Stereoselective and Stereospecific Triflate‐Mediated Intramolecular Schmidt Reaction: Ready Access to Alkaloid Skeletons

The stereoselectivity and stereospecificity of the triflate‐mediated intramolecular Schmidt reaction of substituted 3‐(1‐azidocyclohexyl)propanol derivatives leading to octahydro‐1H‐pyrrolo[1,2‐a]azepine, the structural skeleton of several important families of alkaloids such as the Stemona alkaloid...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-04, Vol.60 (18), p.10179-10185
Hauptverfasser:	Gnägi, Lars, Arnold, Remo, Giornal, Florence, Jangra, Harish, Kapat, Ajoy, Nyfeler, Erich, Schärer, Robin M., Zipse, Hendrik, Renaud, Philippe
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Alkaloids azabicyclic compounds azides Diastereoisomers Propanol Racemization Schmidt reaction stereochemistry Stereoselectivity Stereospecificity Venom Workers (insect caste)
Online-Zugang:	Volltext
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