Evaluation of Hydrogenation Kinetics and Life Cycle Assessment on Mg2NiHx–CaO Composites
Magnesium-based alloys are attractive as hydrogen storage materials due to their lightweight and high absorption, but their high operating temperatures and very slow kinetics are obstacles to practical applications. Therefore, the effect of CaO has improved the hydrogenation kinetics and slowed down...
Gespeichert in:
| Veröffentlicht in: | Materials 2021-05, Vol.14 (11), p.2848 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 11 |
| container_start_page | 2848 |
| container_title | Materials |
| container_volume | 14 |
| creator | Shin, Hyo-Won Hwang, June-Hyeon Kim, Eun-A Hong, Tae-Whan |
| description | Magnesium-based alloys are attractive as hydrogen storage materials due to their lightweight and high absorption, but their high operating temperatures and very slow kinetics are obstacles to practical applications. Therefore, the effect of CaO has improved the hydrogenation kinetics and slowed down the degradation. The Mg2NiHx–CaO composites were prepared by hydrogen-induced mechanical alloying (HIMA). Hydrogenation kinetics was performed by using an Automatic PCT Measuring System and evaluated in the temperature range of 423, 523, and 623 K. As a result of calculating the hydrogen absorption amounts through the hydrogenation kinetics curve, they were calculated as about 0.52 wt%, 1.21 wt%, and 1.59 wt% (Mg2NiHx–10 wt% CaO). In this study, the material environmental aspects of Mg2NiHx–CaO composites were investigated through life cycle assessment (LCA). LCA was performed analyzing the environmental impact characteristics of the manufacturing process by using Gabi software and the Eco-Indicator 99’ and Centrum voor Milieuweten schappen (CML 2001) methodology. As a result, the contents of global warming potential (GWP) and fossil fuels were found to have a higher impact than other impact categories. |
| doi_str_mv | 10.3390/ma14112848 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8197870</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2539938649</sourcerecordid><originalsourceid>FETCH-LOGICAL-c383t-8c96d5e5d0af2e5f22833274aa26a9b3bb538f26e8ab7a3773a3d3c24da7b3f33</originalsourceid><addsrcrecordid>eNpdkc9Kw0AQxhdRrNRefIKAFxGq2Z1NsnsRSqhWrPaiFy_LJNnULUm2ZpNib76Db-iTmNLiv7nMMPPj4xs-Qk6ofwEg_csSKaeUCS72yBGVMhxSyfn-r7lHBs4t_K4AqGDykPSA-xFwJo_I83iFRYuNsZVnc2-yzmo719V2cWcq3ZjUeVhl3tTk2ovXaaG9kXPauVJXjddR93P2YCZvn-8fMc682JZL60yj3TE5yLFwerDrffJ0PX6MJ8Pp7OY2Hk2HKQhohiKVYRboIPMxZzrIGRMALOKILESZQJIEIHIWaoFJhBBFgJBByniGUQI5QJ9cbXWXbVLqLO1s1VioZW1KrNfKolF_L5V5UXO7UoLKSER-J3C2E6jta6tdo0rjUl0UWGnbOsUCCLlk4NMOPf2HLmxbV917G0pKEB3ZUedbKq2tc7XOv81QX21SUz-pwRe_lYly</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2539938649</pqid></control><display><type>article</type><title>Evaluation of Hydrogenation Kinetics and Life Cycle Assessment on Mg2NiHx–CaO Composites</title><source>PubMed Central Open Access</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Shin, Hyo-Won ; Hwang, June-Hyeon ; Kim, Eun-A ; Hong, Tae-Whan</creator><creatorcontrib>Shin, Hyo-Won ; Hwang, June-Hyeon ; Kim, Eun-A ; Hong, Tae-Whan</creatorcontrib><description>Magnesium-based alloys are attractive as hydrogen storage materials due to their lightweight and high absorption, but their high operating temperatures and very slow kinetics are obstacles to practical applications. Therefore, the effect of CaO has improved the hydrogenation kinetics and slowed down the degradation. The Mg2NiHx–CaO composites were prepared by hydrogen-induced mechanical alloying (HIMA). Hydrogenation kinetics was performed by using an Automatic PCT Measuring System and evaluated in the temperature range of 423, 523, and 623 K. As a result of calculating the hydrogen absorption amounts through the hydrogenation kinetics curve, they were calculated as about 0.52 wt%, 1.21 wt%, and 1.59 wt% (Mg2NiHx–10 wt% CaO). In this study, the material environmental aspects of Mg2NiHx–CaO composites were investigated through life cycle assessment (LCA). LCA was performed analyzing the environmental impact characteristics of the manufacturing process by using Gabi software and the Eco-Indicator 99’ and Centrum voor Milieuweten schappen (CML 2001) methodology. As a result, the contents of global warming potential (GWP) and fossil fuels were found to have a higher impact than other impact categories.