Hyper-Crosslinked Polymer Nanocomposites Containing Mesoporous Silica Nanoparticles with Enhanced Adsorption Towards Polar Dyes
The development of new styrene-based hyper-crosslinked nanocomposites (HCLN) containing mesoporous silica nanoparticles (MSN) is reported here as a new strategy to obtain functional high surface area materials with an enhanced hydrophilic character. The HCLN composition, morphology and porous struct...
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| Veröffentlicht in: | Polymers 2020-06, Vol.12 (6), p.1388 |
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| creator | Guerritore, Marco Castaldo, Rachele Silvestri, Brigida Avolio, Roberto Cocca, Mariacristina Errico, Maria Emanuela Avella, Maurizio Gentile, Gennaro Ambrogi, Veronica |
| description | The development of new styrene-based hyper-crosslinked nanocomposites (HCLN) containing mesoporous silica nanoparticles (MSN) is reported here as a new strategy to obtain functional high surface area materials with an enhanced hydrophilic character. The HCLN composition, morphology and porous structure were analyzed using a multi-technique approach. The HCLN displayed a high surface area (above 1600 m
/g) and higher microporosity than the corresponding hyper-crosslinked neat resin. The enhanced adsorption properties of the HCLN towards polar organic dyes was demonstrated through the adsorption of a reactive dye, Remazol Brilliant Blue R (RB). In particular, the HCLN containing 5phr MSN showed the highest adsorption capacity of RB. |
| doi_str_mv | 10.3390/polym12061388 |
| format | Article |
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/g) and higher microporosity than the corresponding hyper-crosslinked neat resin. The enhanced adsorption properties of the HCLN towards polar organic dyes was demonstrated through the adsorption of a reactive dye, Remazol Brilliant Blue R (RB). In particular, the HCLN containing 5phr MSN showed the highest adsorption capacity of RB.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym12061388</identifier><identifier>PMID: 32575792</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Adsorbents ; Adsorption ; Crosslinking ; Dyes ; Ethanol ; Microporosity ; Morphology ; Nanocomposites ; Nanoparticles ; Nitrogen ; Pollutants ; Polymerization ; Polymers ; Pore size ; Resins ; Silicon dioxide ; Spectrum analysis ; Surface area ; Surface chemistry ; Surfactants ; Textile industry ; Volumetric analysis</subject><ispartof>Polymers, 2020-06, Vol.12 (6), p.1388</ispartof><rights>2020. This work is licensed under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2020 by the authors. 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c415t-a8b9965a1753275202ac2ecbd82e4f94e8b690884d50c96ee88f825694e226a43</citedby><cites>FETCH-LOGICAL-c415t-a8b9965a1753275202ac2ecbd82e4f94e8b690884d50c96ee88f825694e226a43</cites><orcidid>0000-0002-4487-2287 ; 0000-0003-1654-8698 ; 0000-0002-1280-8926 ; 0000-0002-5701-3625 ; 0000-0002-5733-0161</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7362258/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7362258/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32575792$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Guerritore, Marco</creatorcontrib><creatorcontrib>Castaldo, Rachele</creatorcontrib><creatorcontrib>Silvestri, Brigida</creatorcontrib><creatorcontrib>Avolio, Roberto</creatorcontrib><creatorcontrib>Cocca, Mariacristina</creatorcontrib><creatorcontrib>Errico, Maria Emanuela</creatorcontrib><creatorcontrib>Avella, Maurizio</creatorcontrib><creatorcontrib>Gentile, Gennaro</creatorcontrib><creatorcontrib>Ambrogi, Veronica</creatorcontrib><title>Hyper-Crosslinked Polymer Nanocomposites Containing Mesoporous Silica Nanoparticles with Enhanced Adsorption Towards Polar Dyes</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>The development of new styrene-based hyper-crosslinked nanocomposites (HCLN) containing mesoporous silica nanoparticles (MSN) is reported here as a new strategy to obtain functional high surface area materials with an enhanced hydrophilic character. The HCLN composition, morphology and porous structure were analyzed using a multi-technique approach. The HCLN displayed a high surface area (above 1600 m
/g) and higher microporosity than the corresponding hyper-crosslinked neat resin. The enhanced adsorption properties of the HCLN towards polar organic dyes was demonstrated through the adsorption of a reactive dye, Remazol Brilliant Blue R (RB). In particular, the HCLN containing 5phr MSN showed the highest adsorption capacity of RB.