Palladium-catalyzed asymmetric hydrophosphorylation of alkynes: facile access to P -stereogenic phosphinates

Despite the importance of P-chiral organophosphorus compounds in asymmetric catalysis, transition metal-catalyzed methods for accessing P-chiral phosphine derivatives are still limited. Herein, a catalytic enantioselective method for the synthesis of P-stereogenic alkenylphosphinates is developed th...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-06, Vol.11 (28), p.7451-7455
Hauptverfasser:	Yang, Zhiping, Gu, Xiaodong, Han, Li-Biao, Wang, Jun (Joelle)
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Asymmetry Catalysis Chemical synthesis Chemistry Crystallography Enantiomers Organophosphorus compounds Palladium Phosphines Transition metals
Online-Zugang:	Volltext
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