How the Lewis Base F– Catalyzes the 1,3-Dipolar Cycloaddition between Carbon Dioxide and Nitrilimines

The mechanism of the Lewis base F– catalyzed 1,3-dipolar cycloaddition between CO2 and nitrilimines is interrogated using DFT calculations. F– activates the nitrilimine, not CO2 as proposed in the literature, and imparts a significant rate enhancement for the cycloaddition. The origin of this cataly...

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Veröffentlicht in:	Journal of organic chemistry 2021-03, Vol.86 (5), p.4320-4325
Hauptverfasser:	Svatunek, Dennis, Hansen, Thomas, Houk, Kendall N, Hamlin, Trevor A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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