Effect of Additives during Interfacial Polymerization Reaction for Fabrication of Organic Solvent Nanofiltration (OSN) Membranes
Thin film composite (TFC) membranes is the dominant type of desalination in the field of membrane technology. Most of the TFC membranes are fabricated via interfacial polymerization (IP) technique. The ingenious chemistry of reacting acyl chlorides with diamines at the interface between two immiscib...
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| Veröffentlicht in: | Polymers 2021-05, Vol.13 (11), p.1716 |
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| creator | Kim, Su-Min Hong, Sena Duy Nguyen, Bao-Tran Nguyen Thi, Hai-Yen Park, Sang-Hee Kim, Jeong-F. |
| description | Thin film composite (TFC) membranes is the dominant type of desalination in the field of membrane technology. Most of the TFC membranes are fabricated via interfacial polymerization (IP) technique. The ingenious chemistry of reacting acyl chlorides with diamines at the interface between two immiscible phases was first suggested by Cadotte back in the 1980s, and is still the main chemistry employed now. Researchers have made incremental improvements by incorporating various organic and inorganic additives. However, most of the TFC membrane literature are focused on improving the water desalination performance. Recently, the application spectrum of membrane technology has been expanding from the aqueous environment to harsh solvent environments, now commonly known as Organic Solvent Nanofiltration (OSN) technology. In this work, some of the main additives widely used in the desalination TFC membranes were applied to OSN TFC membranes. It was found that tributyl phosphate (TBP) can improve the solubility of diamine monomer in the organic phase, and sodium dodecyl sulfate (SDS) surfactant can effectively stabilize the IP reaction interface. Employing both TBP and SDS exhibited synergistic effect that improved the membrane permeance and rejection in solvent environments. |
| doi_str_mv | 10.3390/polym13111716 |
| format | Article |
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Most of the TFC membranes are fabricated via interfacial polymerization (IP) technique. The ingenious chemistry of reacting acyl chlorides with diamines at the interface between two immiscible phases was first suggested by Cadotte back in the 1980s, and is still the main chemistry employed now. Researchers have made incremental improvements by incorporating various organic and inorganic additives. However, most of the TFC membrane literature are focused on improving the water desalination performance. Recently, the application spectrum of membrane technology has been expanding from the aqueous environment to harsh solvent environments, now commonly known as Organic Solvent Nanofiltration (OSN) technology. In this work, some of the main additives widely used in the desalination TFC membranes were applied to OSN TFC membranes. It was found that tributyl phosphate (TBP) can improve the solubility of diamine monomer in the organic phase, and sodium dodecyl sulfate (SDS) surfactant can effectively stabilize the IP reaction interface. Employing both TBP and SDS exhibited synergistic effect that improved the membrane permeance and rejection in solvent environments.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13111716</identifier><identifier>PMID: 34073893</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Additives ; Aqueous environments ; Chemicals ; Chemistry ; Chromatography ; Desalination ; Diamines ; Fourier transforms ; Membranes ; Molecular weight ; Nanofiltration ; Polymerization ; Polymers ; Pore size ; Sodium dodecyl sulfate ; Solvents ; Synergistic effect ; Thin films ; Water treatment</subject><ispartof>Polymers, 2021-05, Vol.13 (11), p.1716</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-84b2a9f01ae3359c5d236cc62fa9fff65508becdbd18b22fc28d87b200a68cf63</citedby><cites>FETCH-LOGICAL-c392t-84b2a9f01ae3359c5d236cc62fa9fff65508becdbd18b22fc28d87b200a68cf63</cites><orcidid>0000-0002-5575-4374 ; 0000-0003-0847-6356 ; 0000-0002-2539-3168</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8197207/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8197207/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27923,27924,53790,53792</link.rule.ids></links><search><creatorcontrib>Kim, Su-Min</creatorcontrib><creatorcontrib>Hong, Sena</creatorcontrib><creatorcontrib>Duy Nguyen, Bao-Tran</creatorcontrib><creatorcontrib>Nguyen Thi, Hai-Yen</creatorcontrib><creatorcontrib>Park, Sang-Hee</creatorcontrib><creatorcontrib>Kim, Jeong-F.</creatorcontrib><title>Effect of Additives during Interfacial Polymerization Reaction for Fabrication of Organic Solvent Nanofiltration (OSN) Membranes</title><title>Polymers</title><description>Thin film composite (TFC) membranes is the dominant type of desalination in the field of membrane technology. Most of the TFC membranes are fabricated via interfacial polymerization (IP) technique. The ingenious chemistry of reacting acyl chlorides with diamines at the interface between two immiscible phases was first suggested by Cadotte back in the 1980s, and is still the main chemistry employed now. Researchers have made incremental improvements by incorporating various organic and inorganic additives. However, most of the TFC membrane literature are focused on improving the water desalination performance. Recently, the application spectrum of membrane technology has been expanding from the aqueous environment to harsh solvent environments, now commonly known as Organic Solvent Nanofiltration (OSN) technology. In this work, some of the main additives widely used in the desalination TFC membranes were applied to OSN TFC membranes. It was found that tributyl phosphate (TBP) can improve the solubility of diamine monomer in the organic phase, and sodium dodecyl sulfate (SDS) surfactant can effectively stabilize the IP reaction interface. Employing both TBP and SDS exhibited synergistic effect that improved the membrane permeance and rejection in solvent environments.