Trapped interfacial redox introduces reversibility in the oxygen reduction reaction in a non-aqueous Ca2+ electrolyte

Electrochemical investigations of the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) have been conducted in a Ca2+-containing dimethyl sulfoxide electrolyte. While the ORR appears irreversible, the introduction of a tetrabutylammonium perchlorate (TBAClO4) co-salt in excess conc...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemical science (Cambridge) 2021-05, Vol.12 (25), p.8909-8919
Hauptverfasser:	Yi-Ting, Lu, Neale, Alex R, Chi-Chang, Hu, Hardwick, Laurence J
Format:	Artikel
Sprache:	eng
Schlagworte:	Calcium ions Cations Chemistry Dimethyl sulfoxide Electrodes Electrolytes Interlayers Ion pairs Oxidation Oxygen evolution reactions Oxygen reduction reactions
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!