Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions

In this paper, several Mn­(I) complexes were applied as catalysts for the homogeneous hydrogenation of ketones. The most active precatalyst is the bench-stable alkyl bisphosphine Mn­(I) complex fac-[Mn­(dippe) (CO)3(CH2CH2CH3)]. The reaction proceeds at room temperature under base-free conditions wi...

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Veröffentlicht in:Organometallics 2021-05, Vol.40 (9), p.1388-1394
Hauptverfasser: Weber, Stefan, Brünig, Julian, Veiros, Luis F, Kirchner, Karl
Format: Artikel
Sprache:eng
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