Activation of Aromatic C−F Bonds by a N‐Heterocyclic Olefin (NHO)
A N‐heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C−F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes in which the central carbon–carbon double bond...
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| Veröffentlicht in: | Chemistry : a European journal 2020-05, Vol.26 (27), p.5951-5955 |
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| creator | Mandal, Debdeep Chandra, Shubhadeep Neuman, Nicolás I. Mahata, Alok Sarkar, Arighna Kundu, Abhinanda Anga, Srinivas Rawat, Hemant Schulzke, Carola Mote, Kaustubh R. Sarkar, Biprajit Chandrasekhar, Vadapalli Jana, Anukul |
| description | A N‐heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C−F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes in which the central carbon–carbon double bond is in a twisted geometry.
NHO activation: The activation of aromatic C−F bonds by N‐heterocyclic olefin (NHO) occurs without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes. |
| doi_str_mv | 10.1002/chem.202000276 |
| format | Article |
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NHO activation: The activation of aromatic C−F bonds by N‐heterocyclic olefin (NHO) occurs without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes.</description><subject>Alkenes</subject><subject>C-F activation</subject><subject>Carbon</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Communication</subject><subject>Communications</subject><subject>fluorine</subject><subject>N-heterocyclic olefins</subject><subject>nucleophilic substitution</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><sourceid>AOWDO</sourceid><recordid>eNqNkUtv1DAUhS1ERYfCliWKxKaoynD9TLxBGqIpg1Q6G1hbtuNQV0lc4qRodixZov7E_hLczjA8NrCyr_yd43N1EHqGYY4ByCt74bo5AQJpKMQDNMOc4JwWgj9EM5CsyAWn8hA9jvEyMVJQ-ggd0qQoQNAZWi7s6K_16EOfhSZbDKFLg82q2283p9mb0NcxM5tMZ-e3X7-v3OiGYDe2TcS6dY3vs-Pz1frlE3TQ6Da6p7vzCH08XX6oVvnZ-u27anGWWw5c5NIBtiXR0nJrOK25o67QUlsr6gJMCcI0nAEwQYHSxjS1NULiwgjNGNiGHqHXW9-ryXSutq4fB92qq8F3etiooL3686X3F-pTuFYFxYVkJBkc7wyG8HlycVSdj9a1re5dmKIilBPg6X-W0Bd_oZdhGvq0niIpo8TASkjUfEvZIcQ4uGYfBoO6a0jdNaT2DSXB899X2OM_K0nAyRb44kxoovWut26PJRdOSimZTDfAiS7_n678eN90FaZ-TFK5k_rWbf6RW1Wr5ftfW_wAz0S98g</recordid><startdate>20200512</startdate><enddate>20200512</enddate><creator>Mandal, Debdeep</creator><creator>Chandra, Shubhadeep</creator><creator>Neuman, Nicolás I.</creator><creator>Mahata, Alok</creator><creator>Sarkar, Arighna</creator><creator>Kundu, Abhinanda</creator><creator>Anga, Srinivas</creator><creator>Rawat, Hemant</creator><creator>Schulzke, Carola</creator><creator>Mote, Kaustubh R.</creator><creator>Sarkar, Biprajit</creator><creator>Chandrasekhar, Vadapalli</creator><creator>Jana, Anukul</creator><general>Wiley</general><general>Wiley Subscription Services, Inc</general><general>John Wiley and Sons Inc</general><scope>24P</scope><scope>WIN</scope><scope>1KM</scope><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-7530-539X</orcidid><orcidid>https://orcid.org/0000-0002-1657-1321</orcidid><orcidid>https://orcid.org/0000-0003-3368-0228</orcidid><orcidid>https://orcid.org/0000-0003-3692-0784</orcidid><orcidid>https://orcid.org/0000-0003-4887-7277</orcidid></search><sort><creationdate>20200512</creationdate><title>Activation of Aromatic C−F Bonds by a N‐Heterocyclic Olefin (NHO)</title><author>Mandal, Debdeep ; Chandra, Shubhadeep ; Neuman, Nicolás I. ; Mahata, Alok ; Sarkar, Arighna ; Kundu, Abhinanda ; Anga, Srinivas ; Rawat, Hemant ; Schulzke, Carola ; Mote, Kaustubh R. ; Sarkar, Biprajit ; Chandrasekhar, Vadapalli ; Jana, Anukul</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5056-9e01c82a9c5cb53d5e3e7a9acc6d70b806bf5400463033fbfdcb6917b6a440cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alkenes</topic><topic>C-F activation</topic><topic>Carbon</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry, Multidisciplinary</topic><topic>Communication</topic><topic>Communications</topic><topic>fluorine</topic><topic>N-heterocyclic olefins</topic><topic>nucleophilic substitution</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mandal, Debdeep</creatorcontrib><creatorcontrib>Chandra, Shubhadeep</creatorcontrib><creatorcontrib>Neuman, Nicolás I.</creatorcontrib><creatorcontrib>Mahata, Alok</creatorcontrib><creatorcontrib>Sarkar, Arighna</creatorcontrib><creatorcontrib>Kundu, Abhinanda</creatorcontrib><creatorcontrib>Anga, Srinivas</creatorcontrib><creatorcontrib>Rawat, Hemant</creatorcontrib><creatorcontrib>Schulzke, Carola</creatorcontrib><creatorcontrib>Mote, Kaustubh R.</creatorcontrib><creatorcontrib>Sarkar, Biprajit</creatorcontrib><creatorcontrib>Chandrasekhar, Vadapalli</creatorcontrib><creatorcontrib>Jana, Anukul</creatorcontrib><collection>Wiley Online Library (Open Access Collection)</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>Index Chemicus</collection><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mandal, Debdeep</au><au>Chandra, Shubhadeep</au><au>Neuman, Nicolás I.</au><au>Mahata, Alok</au><au>Sarkar, Arighna</au><au>Kundu, Abhinanda</au><au>Anga, Srinivas</au><au>Rawat, Hemant</au><au>Schulzke, Carola</au><au>Mote, Kaustubh R.</au><au>Sarkar, Biprajit</au><au>Chandrasekhar, Vadapalli</au><au>Jana, Anukul</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Activation of Aromatic C−F Bonds by a N‐Heterocyclic Olefin (NHO)</atitle><jtitle>Chemistry : a European journal</jtitle><stitle>CHEM-EUR J</stitle><addtitle>Chemistry</addtitle><date>2020-05-12</date><risdate>2020</risdate><volume>26</volume><issue>27</issue><spage>5951</spage><epage>5955</epage><pages>5951-5955</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>A N‐heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C−F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes in which the central carbon–carbon double bond is in a twisted geometry.
NHO activation: The activation of aromatic C−F bonds by N‐heterocyclic olefin (NHO) occurs without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes.</abstract><cop>WEINHEIM</cop><pub>Wiley</pub><pmid>32027063</pmid><doi>10.1002/chem.202000276</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-7530-539X</orcidid><orcidid>https://orcid.org/0000-0002-1657-1321</orcidid><orcidid>https://orcid.org/0000-0003-3368-0228</orcidid><orcidid>https://orcid.org/0000-0003-3692-0784</orcidid><orcidid>https://orcid.org/0000-0003-4887-7277</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Alkenes C-F activation Carbon Catalysts Chemistry Chemistry, Multidisciplinary Communication Communications fluorine N-heterocyclic olefins nucleophilic substitution Physical Sciences Science & Technology |
| title | Activation of Aromatic C−F Bonds by a N‐Heterocyclic Olefin (NHO) |
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