Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application
In this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NH SCN dopant salt. Three different concentrations of glycerol w...
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| Veröffentlicht in: | Polymers 2021-04, Vol.13 (8), p.1183 |
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| creator | Aziz, Shujahadeen B Asnawi, Ahmad S F M Kadir, Mohd Fakhrul Zamani Alshehri, Saad M Ahamad, Tansir Yusof, Yuhanees M Hadi, Jihad M |
| description | In this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NH
SCN dopant salt. Three different concentrations of glycerol was successfully incorporated as a plasticizer into the CS-MC-NH
SCN electrolyte system. The structural, electrical, and ion transport properties were investigated. The highest conductivity of 2.29 × 10
S cm
is recorded for the electrolyte incorporated 42 wt.% of plasticizer. The complexation and interaction of polymer electrolyte components are studied using the FTIR spectra. The deconvolution (DVN) of FTIR peaks as a sensitive method was used to calculate ion transport parameters. The percentage of free ions is found to influence the transport parameters of number density (
), ionic mobility (
), and diffusion coefficient (
). All electrolytes in this work obey the non-Debye behavior. The highest conductivity electrolyte exhibits the dominancy of ions, where the ionic transference number,
value of (0.976) is near to infinity with a voltage of breakdown of 2.11 V. The fabricated electrochemical double-layer capacitor (EDLC) achieves the highest specific capacitance,
of 98.08 F/g at 10 mV/s by using the cyclic voltammetry (CV) technique. |
| doi_str_mv | 10.3390/polym13081183 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8067534</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2520858181</sourcerecordid><originalsourceid>FETCH-LOGICAL-c415t-7564fcb36019c9e1677eb2c14311f342bf5ebc5f263150ba20e7741ade3f44413</originalsourceid><addsrcrecordid>eNpdkU1v1DAQhiMEolXpkSuyxGUrEerPOOGA1EZLQWoF0pZz5Hgnu66cOLUdpPBf-K94223V1hfb42femdeTZe8J_sxYhU9HZ-eeMFwSUrJX2SHFkuWcFfj1k_NBdhzCDU6Li6Ig8m12kJJJUcnqMPu3in7ScfLKfkJLCzp6o5VFaljvr05vob-L_fJuBB8NBOQ6dGFnDd5Z8xfW6Ny4u17AB3SuQoq4AdVbE11QA1rUq5Mv6AridrYarJ2sC4AWV_UJ6pxHywH8Zkar6LzaADobR5vqReOGd9mbTtkAx_v9KPv9bXldf88vf178qM8uc82JiLkUBe90m7ySSldACimhpZpwRkjHOG07Aa0WHS0YEbhVFIOUnKg1sI5zTthR9vVed5zaHtYahpg-pBm96ZWfG6dM8_xlMNtm4_40JS6kYDwJLPYC3t1OEGLTm7CzqgZwU2iooLgUJSl3tT6-QG_c5IdkL1ECU4ElpYnK7yntXQgeusdmCG52s2-ezT7xH546eKQfJs3-A1aXrOg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2550250722</pqid></control><display><type>article</type><title>Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central Open Access</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>PubMed Central</source><creator>Aziz, Shujahadeen B ; Asnawi, Ahmad S F M ; Kadir, Mohd Fakhrul Zamani ; Alshehri, Saad M ; Ahamad, Tansir ; Yusof, Yuhanees M ; Hadi, Jihad M</creator><creatorcontrib>Aziz, Shujahadeen B ; Asnawi, Ahmad S F M ; Kadir, Mohd Fakhrul Zamani ; Alshehri, Saad M ; Ahamad, Tansir ; Yusof, Yuhanees M ; Hadi, Jihad M</creatorcontrib><description>In this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NH
SCN dopant salt. Three different concentrations of glycerol was successfully incorporated as a plasticizer into the CS-MC-NH
SCN electrolyte system. The structural, electrical, and ion transport properties were investigated. The highest conductivity of 2.29 × 10
S cm
is recorded for the electrolyte incorporated 42 wt.% of plasticizer. The complexation and interaction of polymer electrolyte components are studied using the FTIR spectra. The deconvolution (DVN) of FTIR peaks as a sensitive method was used to calculate ion transport parameters. The percentage of free ions is found to influence the transport parameters of number density (
), ionic mobility (
), and diffusion coefficient (
). All electrolytes in this work obey the non-Debye behavior. The highest conductivity electrolyte exhibits the dominancy of ions, where the ionic transference number,
