Diastereoselective synthesis of [1]rotaxanes via an active metal template strategy

Despite the impressive number of interlocked molecules described in the literature over the past 30 years, only a few stereoselective syntheses of mechanically chiral rotaxanes have been reported so far. In this study, we present the first diastereoselective synthesis of mechanically planar chiral [...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-12, Vol.12 (7), p.2521-2526
Hauptverfasser:	Pairault, Noël, Bessaguet, Adrien, Barat, Romain, Frédéric, Lucas, Pieters, Grégory, Crassous, Jeanne, Opalinski, Isabelle, Papot, Sébastien
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Chemical Sciences Chemistry Cycloaddition Molecular structure Rotaxanes Stereoselectivity Synthesis
Online-Zugang:	Volltext
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