Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds

Borosulfates are oxoanionic compounds consisting of condensed sulfur‐ and boron‐centered tetrahedra. Hitherto, they were mostly achieved from solvothermal syntheses in SO3‐enriched sulfuric acid, or from reactions with the superacid H[B(HSO4)4]. The crystal structures are very similar to those of th...

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Veröffentlicht in:	Chemistry : a European journal 2020-06, Vol.26 (36), p.7966-7980
Hauptverfasser:	Bruns, Jörn, Höppe, Henning A., Daub, Michael, Hillebrecht, Harald, Huppertz, Hubert
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron Boron compounds boroselenates borosulfates Chemical synthesis Chemistry Crystal structure inorganic synthesis Review Reviews Silicates Sulfur Sulfur trioxide Sulfuric acid Tetrahedra
Online-Zugang:	Volltext
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