Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis
Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunab...
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| Veröffentlicht in: | ACS catalysis 2020-07, Vol.10 (13), p.7250-7261 |
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| container_title | ACS catalysis |
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| creator | Rossi-Ashton, James A Clarke, Aimee K Unsworth, William P Taylor, Richard J. K |
| description | Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunable mediators in photoredox catalysis, highlighting how two distinct methods for phosphoranyl radical formation (radical addition and nucleophilic addition) can be used to generate versatile radical intermediates with diverse reactivity profiles. |
| doi_str_mv | 10.1021/acscatal.0c01923 |
| format | Article |
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| source | ACS Publications |
| title | Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis |
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