Effect of Ti Content on the Microstructure and High-Temperature Creep Property of Cast Fe-Ni-Based Alloys with High-Al Content

The cast Fe-Ni-based austenitic heat-resistant alloys with 4.5 wt% Al and varying Ti content were developed for high-temperature application. With increase in Ti content, strength of model alloys increased gradually at 700 °C and 750 °C. At 750 °C, alloys with 35Ni-(2~4)Ti composition showed a signi...

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Veröffentlicht in:Materials 2020-12, Vol.14 (1), p.82
Hauptverfasser: Subramanian, Gokul Obulan, Jang, Changheui, Shin, Ji Ho, Jeong, Chaewon
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Jeong, Chaewon
description The cast Fe-Ni-based austenitic heat-resistant alloys with 4.5 wt% Al and varying Ti content were developed for high-temperature application. With increase in Ti content, strength of model alloys increased gradually at 700 °C and 750 °C. At 750 °C, alloys with 35Ni-(2~4)Ti composition showed a significant increase in creep rupture life compared to 30Ni-1Ti alloy, attributed to the increase in γ'-Ni (Al,Ti) precipitates due to higher Ni and Ti content. Among the 35Ni-(2~4)Ti alloys, increasing Ti content from 2 to 4 wt% gradually increased the creep rupture life in the as-cast condition. The creep rupture life was improved after solution annealing treatment, however, the beneficial effect of higher Ti content was not evident for 35Ni-(2~4)Ti alloys. After solution annealing, interdendritic phases were partially dissolved, but coarse B2-NiAl phases were formed. The size and amount of coarse B2-NiAl phases increased with Ti content. In the creep-tested specimens, creep void nucleation and crack propagation were observed along the coarse B2-NiAl phases, especially for high-Ti alloys. Therefore, the beneficial effect of the increase in γ'-Ni (Al,Ti) precipitates for high-Ti alloys on creep property was limited due to the detrimental effect of the presence of coarse B2-NiAl phases.
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With increase in Ti content, strength of model alloys increased gradually at 700 °C and 750 °C. At 750 °C, alloys with 35Ni-(2~4)Ti composition showed a significant increase in creep rupture life compared to 30Ni-1Ti alloy, attributed to the increase in γ'-Ni (Al,Ti) precipitates due to higher Ni and Ti content. Among the 35Ni-(2~4)Ti alloys, increasing Ti content from 2 to 4 wt% gradually increased the creep rupture life in the as-cast condition. The creep rupture life was improved after solution annealing treatment, however, the beneficial effect of higher Ti content was not evident for 35Ni-(2~4)Ti alloys. After solution annealing, interdendritic phases were partially dissolved, but coarse B2-NiAl phases were formed. The size and amount of coarse B2-NiAl phases increased with Ti content. In the creep-tested specimens, creep void nucleation and crack propagation were observed along the coarse B2-NiAl phases, especially for high-Ti alloys. Therefore, the beneficial effect of the increase in γ'-Ni (Al,Ti) precipitates for high-Ti alloys on creep property was limited due to the detrimental effect of the presence of coarse B2-NiAl phases.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14010082</identifier><identifier>PMID: 33375287</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Alloy development ; Annealing ; Chemical precipitation ; Crack propagation ; Creep (materials) ; Creep tests ; Heat resistant alloys ; Heat resisting alloys ; High temperature ; Intermetallic compounds ; Iron ; Iron alloys ; Morphology ; Nickel aluminides ; Nickel base alloys ; Nickel compounds ; Nuclear power plants ; Nuclear reactors ; Nucleation ; Oxidation ; Phases ; Precipitates ; Rupture ; Solution annealing ; Titanium base alloys ; Transmission electron microscopy</subject><ispartof>Materials, 2020-12, Vol.14 (1), p.82</ispartof><rights>2021. This work is licensed under http://creativecommons.org/licenses/by/3.0/ (the “License”). 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With increase in Ti content, strength of model alloys increased gradually at 700 °C and 750 °C. At 750 °C, alloys with 35Ni-(2~4)Ti composition showed a significant increase in creep rupture life compared to 30Ni-1Ti alloy, attributed to the increase in γ'-Ni (Al,Ti) precipitates due to higher Ni and Ti content. Among the 35Ni-(2~4)Ti alloys, increasing Ti content from 2 to 4 wt% gradually increased the creep rupture life in the as-cast condition. The creep rupture life was improved after solution annealing treatment, however, the beneficial effect of higher Ti content was not evident for 35Ni-(2~4)Ti alloys. After solution annealing, interdendritic phases were partially dissolved, but coarse B2-NiAl phases were formed. The size and amount of coarse B2-NiAl phases increased with Ti content. In the creep-tested specimens, creep void nucleation and crack propagation were observed along the coarse B2-NiAl phases, especially for high-Ti alloys. Therefore, the beneficial effect of the increase in γ'-Ni (Al,Ti) precipitates for high-Ti alloys on creep property was limited due to the detrimental effect of the presence of coarse B2-NiAl phases.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>33375287</pmid><doi>10.3390/ma14010082</doi><orcidid>https://orcid.org/0000-0002-5397-7742</orcidid><orcidid>https://orcid.org/0000-0002-8970-704X</orcidid><oa>free_for_read</oa></addata></record>
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source MDPI - Multidisciplinary Digital Publishing Institute; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access
subjects Alloy development
Annealing
Chemical precipitation
Crack propagation
Creep (materials)
Creep tests
Heat resistant alloys
Heat resisting alloys
High temperature
Intermetallic compounds
Iron
Iron alloys
Morphology
Nickel aluminides
Nickel base alloys
Nickel compounds
Nuclear power plants
Nuclear reactors
Nucleation
Oxidation
Phases
Precipitates
Rupture
Solution annealing
Titanium base alloys
Transmission electron microscopy
title Effect of Ti Content on the Microstructure and High-Temperature Creep Property of Cast Fe-Ni-Based Alloys with High-Al Content
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