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Crosslinking</subject><subject>Dyes</subject><subject>Ethanol</subject><subject>Microporosity</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Nitrogen</subject><subject>Pollutants</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Pore size</subject><subject>Resins</subject><subject>Silicon dioxide</subject><subject>Spectrum analysis</subject><subject>Surface area</subject><subject>Surface chemistry</subject><subject>Surfactants</subject><subject>Textile industry</subject><subject>Volumetric analysis</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkctPGzEQh62qqCDg2Gu1Ui-9LPVj_bogoZCSSoFWKj1bjndCDLv21t4U5cS_jsNLgC-2NJ8-z8wPoc8EHzGm8fchdpueUCwIU-oD2qNYsrphAn989d5Fhzlf43IaLgSRn9Auo1xyqekeupttBkj1JMWcOx9uoK1-b6WQqgsboov9ELMfIVeTGEbrgw9X1TnkOMQU17n64zvv7AM72DR61xX01o-rahpWNrjiO2lzTMPoY6gu461Nbd5-YVN1uoF8gHaWtstw-HTvo78_ppeTWT3_dfZzcjKvXUP4WFu10FpwSyRnVHKKqXUU3KJVFJqlbkAthMZKNS3HTgsApZaKclEqlArbsH10_Ogd1oseWgdhTLYzQ_K9TRsTrTdvK8GvzFX8byQTlHJVBN-eBCn-W0MeTe-zg66zAcoiDG2I0ExKiQv69R16HdcplPEeKCk4kbpQ9SPltrtPsHxphmCzTde8SbfwX15P8EI_Z8nuAbyUo5s</recordid><startdate>20200620</startdate><enddate>20200620</enddate><creator>Guerritore, Marco</creator><creator>Castaldo, Rachele</creator><creator>Silvestri, Brigida</creator><creator>Avolio, Roberto</creator><creator>Cocca, Mariacristina</creator><creator>Errico, Maria Emanuela</creator><creator>Avella, Maurizio</creator><creator>Gentile, Gennaro</creator><creator>Ambrogi, Veronica</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-4487-2287</orcidid><orcidid>https://orcid.org/0000-0003-1654-8698</orcidid><orcidid>https://orcid.org/0000-0002-1280-8926</orcidid><orcidid>https://orcid.org/0000-0002-5701-3625</orcidid><orcidid>https://orcid.org/0000-0002-5733-0161</orcidid></search><sort><creationdate>20200620</creationdate><title>Hyper-Crosslinked Polymer Nanocomposites Containing Mesoporous Silica Nanoparticles with Enhanced Adsorption Towards Polar Dyes</title><author>Guerritore, Marco ; Castaldo, Rachele ; Silvestri, Brigida ; Avolio, Roberto ; Cocca, Mariacristina ; Errico, Maria Emanuela ; Avella, Maurizio ; Gentile, Gennaro ; Ambrogi, Veronica</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c415t-a8b9965a1753275202ac2ecbd82e4f94e8b690884d50c96ee88f825694e226a43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Crosslinking</topic><topic>Dyes</topic><topic>Ethanol</topic><topic>Microporosity</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Nitrogen</topic><topic>Pollutants</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Pore size</topic><topic>Resins</topic><topic>Silicon dioxide</topic><topic>Spectrum analysis</topic><topic>Surface area</topic><topic>Surface chemistry</topic><topic>Surfactants</topic><topic>Textile industry</topic><topic>Volumetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guerritore, Marco</creatorcontrib><creatorcontrib>Castaldo, Rachele</creatorcontrib><creatorcontrib>Silvestri, Brigida</creatorcontrib><creatorcontrib>Avolio, Roberto</creatorcontrib><creatorcontrib>Cocca, Mariacristina</creatorcontrib><creatorcontrib>Errico, Maria Emanuela</creatorcontrib><creatorcontrib>Avella, Maurizio</creatorcontrib><creatorcontrib>Gentile, Gennaro</creatorcontrib><creatorcontrib>Ambrogi, Veronica</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guerritore, Marco</au><au>Castaldo, Rachele</au><au>Silvestri, Brigida</au><au>Avolio, Roberto</au><au>Cocca, Mariacristina</au><au>Errico, Maria Emanuela</au><au>Avella, Maurizio</au><au>Gentile, Gennaro</au><au>Ambrogi, Veronica</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hyper-Crosslinked Polymer Nanocomposites Containing Mesoporous Silica Nanoparticles with Enhanced Adsorption Towards Polar Dyes</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2020-06-20</date><risdate>2020</risdate><volume>12</volume><issue>6</issue><spage>1388</spage><pages>1388-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>The development of new styrene-based hyper-crosslinked nanocomposites (HCLN) containing mesoporous silica nanoparticles (MSN) is reported here as a new strategy to obtain functional high surface area materials with an enhanced hydrophilic character. 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/g) and higher microporosity than the corresponding hyper-crosslinked neat resin. The enhanced adsorption properties of the HCLN towards polar organic dyes was demonstrated through the adsorption of a reactive dye, Remazol Brilliant Blue R (RB). In particular, the HCLN containing 5phr MSN showed the highest adsorption capacity of RB.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>32575792</pmid><doi>10.3390/polym12061388</doi><orcidid>https://orcid.org/0000-0002-4487-2287</orcidid><orcidid>https://orcid.org/0000-0003-1654-8698</orcidid><orcidid>https://orcid.org/0000-0002-1280-8926</orcidid><orcidid>https://orcid.org/0000-0002-5701-3625</orcidid><orcidid>https://orcid.org/0000-0002-5733-0161</orcidid><oa>free_for_read</oa></addata></record> |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; PubMed Central Open Access |
| subjects | Adsorbents Adsorption Crosslinking Dyes Ethanol Microporosity Morphology Nanocomposites Nanoparticles Nitrogen Pollutants Polymerization Polymers Pore size Resins Silicon dioxide Spectrum analysis Surface area Surface chemistry Surfactants Textile industry Volumetric analysis |
| title | Hyper-Crosslinked Polymer Nanocomposites Containing Mesoporous Silica Nanoparticles with Enhanced Adsorption Towards Polar Dyes |
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