Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds
Borosulfates are oxoanionic compounds consisting of condensed sulfur‐ and boron‐centered tetrahedra. Hitherto, they were mostly achieved from solvothermal syntheses in SO3‐enriched sulfuric acid, or from reactions with the superacid H[B(HSO4)4]. The crystal structures are very similar to those of th...
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| Veröffentlicht in: | Chemistry : a European journal 2020-06, Vol.26 (36), p.7966-7980 |
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| creator | Bruns, Jörn Höppe, Henning A. Daub, Michael Hillebrecht, Harald Huppertz, Hubert |
| description | Borosulfates are oxoanionic compounds consisting of condensed sulfur‐ and boron‐centered tetrahedra. Hitherto, they were mostly achieved from solvothermal syntheses in SO3‐enriched sulfuric acid, or from reactions with the superacid H[B(HSO4)4]. The crystal structures are very similar to those of the corresponding class of silicates and their substitution variants, especially regarding the typical structural motif of corner‐sharing tetrahedra. However, the borosulfates are supposed to be even more versatile, because (BO3) units might also be part of the anionic network. The following article deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties.
Borosulfates are structurally similar to silicates. Their anionic subunits consist of alternating (SO4) and (BO4) tetrahedra forming oligomers, single and multiple chains, layers and extended 3D network structures. The review deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties. |
| doi_str_mv | 10.1002/chem.201905449 |
| format | Article |
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Borosulfates are structurally similar to silicates. Their anionic subunits consist of alternating (SO4) and (BO4) tetrahedra forming oligomers, single and multiple chains, layers and extended 3D network structures. The review deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties.</description><identifier>ISSN: 0947-6539</identifier><identifier>ISSN: 1521-3765</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201905449</identifier><identifier>PMID: 31943390</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Boron ; Boron compounds ; boroselenates ; borosulfates ; Chemical synthesis ; Chemistry ; Crystal structure ; inorganic synthesis ; Review ; Reviews ; Silicates ; Sulfur ; Sulfur trioxide ; Sulfuric acid ; Tetrahedra</subject><ispartof>Chemistry : a European journal, 2020-06, Vol.26 (36), p.7966-7980</ispartof><rights>2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.</rights><rights>2020. This article is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5059-df48710e24adefe20200041b0f64e63e177295c4fb8cec5cf077458b8b5368013</citedby><cites>FETCH-LOGICAL-c5059-df48710e24adefe20200041b0f64e63e177295c4fb8cec5cf077458b8b5368013</cites><orcidid>0000-0002-8414-3871 ; 0000-0002-2098-6087 ; 0000-0002-8734-8258 ; 0000-0002-8589-6154</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201905449$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201905449$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31943390$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bruns, Jörn</creatorcontrib><creatorcontrib>Höppe, Henning A.</creatorcontrib><creatorcontrib>Daub, Michael</creatorcontrib><creatorcontrib>Hillebrecht, Harald</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><title>Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Borosulfates are oxoanionic compounds consisting of condensed sulfur‐ and boron‐centered tetrahedra. Hitherto, they were mostly achieved from solvothermal syntheses in SO3‐enriched sulfuric acid, or from reactions with the superacid H[B(HSO4)4]. The crystal structures are very similar to those of the corresponding class of silicates and their substitution variants, especially regarding the typical structural motif of corner‐sharing tetrahedra. However, the borosulfates are supposed to be even more versatile, because (BO3) units might also be part of the anionic network. The following article deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties.