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14112848</identifier><identifier>PMID: 34073429</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Absorption ; Carbon ; Clean technology ; Composite materials ; Emissions ; Energy ; Environmental impact ; Evaluation ; Fossil fuels ; Hydrogen ; Hydrogen storage materials ; Hydrogenation ; Impact analysis ; Inventory ; Kinetics ; Life cycle assessment ; Magnesium base alloys ; Manufacturing ; Mathematical analysis ; Mechanical alloying ; Methods ; Operating temperature ; Raw materials</subject><ispartof>Materials, 2021-05, Vol.14 (11), p.2848</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-8c96d5e5d0af2e5f22833274aa26a9b3bb538f26e8ab7a3773a3d3c24da7b3f33</citedby><cites>FETCH-LOGICAL-c383t-8c96d5e5d0af2e5f22833274aa26a9b3bb538f26e8ab7a3773a3d3c24da7b3f33</cites><orcidid>0000-0002-5237-0826 ; 0000-0001-7505-0246</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8197870/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8197870/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,886,27926,27927,53793,53795</link.rule.ids></links><search><creatorcontrib>Shin, Hyo-Won</creatorcontrib><creatorcontrib>Hwang, June-Hyeon</creatorcontrib><creatorcontrib>Kim, Eun-A</creatorcontrib><creatorcontrib>Hong, Tae-Whan</creatorcontrib><title>Evaluation of Hydrogenation Kinetics and Life Cycle Assessment on Mg2NiHx–CaO Composites</title><title>Materials</title><description>Magnesium-based alloys are attractive as hydrogen storage materials due to their lightweight and high absorption, but their high operating temperatures and very slow kinetics are obstacles to practical applications. Therefore, the effect of CaO has improved the hydrogenation kinetics and slowed down the degradation. The Mg2NiHx–CaO composites were prepared by hydrogen-induced mechanical alloying (HIMA). Hydrogenation kinetics was performed by using an Automatic PCT Measuring System and evaluated in the temperature range of 423, 523, and 623 K. As a result of calculating the hydrogen absorption amounts through the hydrogenation kinetics curve, they were calculated as about 0.52 wt%, 1.21 wt%, and 1.59 wt% (Mg2NiHx–10 wt% CaO). In this study, the material environmental aspects of Mg2NiHx–CaO composites were investigated through life cycle assessment (LCA). LCA was performed analyzing the environmental impact characteristics of the manufacturing process by using Gabi software and the Eco-Indicator 99’ and Centrum voor Milieuweten schappen (CML 2001) methodology. As a result, the contents of global warming potential (GWP) and fossil fuels were found to have a higher impact than other impact categories.</description><subject>Absorption</subject><subject>Carbon</subject><subject>Clean technology</subject><subject>Composite materials</subject><subject>Emissions</subject><subject>Energy</subject><subject>Environmental impact</subject><subject>Evaluation</subject><subject>Fossil fuels</subject><subject>Hydrogen</subject><subject>Hydrogen storage materials</subject><subject>Hydrogenation</subject><subject>Impact analysis</subject><subject>Inventory</subject><subject>Kinetics</subject><subject>Life cycle assessment</subject><subject>Magnesium base alloys</subject><subject>Manufacturing</subject><subject>Mathematical analysis</subject><subject>Mechanical alloying</subject><subject>Methods</subject><subject>Operating temperature</subject><subject>Raw materials</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkc9Kw0AQxhdRrNRefIKAFxGq2Z1NsnsRSqhWrPaiFy_LJNnULUm2ZpNib76Db-iTmNLiv7nMMPPj4xs-Qk6ofwEg_csSKaeUCS72yBGVMhxSyfn-r7lHBs4t_K4AqGDykPSA-xFwJo_I83iFRYuNsZVnc2-yzmo719V2cWcq3ZjUeVhl3tTk2ovXaaG9kXPauVJXjddR93P2YCZvn-8fMc682JZL60yj3TE5yLFwerDrffJ0PX6MJ8Pp7OY2Hk2HKQhohiKVYRboIPMxZzrIGRMALOKILESZQJIEIHIWaoFJhBBFgJBByniGUQI5QJ9cbXWXbVLqLO1s1VioZW1KrNfKolF_L5V5UXO7UoLKSER-J3C2E6jta6tdo0rjUl0UWGnbOsUCCLlk4NMOPf2HLmxbV917G0pKEB3ZUedbKq2tc7XOv81QX21SUz-pwRe_lYly</recordid><startdate>20210526</startdate><enddate>20210526</enddate><creator>Shin, Hyo-Won</creator><creator>Hwang, June-Hyeon</creator><creator>Kim, Eun-A</creator><creator>Hong, Tae-Whan</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5237-0826</orcidid><orcidid>https://orcid.org/0000-0001-7505-0246</orcidid></search><sort><creationdate>20210526</creationdate><title>Evaluation of Hydrogenation