Supramolecular Additive-Initiated Controlled Atom Transfer Radical Polymerization of Zwitterionic Polymers on Ureido-pyrimidinone-Based Biomaterial Surfaces
Surface-initiated controlled radical polymerization is a popular technique for the modification of biomaterials with, for example, antifouling polymers. Here, we report on the functionalization of a supramolecular biomaterial with zwitterionic poly(sulfobetaine methacrylate) via atom transfer radica...
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| Veröffentlicht in: | Macromolecules 2020-06, Vol.53 (11), p.4454-4464 |
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| container_title | Macromolecules |
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| creator | Ippel, Bastiaan D. Komil, Muhabbat I. Bartels, Paul A. A. Söntjens, Serge H. M. Boonen, Roy J. E. A. Smulders, Maarten M. J. Dankers, Patricia Y. W. |
| description | Surface-initiated controlled
radical polymerization is a popular technique for the modification
of biomaterials with, for example, antifouling polymers. Here, we
report on the functionalization of a supramolecular biomaterial with
zwitterionic poly(sulfobetaine methacrylate) via atom transfer radical
polymerization from a macroinitiator additive, which is embedded in
the hard phase of the ureido-pyrimidinone-based material. Poly(sulfobetaine
methacrylate) was successfully polymerized from these surfaces, and
the polymerized sulfobetaine content, with corresponding antifouling
properties, depended on both the macroinitiator additive concentration
and polymerization time. Furthermore, the polymerization from the
macroinitiator additive was successfully translated to functional
electrospun scaffolds, showing the potential for this functionalization
strategy in supramolecular material systems. |
| doi_str_mv | 10.1021/acs.macromol.0c00160 |
| format | Article |
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radical polymerization is a popular technique for the modification
of biomaterials with, for example, antifouling polymers. Here, we
report on the functionalization of a supramolecular biomaterial with
zwitterionic poly(sulfobetaine methacrylate) via atom transfer radical
polymerization from a macroinitiator additive, which is embedded in
the hard phase of the ureido-pyrimidinone-based material. Poly(sulfobetaine
methacrylate) was successfully polymerized from these surfaces, and
the polymerized sulfobetaine content, with corresponding antifouling
properties, depended on both the macroinitiator additive concentration
and polymerization time. Furthermore, the polymerization from the
macroinitiator additive was successfully translated to functional
electrospun scaffolds, showing the potential for this functionalization
strategy in supramolecular material systems.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/acs.macromol.0c00160</identifier><identifier>PMID: 32581395</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Macromolecules, 2020-06, Vol.53 (11), p.4454-4464</ispartof><rights>Copyright © 2020 American Chemical Society 2020 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-49a0b23b4a824c9d6630c2a5fd6ea82393fd31a8325ae3f9e9f7661603abec8c3</citedby><cites>FETCH-LOGICAL-c385t-49a0b23b4a824c9d6630c2a5fd6ea82393fd31a8325ae3f9e9f7661603abec8c3</cites><orcidid>0000-0002-6855-0426 ; 0000-0002-8997-181X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,2765,27924,27925</link.rule.ids></links><search><creatorcontrib>Ippel, Bastiaan D.</creatorcontrib><creatorcontrib>Komil, Muhabbat I.</creatorcontrib><creatorcontrib>Bartels, Paul A. A.</creatorcontrib><creatorcontrib>Söntjens, Serge H. M.</creatorcontrib><creatorcontrib>Boonen, Roy J. E. A.</creatorcontrib><creatorcontrib>Smulders, Maarten M. J.</creatorcontrib><creatorcontrib>Dankers, Patricia Y. W.</creatorcontrib><title>Supramolecular Additive-Initiated Controlled Atom Transfer Radical Polymerization of Zwitterionic Polymers on Ureido-pyrimidinone-Based Biomaterial Surfaces</title><title>Macromolecules</title><description>Surface-initiated controlled
