Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds

Phenanthroline ligands and [Ir(cod)(OMe)] form complexes that catalyze the silylation of aromatic and aliphatic C-H bonds. However, no experimental data on the identity of complexes related to the mechanism of this process or the mechanisms by which they react to functionalize C-H bonds have been re...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-06, Vol.142 (23), p.10494-10505
Hauptverfasser:	Karmel, Caleb, Hartwig, John F
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Coordination Complexes - chemistry Iridium - chemistry Molecular Structure Organosilicon Compounds - chemical synthesis Organosilicon Compounds - chemistry Phenanthrolines - chemistry
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