity-basicity constants were calculated with net retention volumes obtained from IGC-ID experiment results. When the DHA S and DGA S are constants, DBA surface was found to be an acidic character (KD/KA @ 0.89).</description><identifier>ISSN: 1303-6130</identifier><identifier>ISSN: 1300-0527</identifier><identifier>EISSN: 1303-6130</identifier><identifier>DOI: 10.3906/kim-2101-13</identifier><identifier>PMID: 34385871</identifier><language>eng</language><publisher>The Scientific and Technological Research Council of Turkey</publisher><ispartof>Turkish journal of chemistry, 2021-01, Vol.45 (3), p.845-857</ispartof><rights>Copyright © 2021 The Author(s) 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-33688118feb9143dcfbe68f13310025a8d0d2b2f48be834ed9f299685293b7493</citedby><orcidid>0000-0002-4121-6786 ; 0000-0002-9323-3780 ; 0000-0001-6192-1370 ; 0000-0002-8383-1170</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8326467/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8326467/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids></links><search><creatorcontrib>IŞIK, Birol</creatorcontrib><creatorcontrib>ÇAKAR, Fatih</creatorcontrib><creatorcontrib>CANKURTARAN, Hüsnü</creatorcontrib><creatorcontrib>CANKURTARAN, Özlem</creatorcontrib><title>Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation</title><title>Turkish journal of chemistry</title><description>The selectivity of 4-(Decyloxy) benzoic acid (DBA) liquid crystal in surface adsorption region (303.2–328.2 K) and thermodynamic region (423.2 – 433.2 K) was investigated by inverse gas chromatography at infinite dilution (IGC-ID). The selectivity parameters of the structural isomer series named butyl acetate, butyl alcohol, and amyl alcohol series were calculated for the DBA using IGC-ID technique. Additionally, the surface properties including dispersive surface energy (gS D), free energy (DGA S), enthalpy (DHA S), and acidity-basicity constants were calculated with net retention volumes obtained from IGC-ID experiment results. When the DHA S and DGA S are constants, DBA surface was found to be an acidic character (KD/KA @ 0.89).</description><issn>1303-6130</issn><issn>1300-0527</issn><issn>1303-6130</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpVUU1r3DAQFaWh2SQ99Q_ouKU4kSxZK18CJd-wkEtyFrI8atTallcfIRv646NtQmhgmBl4j_dmeAh9o-SYtUSc_HFjVVNCK8o-oQVlhFWi9M__7fvoIMbfhNC21Be0zziTjVzRBfp78aiHrJPzE_YWpwfAMQerDeA5-BlCchB3CK-W52C2g3_afscdTM_eGayN6_HgNrkME7Yx6QHrqccuRZwjYDfhmEI2KYeCuOhHCDjCrMM_xyO0Z_UQ4evbPET3lxd3Z9fV-vbq5uznujKskaliTEhJqbTQtZSz3tgOhLSUMUpI3WjZk77uastlB5Jx6Ftbt62QTd2ybsVbdohOX3Xn3I3QG5hSuUfNwY06bJXXTn1EJvegfvlHJVktuFgVgeWbQPCbDDGp0UUDw6An8DmquhGUSyE4KdQfr1QTfIwB7LsNJWqXlyp5qV1eqjzwAsWgiYA</recordid><startdate>20210101</startdate><enddate>20210101</enddate><creator>IŞIK, Birol</creator><creator>ÇAKAR, Fatih</creator><creator>CANKURTARAN, Hüsnü</creator><creator>CANKURTARAN, Özlem</creator><general>The Scientific and Technological Research Council of Turkey</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-4121-6786</orcidid><orcidid>https://orcid.org/0000-0002-9323-3780</orcidid><orcidid>https://orcid.org/0000-0001-6192-1370</orcidid><orcidid>https://orcid.org/0000-0002-8383-1170</orcidid></search><sort><creationdate>20210101</creationdate><title>Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation</title><author>IŞIK, Birol ; ÇAKAR, Fatih ; CANKURTARAN, Hüsnü ; CANKURTARAN, Özlem</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-33688118feb9143dcfbe68f13310025a8d0d2b2f48be834ed9f299685293b7493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>IŞIK, Birol</creatorcontrib><creatorcontrib>ÇAKAR, Fatih</creatorcontrib><creatorcontrib>CANKURTARAN, Hüsnü</creatorcontrib><creatorcontrib>CANKURTARAN, Özlem</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Turkish journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>IŞIK, Birol</au><au>ÇAKAR, Fatih</au><au>CANKURTARAN, Hüsnü</au><au>CANKURTARAN, Özlem</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation</atitle><jtitle>Turkish journal of chemistry</jtitle><date>2021-01-01</date><risdate>2021</risdate><volume>45</volume><issue>3</issue><spage>845</spage><epage>857</epage><pages>845-857</pages><issn>1303-6130</issn><issn>1300-0527</issn><eissn>1303-6130</eissn><abstract>The selectivity of 4-(Decyloxy) benzoic acid (DBA) liquid crystal in surface adsorption region (303.2–328.2 K) and thermodynamic region (423.2 – 433.2 K) was investigated by inverse gas chromatography at infinite dilution (IGC-ID). The selectivity parameters of the structural isomer series named butyl acetate, butyl alcohol, and amyl alcohol series were calculated for the DBA using IGC-ID technique. Additionally, the surface properties including dispersive surface energy (gS D), free energy (DGA S), enthalpy (DHA S), and acidity-basicity constants were calculated with net retention volumes obtained from IGC-ID experiment results. When the DHA S and DGA S are constants, DBA surface was found to be an acidic character (KD/KA @ 0.89).</abstract><pub>The Scientific and Technological Research Council of Turkey</pub><pmid>34385871</pmid><doi>10.3906/kim-2101-13</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-4121-6786</orcidid><orcidid>https://orcid.org/0000-0002-9323-3780</orcidid><orcidid>https://orcid.org/0000-0001-6192-1370</orcidid><orcidid>https://orcid.org/0000-0002-8383-1170</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1303-6130
ispartof Turkish journal of chemistry, 2021-01, Vol.45 (3), p.845-857
issn 1303-6130
1300-0527
1303-6130
language eng
recordid cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8326467
source Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; TÜBİTAK Scientific Journals; PubMed Central Open Access
title Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-14T04%3A53%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Evaluation%20of%20the%20surface%20properties%20of%204-(Decyloxy)%20benzoic%20acid%20liquid%20crystal%20and%20its%20use%20in%20structural%20isomer%20separation&rft.jtitle=Turkish%20journal%20of%20chemistry&rft.au=I%C5%9EIK,%20Birol&rft.date=2021-01-01&rft.volume=45&rft.issue=3&rft.spage=845&rft.epage=857&rft.pages=845-857&rft.issn=1303-6130&rft.eissn=1303-6130&rft_id=info:doi/10.3906/kim-2101-13&rft_dat=%3Cproquest_pubme%3E2561486640%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2561486640&rft_id=info:pmid/34385871&rfr_iscdi=true