value of (0.976) is near to infinity with a voltage of breakdown of 2.11 V. The fabricated electrochemical double-layer capacitor (EDLC) achieves the highest specific capacitance,
of 98.08 F/g at 10 mV/s by using the cyclic voltammetry (CV) technique.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13081183</identifier><identifier>PMID: 33916979</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Activated carbon ; Biopolymers ; Chitosan ; Diffusion coefficient ; Electrochemical analysis ; Electrodes ; Electrolytes ; Energy storage ; Fourier transforms ; Glycerol ; Ion transport ; Ionic mobility ; Mathematical analysis ; Parameter sensitivity ; Plasticizers ; Polymer blends ; Spectrum analysis ; Thiocyanates ; Transport properties ; Voltammetry</subject><ispartof>Polymers, 2021-04, Vol.13 (8), p.1183</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c415t-7564fcb36019c9e1677eb2c14311f342bf5ebc5f263150ba20e7741ade3f44413</citedby><cites>FETCH-LOGICAL-c415t-7564fcb36019c9e1677eb2c14311f342bf5ebc5f263150ba20e7741ade3f44413</cites><orcidid>0000-0002-1116-5885 ; 0000-0003-4916-5394</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8067534/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8067534/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33916979$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Aziz, Shujahadeen B</creatorcontrib><creatorcontrib>Asnawi, Ahmad S F M</creatorcontrib><creatorcontrib>Kadir, Mohd Fakhrul Zamani</creatorcontrib><creatorcontrib>Alshehri, Saad M</creatorcontrib><creatorcontrib>Ahamad, Tansir</creatorcontrib><creatorcontrib>Yusof, Yuhanees M</creatorcontrib><creatorcontrib>Hadi, Jihad M</creatorcontrib><title>Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>In this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NH
SCN dopant salt. Three different concentrations of glycerol was successfully incorporated as a plasticizer into the CS-MC-NH
SCN electrolyte system. The structural, electrical, and ion transport properties were investigated. The highest conductivity of 2.29 × 10
S cm
is recorded for the electrolyte incorporated 42 wt.% of plasticizer. The complexation and interaction of polymer electrolyte components are studied using the FTIR spectra. The deconvolution (DVN) of FTIR peaks as a sensitive method was used to calculate ion transport parameters. The percentage of free ions is found to influence the transport parameters of number density (
), ionic mobility (
), and diffusion coefficient (
). All electrolytes in this work obey the non-Debye behavior. The highest conductivity electrolyte exhibits the dominancy of ions, where the ionic transference number,
value of (0.976) is near to infinity with a voltage of breakdown of 2.11 V. The fabricated electrochemical double-layer capacitor (EDLC) achieves the highest specific capacitance,
of 98.08 F/g at 10 mV/s by using the cyclic voltammetry (CV) technique.</description><subject>Activated carbon</subject><subject>Biopolymers</subject><subject>Chitosan</subject><subject>Diffusion coefficient</subject><subject>Electrochemical analysis</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Energy storage</subject><subject>Fourier transforms</subject><subject>Glycerol</subject><subject>Ion transport</subject><subject>Ionic mobility</subject><subject>Mathematical analysis</subject><subject>Parameter sensitivity</subject><subject>Plasticizers</subject><subject>Polymer blends</subject><subject>Spectrum analysis</subject><subject>Thiocyanates</subject><subject>Transport properties</subject><subject>Voltammetry</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkU1v1DAQhiMEolXpkSuyxGUrEerPOOGA1EZLQWoF0pZz5Hgnu66cOLUdpPBf-K94223V1hfb42femdeTZe8J_sxYhU9HZ-eeMFwSUrJX2SHFkuWcFfj1k_NBdhzCDU6Li6Ig8m12kJJJUcnqMPu3in7ScfLKfkJLCzp6o5VFaljvr05vob-L_fJuBB8NBOQ6dGFnDd5Z8xfW6Ny4u17AB3SuQoq4AdVbE11QA1rUq5Mv6AridrYarJ2sC4AWV_UJ6pxHywH8Zkar6LzaADobR5vqReOGd9mbTtkAx_v9KPv9bXldf88vf178qM8uc82JiLkUBe90m7ySSldACimhpZpwRkjHOG07Aa0WHS0YEbhVFIOUnKg1sI5zTthR9vVed5zaHtYahpg-pBm96ZWfG6dM8_xlMNtm4_40JS6kYDwJLPYC3t1OEGLTm7CzqgZwU2iooLgUJSl3tT6-QG_c5IdkL1ECU4ElpYnK7yntXQgeusdmCG52s2-ezT7xH546eKQfJs3-A1aXrOg</recordid><startdate>20210407</startdate><enddate>20210407</enddate><creator>Aziz, Shujahadeen