The Influences of 1-Butyl-3-Methylimidazolium Tetrafluoroborate on Electrochemical, Thermal and Structural Studies as Ionic Liquid Gel Polymer Electrolyte
After decades of development, ionic liquid gel polymer electrolytes (ILGPEs) are currently experiencing a renaissance as a promising electrolyte to be used in electrochemical devices. Their inherent tendency towards poor electrochemical properties have limited their applications and commercializatio...
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| Veröffentlicht in: | Polymers 2021-04, Vol.13 (8), p.1277 |
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| creator | Dzulkipli, Mariah Zuliana Karim, Jamilah Ahmad, Azizan Dzulkurnain, Nurul Akmaliah Su'ait, Mohd Sukor Yoshizawa-Fujita, Masahiro Tian Khoon, Lee Hassan, Nur Hasyareeda |
| description | After decades of development, ionic liquid gel polymer electrolytes (ILGPEs) are currently experiencing a renaissance as a promising electrolyte to be used in electrochemical devices. Their inherent tendency towards poor electrochemical properties have limited their applications and commercialization activities. Henceforth, gel polymer electrolyte (GPE) is being introduced to alleviate the abovementioned issues. In this work, the assessment of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF
] in poly (vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) to form ILGPE was done. The relationship of [BMIM][BF
] towards the dielectric properties at different wt. % ratios and temperature was ascertained. The results indicated that [BMIM]BF
is able to facilitate fast conduction. Moreover, it was found that [BMIM][BF
] could serve as an effective agent in reducing crystallinity and glass transition temperature of the polymer and thus enhanced the ionic conductivity of the samples. Notwithstanding, the ILGPE sample possessed a high thermal stability up to 300 °C and good electrochemical stability of 4.2 V which are beneficial for operation in electrochemical devices. All in all, the correlation between the ionic liquid chemistry and electrochemical performances could provide a valuable insight to rational selection and design for ILGPE electrolytes. |
| doi_str_mv | 10.3390/polym13081277 |
| format | Article |
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] in poly (vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) to form ILGPE was done. The relationship of [BMIM][BF
] towards the dielectric properties at different wt. % ratios and temperature was ascertained. The results indicated that [BMIM]BF
is able to facilitate fast conduction. Moreover, it was found that [BMIM][BF
] could serve as an effective agent in reducing crystallinity and glass transition temperature of the polymer and thus enhanced the ionic conductivity of the samples. Notwithstanding, the ILGPE sample possessed a high thermal stability up to 300 °C and good electrochemical stability of 4.2 V which are beneficial for operation in electrochemical devices. All in all, the correlation between the ionic liquid chemistry and electrochemical performances could provide a valuable insight to rational selection and design for ILGPE electrolytes.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13081277</identifier><identifier>PMID: 33919960</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Batteries ; Commercialization ; Dielectric properties ; Electrochemical analysis ; Electrodes ; Electrolytes ; Fluorides ; Fuel cells ; Glass transition temperature ; High temperature ; Ion currents ; Ionic liquids ; Ions ; Molecular weight ; Polymers ; Solvents ; Stainless steel ; Thermal stability ; Vinylidene ; Vinylidene fluoride ; Viscosity</subject><ispartof>Polymers, 2021-04, Vol.13 (8), p.1277</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c415t-351d0f0c61deb8aba1fc393f105378000afa5f2d6eefb217b34416f55515405f3</citedby><cites>FETCH-LOGICAL-c415t-351d0f0c61deb8aba1fc393f105378000afa5f2d6eefb217b34416f55515405f3</cites><orcidid>0000-0002-8269-985X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8070978/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8070978/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,724,777,781,882,27905,27906,53772,53774</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33919960$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dzulkipli, Mariah