Not‐So‐Innocent Anions Determine the Mechanism of Cationic Alkylators

Alkylating reagents based on thioimidazolium ionic liquids were synthesized and the influence of the anion on the alkylation reaction mechanism explored in detail using both experimental and computational methods. Thioimidazolium cations transfer alkyl substituents to nucleophiles, however the react...

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Veröffentlicht in:	Chemistry : a European journal 2021-02, Vol.27 (10), p.3440-3448
Hauptverfasser:	Taimoory, S. Maryamdokht, Cataldo, Vincenzo Alessandro, Schäfer, Andreas, Trant, John F., Guterman, Ryan
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation Anions Cations Chemical synthesis Chemistry colloids computational chemistry Computer applications Gene expression Ionic liquids Ions Nucleophiles Polymers Potential energy Reaction mechanisms Reagents
Online-Zugang:	Volltext
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