Kinetics and Life Cycle Assessment on Mg2NiHx–CaO Composites</title><author>Shin, Hyo-Won ; Hwang, June-Hyeon ; Kim, Eun-A ; Hong, Tae-Whan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-8c96d5e5d0af2e5f22833274aa26a9b3bb538f26e8ab7a3773a3d3c24da7b3f33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Absorption</topic><topic>Carbon</topic><topic>Clean technology</topic><topic>Composite materials</topic><topic>Emissions</topic><topic>Energy</topic><topic>Environmental impact</topic><topic>Evaluation</topic><topic>Fossil fuels</topic><topic>Hydrogen</topic><topic>Hydrogen storage materials</topic><topic>Hydrogenation</topic><topic>Impact analysis</topic><topic>Inventory</topic><topic>Kinetics</topic><topic>Life cycle assessment</topic><topic>Magnesium base alloys</topic><topic>Manufacturing</topic><topic>Mathematical analysis</topic><topic>Mechanical alloying</topic><topic>Methods</topic><topic>Operating temperature</topic><topic>Raw materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shin, Hyo-Won</creatorcontrib><creatorcontrib>Hwang, June-Hyeon</creatorcontrib><creatorcontrib>Kim, Eun-A</creatorcontrib><creatorcontrib>Hong, Tae-Whan</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shin, Hyo-Won</au><au>Hwang, June-Hyeon</au><au>Kim, Eun-A</au><au>Hong, Tae-Whan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evaluation of Hydrogenation Kinetics and Life Cycle Assessment on Mg2NiHx–CaO Composites</atitle><jtitle>Materials</jtitle><date>2021-05-26</date><risdate>2021</risdate><volume>14</volume><issue>11</issue><spage>2848</spage><pages>2848-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>Magnesium-based alloys are attractive as hydrogen storage materials due to their lightweight and high absorption, but their high operating temperatures and very slow kinetics are obstacles to practical applications. Therefore, the effect of CaO has improved the hydrogenation kinetics and slowed down the degradation. The Mg2NiHx–CaO composites were prepared by hydrogen-induced mechanical alloying (HIMA). Hydrogenation kinetics was performed by using an Automatic PCT Measuring System and evaluated in the temperature range of 423, 523, and 623 K. As a result of calculating the hydrogen absorption amounts through the hydrogenation kinetics curve, they were calculated as about 0.52 wt%, 1.21 wt%, and 1.59 wt% (Mg2NiHx–10 wt% CaO). In this study, the material environmental aspects of Mg2NiHx–CaO composites were investigated through life cycle assessment (LCA). LCA was performed analyzing the environmental impact characteristics of the manufacturing process by using Gabi software and the Eco-Indicator 99’ and Centrum voor Milieuweten schappen (CML 2001) methodology. As a result, the contents of global warming potential (GWP) and fossil fuels were found to have a higher impact than other impact categories.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>34073429</pmid><doi>10.3390/ma14112848</doi><orcidid>https://orcid.org/0000-0002-5237-0826</orcidid><orcidid>https://orcid.org/0000-0001-7505-0246</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1996-1944 |
| ispartof | Materials, 2021-05, Vol.14 (11), p.2848 |
| issn | 1996-1944 1996-1944 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8197870 |
| source | PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | Absorption Carbon Clean technology Composite materials Emissions Energy Environmental impact Evaluation Fossil fuels Hydrogen Hydrogen storage materials Hydrogenation Impact analysis Inventory Kinetics Life cycle assessment Magnesium base alloys Manufacturing Mathematical analysis Mechanical alloying Methods Operating temperature Raw materials |
| title | Evaluation of Hydrogenation Kinetics and Life Cycle Assessment on Mg2NiHx–CaO Composites |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T09%3A35%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Evaluation%20of%20Hydrogenation%20Kinetics%20and%20Life%20Cycle%20Assessment%20on%20Mg2NiHx%E2%80%93CaO%20Composites&rft.jtitle=Materials&rft.au=Shin,%20Hyo-Won&rft.date=2021-05-26&rft.volume=14&rft.issue=11&rft.spage=2848&rft.pages=2848-&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/10.3390/ma14112848&rft_dat=%3Cproquest_pubme%3E2539938649%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2539938649&rft_id=info:pmid/34073429&rfr_iscdi=true |