Zuliana</creatorcontrib><creatorcontrib>Karim, Jamilah</creatorcontrib><creatorcontrib>Ahmad, Azizan</creatorcontrib><creatorcontrib>Dzulkurnain, Nurul Akmaliah</creatorcontrib><creatorcontrib>Su'ait, Mohd Sukor</creatorcontrib><creatorcontrib>Yoshizawa-Fujita, Masahiro</creatorcontrib><creatorcontrib>Tian Khoon, Lee</creatorcontrib><creatorcontrib>Hassan, Nur Hasyareeda</creatorcontrib><title>The Influences of 1-Butyl-3-Methylimidazolium Tetrafluoroborate on Electrochemical, Thermal and Structural Studies as Ionic Liquid Gel Polymer Electrolyte</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>After decades of development, ionic liquid gel polymer electrolytes (ILGPEs) are currently experiencing a renaissance as a promising electrolyte to be used in electrochemical devices. Their inherent tendency towards poor electrochemical properties have limited their applications and commercialization activities. Henceforth, gel polymer electrolyte (GPE) is being introduced to alleviate the abovementioned issues. In this work, the assessment of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF
] in poly (vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) to form ILGPE was done. The relationship of [BMIM][BF
] towards the dielectric properties at different wt. % ratios and temperature was ascertained. The results indicated that [BMIM]BF
is able to facilitate fast conduction. Moreover, it was found that [BMIM][BF
] could serve as an effective agent in reducing crystallinity and glass transition temperature of the polymer and thus enhanced the ionic conductivity of the samples. Notwithstanding, the ILGPE sample possessed a high thermal stability up to 300 °C and good electrochemical stability of 4.2 V which are beneficial for operation in electrochemical devices. All in all, the correlation between the ionic liquid chemistry and electrochemical performances could provide a valuable insight to rational selection and design for ILGPE electrolytes.</description><subject>Batteries</subject><subject>Commercialization</subject><subject>Dielectric properties</subject><subject>Electrochemical analysis</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Fluorides</subject><subject>Fuel cells</subject><subject>Glass transition temperature</subject><subject>High temperature</subject><subject>Ion currents</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Molecular weight</subject><subject>Polymers</subject><subject>Solvents</subject><subject>Stainless steel</subject><subject>Thermal stability</subject><subject>Vinylidene</subject><subject>Vinylidene fluoride</subject><subject>Viscosity</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkUtr3TAQhUVoSUKaZbdF0E0XdStZlmVvCk1I0gu3JJDbtZDlUa-CbN3oUXB_Sn9tFPIgqTYjoW_OzOEg9J6SL4z15OvOu2WijHS0FmIPHdZEsKphLXnz4n6AjmO8IeU0vG2p2EcHpZn2fUsO0b_NFvBqNi7DrCFibzCtTnJaXMWqn5C2i7OTHdVf72ye8AZSUAX2wQ8-qATYz_jMgU7B6y1MViv3GRfNMCmH1Tzi6xSyTjmU53XKoy0zVMQrP1uN1_Y22xFfgMNX904gPGm5JcE79NYoF-H4sR6hX-dnm9Mf1fryYnX6fV3phvJUMU5HYohu6QhDpwZFjWY9M5RwJrriWhnFTT22AGaoqRhY09DWcM4pbwg37Ah9e9Dd5WGCUcNcPDq5C3ZSYZFeWfn6Z7Zb-dv_kR0RpBddEfj0KBD8bYaY5GSjBufUDD5HWfOadFx0TV3Qj_-hNz6HudgrFCc1L0uzQlUPlA4-xgDmeRlK5H3w8lXwhf_w0sEz_RQzuwNSqazi</recordid><startdate>20210414</startdate><enddate>20210414</enddate><creator>Dzulkipli, Mariah Zuliana</creator><creator>Karim, Jamilah</creator><creator>Ahmad, Azizan</creator><creator>Dzulkurnain, Nurul Akmaliah</creator><creator>Su'ait, Mohd Sukor</creator><creator>Yoshizawa-Fujita, Masahiro</creator><creator>Tian Khoon, Lee</creator><creator>Hassan, Nur Hasyareeda</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-8269-985X</orcidid></search><sort><creationdate>20210414</creationdate><title>The Influences of 1-Butyl-3-Methylimidazolium Tetrafluoroborate on Electrochemical, Thermal and Structural Studies as Ionic Liquid Gel Polymer Electrolyte</title><author>Dzulkipli, Mariah Zuliana ; Karim, Jamilah ; Ahmad, Azizan ; Dzulkurnain, Nurul Akmaliah ; Su'ait, Mohd Sukor ; Yoshizawa-Fujita, Masahiro ; Tian Khoon, Lee ; Hassan, Nur Hasyareeda</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c415t-351d0f0c61deb8aba1fc393f105378000afa5f2d6eefb217b34416f55515405f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Batteries</topic><topic>Commercialization</topic><topic>Dielectric properties</topic><topic>Electrochemical analysis</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Fluorides</topic><topic>Fuel cells</topic><topic>Glass transition temperature</topic><topic>High temperature</topic><topic>Ion currents</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Molecular weight</topic><topic>Polymers</topic><topic>Solvents</topic><topic>Stainless steel</topic><topic>Thermal stability</topic><topic>Vinylidene</topic><topic>Vinylidene fluoride</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dzulkipli, Mariah Zuliana</creatorcontrib><creatorcontrib>Karim, Jamilah</creatorcontrib><creatorcontrib>Ahmad, Azizan</creatorcontrib><creatorcontrib>Dzulkurnain, Nurul Akmaliah</creatorcontrib><creatorcontrib>Su'ait, Mohd Sukor</creatorcontrib><creatorcontrib>Yoshizawa-Fujita, Masahiro</creatorcontrib><creatorcontrib>Tian Khoon, Lee</creatorcontrib><creatorcontrib>Hassan, Nur Hasyareeda</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dzulkipli, Mariah Zuliana</au><au>Karim, Jamilah</au><au>Ahmad, Azizan</au><au>Dzulkurnain, Nurul Akmaliah</au><au>Su'ait, Mohd Sukor</au><au>Yoshizawa-Fujita, Masahiro</au><au>Tian Khoon, Lee</au><au>Hassan, Nur Hasyareeda</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Influences of 1-Butyl-3-Methylimidazolium Tetrafluoroborate on Electrochemical, Thermal and Structural Studies as Ionic Liquid Gel Polymer Electrolyte</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2021-04-14</date><risdate>2021</risdate><volume>13</volume><issue>8</issue><spage>1277</spage><pages>1277-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>After decades of development, ionic liquid gel polymer electrolytes (ILGPEs) are currently experiencing a renaissance as a promising electrolyte to be used in electrochemical devices. Their inherent tendency towards poor electrochemical properties have limited their applications and commercialization activities. Henceforth, gel polymer electrolyte (GPE) is being introduced to alleviate the abovementioned issues. In this work, the assessment of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF
] in poly (vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) to form ILGPE was done. The relationship of [BMIM][BF
] towards the dielectric properties at different wt. % ratios and temperature was ascertained. The results indicated that [BMIM]BF
is able to facilitate fast conduction. Moreover, it was found that [BMIM][BF
] could serve as an effective agent in reducing crystallinity and glass transition temperature of the polymer and thus enhanced the ionic conductivity of the samples. Notwithstanding, the ILGPE sample possessed a high thermal stability up to 300 °C and good electrochemical stability of 4.2 V which are beneficial for operation in electrochemical devices. All in all, the correlation between the ionic liquid chemistry and electrochemical performances could provide a valuable insight to rational selection and design for ILGPE electrolytes.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>33919960</pmid><doi>10.3390/polym13081277</doi><orcidid>https://orcid.org/0000-0002-8269-985X</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Batteries Commercialization Dielectric properties Electrochemical analysis Electrodes Electrolytes Fluorides Fuel cells Glass transition temperature High temperature Ion currents Ionic liquids Ions Molecular weight Polymers Solvents Stainless steel Thermal stability Vinylidene Vinylidene fluoride Viscosity |
| title | The Influences of 1-Butyl-3-Methylimidazolium Tetrafluoroborate on Electrochemical, Thermal and Structural Studies as Ionic Liquid Gel Polymer Electrolyte |
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