Chasing the Mond Cation: Synthesis and Characterization of the Homoleptic Nickel Tetracarbonyl Cation and its Tricarbonyl‐Nitrosyl Analogue

130 years after Mond discovered the first homoleptic carbonyl complex Ni(CO)4, we report on a [Ni(CO)4].+ salt as the first synthesis of any homoleptic nickel carbonyl cation in the condensed phase. It was prepared by oxidation of nickel metal with the synergistic oxidant Ag[F{Al(ORF)3}2]/0.5 I2 (RF...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-06, Vol.60 (27), p.14800-14805
Hauptverfasser:	Schmitt, Manuel, Mayländer, Maximilian, Goost, Julian, Richert, Sabine, Krossing, Ingo
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Carbon monoxide Carbonyl compounds carbonyl ligands Carbonyls Cations Communication Communications Nickel Nickel carbonyl NMR Nuclear magnetic resonance Oxidants Oxidation Oxidizing agents Silver Single crystals Synthesis transition metals weakly coordinating anions
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