Ligand Conformational Flexibility Enables Enantioselective Tertiary C–B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration

Conformationally flexible ancillary ligands have been widely used in transition metal catalysis. However, the benefits of using flexible ligands are often not well understood. We performed density functional theory (DFT) and experimental studies to elucidate the mechanisms and the roles of conformat...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-03, Vol.143 (12), p.4801-4808
Hauptverfasser:	Shao, Huiling, Chakrabarty, Suman, Qi, Xiaotian, Takacs, James M, Liu, Peng
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Boranes - chemical synthesis Boranes - chemistry Catalysis Ligands Molecular Conformation Organophosphonates - chemistry Stereoisomerism
Online-Zugang:	Volltext
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