Aggregation and Solvation of Sodium Hexamethyldisilazide: Across the Solvent Spectrum

We report solution structures of sodium hexamethyldisilazide (NaHMDS) solvated by >30 standard solvents (ligands). These include: toluene, benzene, and styrene; triethylamine and related trialkylamines; pyrrolidine as a representative dialkylamine; dialkylethers including THF, tert-butylmethyl et...

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Veröffentlicht in:	Journal of organic chemistry 2021-02, Vol.86 (3), p.2406-2422
Hauptverfasser:	Woltornist, Ryan A, Collum, David B
Format:	Artikel
Sprache:	eng
Schlagworte:	Ligands Molecular Structure Organosilicon Compounds Solvents
Online-Zugang:	Volltext
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