B</creator><creator>Asnawi, Ahmad S F M</creator><creator>Kadir, Mohd Fakhrul Zamani</creator><creator>Alshehri, Saad M</creator><creator>Ahamad, Tansir</creator><creator>Yusof, Yuhanees M</creator><creator>Hadi, Jihad M</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1116-5885</orcidid><orcidid>https://orcid.org/0000-0003-4916-5394</orcidid></search><sort><creationdate>20210407</creationdate><title>Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application</title><author>Aziz, Shujahadeen B ; Asnawi, Ahmad S F M ; Kadir, Mohd Fakhrul Zamani ; Alshehri, Saad M ; Ahamad, Tansir ; Yusof, Yuhanees M ; Hadi, Jihad M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c415t-7564fcb36019c9e1677eb2c14311f342bf5ebc5f263150ba20e7741ade3f44413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Activated carbon</topic><topic>Biopolymers</topic><topic>Chitosan</topic><topic>Diffusion coefficient</topic><topic>Electrochemical analysis</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Energy storage</topic><topic>Fourier transforms</topic><topic>Glycerol</topic><topic>Ion transport</topic><topic>Ionic mobility</topic><topic>Mathematical analysis</topic><topic>Parameter sensitivity</topic><topic>Plasticizers</topic><topic>Polymer blends</topic><topic>Spectrum analysis</topic><topic>Thiocyanates</topic><topic>Transport properties</topic><topic>Voltammetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aziz, Shujahadeen B</creatorcontrib><creatorcontrib>Asnawi, Ahmad S F M</creatorcontrib><creatorcontrib>Kadir, Mohd Fakhrul Zamani</creatorcontrib><creatorcontrib>Alshehri, Saad M</creatorcontrib><creatorcontrib>Ahamad, Tansir</creatorcontrib><creatorcontrib>Yusof, Yuhanees M</creatorcontrib><creatorcontrib>Hadi, Jihad M</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Access via ProQuest (Open Access)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aziz, Shujahadeen B</au><au>Asnawi, Ahmad S F M</au><au>Kadir, Mohd Fakhrul Zamani</au><au>Alshehri, Saad M</au><au>Ahamad, Tansir</au><au>Yusof, Yuhanees M</au><au>Hadi, Jihad M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2021-04-07</date><risdate>2021</risdate><volume>13</volume><issue>8</issue><spage>1183</spage><pages>1183-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>In this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NH
SCN dopant salt. Three different concentrations of glycerol was successfully incorporated as a plasticizer into the CS-MC-NH
SCN electrolyte system. The structural, electrical, and ion transport properties were investigated. The highest conductivity of 2.29 × 10
S cm
is recorded for the electrolyte incorporated 42 wt.% of plasticizer. The complexation and interaction of polymer electrolyte components are studied using the FTIR spectra. The deconvolution (DVN) of FTIR peaks as a sensitive method was used to calculate ion transport parameters. The percentage of free ions is found to influence the transport parameters of number density (
), ionic mobility (
), and diffusion coefficient (
). All electrolytes in this work obey the non-Debye behavior. The highest conductivity electrolyte exhibits the dominancy of ions, where the ionic transference number,
value of (0.976) is near to infinity with a voltage of breakdown of 2.11 V. The fabricated electrochemical double-layer capacitor (EDLC) achieves the highest specific capacitance,
of 98.08 F/g at 10 mV/s by using the cyclic voltammetry (CV) technique.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>33916979</pmid><doi>10.3390/polym13081183</doi><orcidid>https://orcid.org/0000-0002-1116-5885</orcidid><orcidid>https://orcid.org/0000-0003-4916-5394</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Activated carbon Biopolymers Chitosan Diffusion coefficient Electrochemical analysis Electrodes Electrolytes Energy storage Fourier transforms Glycerol Ion transport Ionic mobility Mathematical analysis Parameter sensitivity Plasticizers Polymer blends Spectrum analysis Thiocyanates Transport properties Voltammetry |
| title | Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application |
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