Generation of Magnesium Pentafluoropropen-2-olate from Hexafluoroisopropanol and Synthesis of 2,2,4,4,4-Pentafluoro-3,3-dihydroxyketones

2,2,4,4,4-Pentafluoro-3,3-dihydroxyketones are valuable precursors to difluoroenolates following fragmentation during the release of trifluoroacetate; however, there are few synthetic strategies to prepare this unique class of compound. We addressed this issue and report a mild, two-step synthesis o...

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Veröffentlicht in:	Journal of organic chemistry 2017-02, Vol.82 (4), p.2231-2236
Hauptverfasser:	Hazlitt, Robert A, Tran, Que-Lynn, Sowaileh, Munia F, Colby, David A
Format:	Artikel
Sprache:	eng
Schlagworte:	Hydrocarbons, Fluorinated - chemistry Molecular Structure Organometallic Compounds - chemistry Propanols - chemistry
Online-Zugang:	Volltext
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