Performance Parameters of Inductively Coupled Plasma Optical Emission Spectrometry and Graphite Furnace Atomic Absorption Spectrometry Techniques for Pd and Pt Determination in Automotive Catalysts

Palladium (Pd) and platinum (Pt) are extensively used as catalysts in the petrochemical and automotive industries, and due to high demand for them on the market, their recycling from spent supported catalysts is clearly needed. To assess the content of Pd and Pt in catalysts in order to establish th...

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Veröffentlicht in:Materials 2020-11, Vol.13 (22), p.5136
Hauptverfasser: Senila, Marin, Cadar, Oana, Senila, Lacrimioara, Böringer, Sarah, Seaudeau-Pirouley, Karine, Ruiu, Andrea, Lacroix-Desmazes, Patrick
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container_start_page 5136
container_title Materials
container_volume 13
creator Senila, Marin
Cadar, Oana
Senila, Lacrimioara
Böringer, Sarah
Seaudeau-Pirouley, Karine
Ruiu, Andrea
Lacroix-Desmazes, Patrick
description Palladium (Pd) and platinum (Pt) are extensively used as catalysts in the petrochemical and automotive industries, and due to high demand for them on the market, their recycling from spent supported catalysts is clearly needed. To assess the content of Pd and Pt in catalysts in order to establish their commercial value or to evaluate the recovery efficiency of technologies used for recycling, reliable analytical methods for determination of these elements are required. Spectrometric methods, such as inductively coupled plasma optical emission spectrometry (ICP-OES) and graphite furnace atomic absorption spectrometry (GFAAS) are powerful tools that can be employed for the determination of Pd and Pt in various sample matrices. However, these methods allow only the injection of liquid samples. In this regard, the digestion of solid sample by microwave-assisted acid extraction procedures at high pressures and temperatures is often used. In this study, a microwave acid digestion method was optimized for the extraction of Pd and Pt from spent catalysts, using a four-step program, at a maximum 200 °C. The resulting solutions were analyzed using ICP-OES, at two different wavelengths for each metal (Pd at 340.458 and 363.470 nm, and Pt at 265.945 and 214.423 nm, respectively) and using GFAAS (Pd at 247.64 nm, Pt at 265.94 nm). Five types of spent catalyst were analyzed and the standard deviations of repeatability for five parallel samples were less than predicted relative standard deviations (PRSD%) calculated using Horvitz’s equation for all the analyzed samples.
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subjects Absorption spectroscopy
Acid digestion
Analytical chemistry
Atomic absorption analysis
Catalysis
Catalysts
Chemical Sciences
Economic conditions
Efficiency
Emission
Graphite
Inductively coupled plasma
Laboratories
Material chemistry
Mathematical analysis
Metals
Optical emission spectroscopy
Palladium
Platinum
Recycling
Reference materials
Scientific imaging
Spectrometry
Standard deviation
title Performance Parameters of Inductively Coupled Plasma Optical Emission Spectrometry and Graphite Furnace Atomic Absorption Spectrometry Techniques for Pd and Pt Determination in Automotive Catalysts
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