An atropisomeric M2L4 cage mixture displaying guest-induced convergence and strong guest emission in water

Introduction of atropisomeric axes into a bent bispyridine ligand leads to the quantitative formation of a complex mixture of atropisomeric M2L4 cages upon treatment with metal ions. Whereas the isomer ratio of the obtained cage mixture, consisting of up to 42 isomers, is insensitive to temperature...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-07, Vol.11 (31), p.8145-8150
Hauptverfasser:	Tsutsui, Takahiro, Catti, Lorenzo, Yoza, Kenji, Yoshizawa, Michito
Format:	Artikel
Sprache:	eng
Schlagworte:	Buckminsterfullerene Cages Chemistry Convergence Crystallography Emission Encapsulation Fullerenes Isomerization Isomers
Online-Zugang:	Volltext
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