</description><subject>Additives</subject><subject>Aqueous environments</subject><subject>Chemicals</subject><subject>Chemistry</subject><subject>Chromatography</subject><subject>Desalination</subject><subject>Diamines</subject><subject>Fourier transforms</subject><subject>Membranes</subject><subject>Molecular weight</subject><subject>Nanofiltration</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Pore size</subject><subject>Sodium dodecyl sulfate</subject><subject>Solvents</subject><subject>Synergistic effect</subject><subject>Thin films</subject><subject>Water treatment</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkU1LxDAQhoMoKusevQe86KGajzZtLoLI-gHqiqvnkKbJGmmTNWkX9ORPN-uKqHOZIe_DOzMZAPYxOqaUo5OFb986TDHGJWYbYJegkmY5ZWjzV70DxjG-oBR5wRgut8EOzZNYcboLPibGaNVDb-BZ09jeLnWEzRCsm8Nr1-tgpLKyhferTjrYd9lb7-CDluqrMD7AC1kHq9ZC8pmGuXRWwZlvl9r18E46b2zbhzVxOJ3dHcFb3dVBOh33wJaRbdTj7zwCTxeTx_Or7GZ6eX1-dpMpykmfVXlNJDcIS01pwVXREMqUYsSkV2NYUaCq1qqpG1zVhBhFqqYqa4KQZJUyjI7A6dp3MdSdblSaLMhWLILtZHgTXlrxV3H2Wcz9UlSYl6u_HIHDb4PgXwcde9HZqHTbpi38EAUpKMt5kZckoQf_0Bc_BJfWW1GcM5RjlKhsTangYwza_AyDkVidV_w5L_0EKbGaEw</recordid><startdate>20210524</startdate><enddate>20210524</enddate><creator>Kim, Su-Min</creator><creator>Hong, Sena</creator><creator>Duy Nguyen, Bao-Tran</creator><creator>Nguyen Thi, Hai-Yen</creator><creator>Park, Sang-Hee</creator><creator>Kim, Jeong-F.</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5575-4374</orcidid><orcidid>https://orcid.org/0000-0003-0847-6356</orcidid><orcidid>https://orcid.org/0000-0002-2539-3168</orcidid></search><sort><creationdate>20210524</creationdate><title>Effect of Additives during Interfacial Polymerization Reaction for Fabrication of Organic Solvent Nanofiltration (OSN) Membranes</title><author>Kim, Su-Min ; Hong, Sena ; Duy Nguyen, Bao-Tran ; Nguyen Thi, Hai-Yen ; Park, Sang-Hee ; Kim, Jeong-F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-84b2a9f01ae3359c5d236cc62fa9fff65508becdbd18b22fc28d87b200a68cf63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Additives</topic><topic>Aqueous environments</topic><topic>Chemicals</topic><topic>Chemistry</topic><topic>Chromatography</topic><topic>Desalination</topic><topic>Diamines</topic><topic>Fourier transforms</topic><topic>Membranes</topic><topic>Molecular weight</topic><topic>Nanofiltration</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Pore size</topic><topic>Sodium dodecyl sulfate</topic><topic>Solvents</topic><topic>Synergistic effect</topic><topic>Thin films</topic><topic>Water treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Su-Min</creatorcontrib><creatorcontrib>Hong, Sena</creatorcontrib><creatorcontrib>Duy Nguyen, Bao-Tran</creatorcontrib><creatorcontrib>Nguyen Thi, Hai-Yen</creatorcontrib><creatorcontrib>Park, Sang-Hee</creatorcontrib><creatorcontrib>Kim, Jeong-F.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Su-Min</au><au>Hong, Sena</au><au>Duy Nguyen, Bao-Tran</au><au>Nguyen Thi, Hai-Yen</au><au>Park, Sang-Hee</au><au>Kim, Jeong-F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Additives during Interfacial Polymerization Reaction for Fabrication of Organic Solvent Nanofiltration (OSN) Membranes</atitle><jtitle>Polymers</jtitle><date>2021-05-24</date><risdate>2021</risdate><volume>13</volume><issue>11</issue><spage>1716</spage><pages>1716-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>Thin film composite (TFC) membranes is the dominant type of desalination in the field of membrane technology. 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It was found that tributyl phosphate (TBP) can improve the solubility of diamine monomer in the organic phase, and sodium dodecyl sulfate (SDS) surfactant can effectively stabilize the IP reaction interface. Employing both TBP and SDS exhibited synergistic effect that improved the membrane permeance and rejection in solvent environments.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>34073893</pmid><doi>10.3390/polym13111716</doi><orcidid>https://orcid.org/0000-0002-5575-4374</orcidid><orcidid>https://orcid.org/0000-0003-0847-6356</orcidid><orcidid>https://orcid.org/0000-0002-2539-3168</orcidid><oa>free_for_read</oa></addata></record> |
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| source | PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Additives Aqueous environments Chemicals Chemistry Chromatography Desalination Diamines Fourier transforms Membranes Molecular weight Nanofiltration Polymerization Polymers Pore size Sodium dodecyl sulfate Solvents Synergistic effect Thin films Water treatment |
| title | Effect of Additives during Interfacial Polymerization Reaction for Fabrication of Organic Solvent Nanofiltration (OSN) Membranes |
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