Borosulfates are structurally similar to silicates. Their anionic subunits consist of alternating (SO4) and (BO4) tetrahedra forming oligomers, single and multiple chains, layers and extended 3D network structures. The review deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties.</description><subject>Boron</subject><subject>Boron compounds</subject><subject>boroselenates</subject><subject>borosulfates</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Crystal structure</subject><subject>inorganic synthesis</subject><subject>Review</subject><subject>Reviews</subject><subject>Silicates</subject><subject>Sulfur</subject><subject>Sulfur trioxide</subject><subject>Sulfuric acid</subject><subject>Tetrahedra</subject><issn>0947-6539</issn><issn>1521-3765</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkc1u1DAUhS1ERYfCliWKxIZNptd_cbxBaqNCKxWBNLC2HOe6kyoTD3EMmh0PwRPyJLiadvjZsPLifvf4nHsIeUFhSQHYqVvjZsmAapBC6EdkQSWjJVeVfEwWoIUqK8n1MXka4y0A6IrzJ-SYUy0417AgH8_DFGIavJ0x_vz-Y7Ub5zXGPhZ27IrVPCU3p8kORZM_6uM87Yrgi1U_9C5vFGejHcJNwqIJm21IYxefkSNvh4jP798T8vntxafmsrz-8O6qObsunQSpy86LWlFAJmyHHhmw7E7QFnwlsOJIlWJaOuHb2qGTzoNSQtZt3Upe1UD5CXmz192mdoOdw3HONs126jd22plge_P3ZOzX5iZ8NYrXglY6C7y-F5jCl4RxNjmfw2GwI4YUDcsHUho0lxl99Q96G9KUo2dKUMWqHKXO1HJPuXzROKE_mKFg7soyd2WZQ1l54eWfEQ74QzsZ0HvgWz_g7j9yprm8eP9b_BeThaLk</recordid><startdate>20200626</startdate><enddate>20200626</enddate><creator>Bruns, Jörn</creator><creator>Höppe, Henning A.</creator><creator>Daub, Michael</creator><creator>Hillebrecht, Harald</creator><creator>Huppertz, Hubert</creator><general>Wiley Subscription Services, Inc</general><general>John Wiley and Sons Inc</general><scope>24P</scope><scope>WIN</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-8414-3871</orcidid><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid><orcidid>https://orcid.org/0000-0002-8734-8258</orcidid><orcidid>https://orcid.org/0000-0002-8589-6154</orcidid></search><sort><creationdate>20200626</creationdate><title>Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds</title><author>Bruns, Jörn ; Höppe, Henning A. ; Daub, Michael ; Hillebrecht, Harald ; Huppertz, Hubert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5059-df48710e24adefe20200041b0f64e63e177295c4fb8cec5cf077458b8b5368013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Boron</topic><topic>Boron compounds</topic><topic>boroselenates</topic><topic>borosulfates</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Crystal structure</topic><topic>inorganic synthesis</topic><topic>Review</topic><topic>Reviews</topic><topic>Silicates</topic><topic>Sulfur</topic><topic>Sulfur trioxide</topic><topic>Sulfuric acid</topic><topic>Tetrahedra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bruns, Jörn</creatorcontrib><creatorcontrib>Höppe, Henning A.</creatorcontrib><creatorcontrib>Daub, Michael</creatorcontrib><creatorcontrib>Hillebrecht, Harald</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><collection>Wiley Online Library (Open Access Collection)</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bruns, Jörn</au><au>Höppe, Henning A.</au><au>Daub, Michael</au><au>Hillebrecht, Harald</au><au>Huppertz, Hubert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2020-06-26</date><risdate>2020</risdate><volume>26</volume><issue>36</issue><spage>7966</spage><epage>7980</epage><pages>7966-7980</pages><issn>0947-6539</issn><issn>1521-3765</issn><eissn>1521-3765</eissn><abstract>Borosulfates are oxoanionic compounds consisting of condensed sulfur‐ and boron‐centered tetrahedra. Hitherto, they were mostly achieved from solvothermal syntheses in SO3‐enriched sulfuric acid, or from reactions with the superacid H[B(HSO4)4]. The crystal structures are very similar to those of the corresponding class of silicates and their substitution variants, especially regarding the typical structural motif of corner‐sharing tetrahedra. However, the borosulfates are supposed to be even more versatile, because (BO3) units might also be part of the anionic network. The following article deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties.
Borosulfates are structurally similar to silicates. Their anionic subunits consist of alternating (SO4) and (BO4) tetrahedra forming oligomers, single and multiple chains, layers and extended 3D network structures. The review deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>31943390</pmid><doi>10.1002/chem.201905449</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0002-8414-3871</orcidid><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid><orcidid>https://orcid.org/0000-0002-8734-8258</orcidid><orcidid>https://orcid.org/0000-0002-8589-6154</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Boron Boron compounds boroselenates borosulfates Chemical synthesis Chemistry Crystal structure inorganic synthesis Review Reviews Silicates Sulfur Sulfur trioxide Sulfuric acid Tetrahedra |
| title | Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds |
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