radical polymerization is a popular technique for the modification
of biomaterials with, for example, antifouling polymers. Here, we
report on the functionalization of a supramolecular biomaterial with
zwitterionic poly(sulfobetaine methacrylate) via atom transfer radical
polymerization from a macroinitiator additive, which is embedded in
the hard phase of the ureido-pyrimidinone-based material. Poly(sulfobetaine
methacrylate) was successfully polymerized from these surfaces, and
the polymerized sulfobetaine content, with corresponding antifouling
properties, depended on both the macroinitiator additive concentration
and polymerization time. Furthermore, the polymerization from the
macroinitiator additive was successfully translated to functional
electrospun scaffolds, showing the potential for this functionalization
strategy in supramolecular material systems.</description><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNpVkc9u1DAQxi0EotvCG3DIkUu2_hMn8QVpuypQqRKIthcu1qw9BiMnXmynaHkWHhZX3SJxGmu-z7_x-CPkDaNrRjk7B5PXE5gUpxjW1FDKevqMrJjktJWjkM_JilLetYqr4YSc5vyjWpjsxEtyIrgcmVByRf7cLPsEFYFmCZCajbW--Htsr-ZaoaBttnEuKYZQj5sSp-Y2wZwdpuYLWG8gNJ9jOEyY_G8oPs5NdM3XX76U2omzN09ybqp2l9Db2O4PyU_e-jnO2F5ArugLHyd4uFOBN0tyYDC_Ii8chIyvj_WM3L2_vN1-bK8_fbjabq5bI0ZZ2k4B3XGx62DknVG27wU1HKSzPdaWUMJZwWCsWwMKp1C5oe_rdwnYoRmNOCPvHrn7ZTehNVgXhqD39ZGQDjqC1_8rs_-uv8V7PQjaKT5UwNsjIMWfC-aiJ58NhgAzxiVr3rFBKMqlqtbu0VqTyzmh-zeGUf0QrK7B6qdg9TFY8Rc8M58T</recordid><startdate>20200609</startdate><enddate>20200609</enddate><creator>Ippel, Bastiaan D.</creator><creator>Komil, Muhabbat I.</creator><creator>Bartels, Paul A. A.</creator><creator>Söntjens, Serge H. M.</creator><creator>Boonen, Roy J. E. A.</creator><creator>Smulders, Maarten M. J.</creator><creator>Dankers, Patricia Y. W.</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-6855-0426</orcidid><orcidid>https://orcid.org/0000-0002-8997-181X</orcidid></search><sort><creationdate>20200609</creationdate><title>Supramolecular Additive-Initiated Controlled Atom Transfer Radical Polymerization of Zwitterionic Polymers on Ureido-pyrimidinone-Based Biomaterial Surfaces</title><author>Ippel, Bastiaan D. ; Komil, Muhabbat I. ; Bartels, Paul A. A. ; Söntjens, Serge H. M. ; Boonen, Roy J. E. A. ; Smulders, Maarten M. J. ; Dankers, Patricia Y. W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-49a0b23b4a824c9d6630c2a5fd6ea82393fd31a8325ae3f9e9f7661603abec8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ippel, Bastiaan D.</creatorcontrib><creatorcontrib>Komil, Muhabbat I.</creatorcontrib><creatorcontrib>Bartels, Paul A. A.</creatorcontrib><creatorcontrib>Söntjens, Serge H. M.</creatorcontrib><creatorcontrib>Boonen, Roy J. E. A.</creatorcontrib><creatorcontrib>Smulders, Maarten M. J.</creatorcontrib><creatorcontrib>Dankers, Patricia Y. W.</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ippel, Bastiaan D.</au><au>Komil, Muhabbat I.</au><au>Bartels, Paul A. A.</au><au>Söntjens, Serge H. M.</au><au>Boonen, Roy J. E. A.</au><au>Smulders, Maarten M. J.</au><au>Dankers, Patricia Y. W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular Additive-Initiated Controlled Atom Transfer Radical Polymerization of Zwitterionic Polymers on Ureido-pyrimidinone-Based Biomaterial Surfaces</atitle><jtitle>Macromolecules</jtitle><date>2020-06-09</date><risdate>2020</risdate><volume>53</volume><issue>11</issue><spage>4454</spage><epage>4464</epage><pages>4454-4464</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><abstract>Surface-initiated controlled
radical polymerization is a popular technique for the modification
of biomaterials with, for example, antifouling polymers. Here, we
report on the functionalization of a supramolecular biomaterial with
zwitterionic poly(sulfobetaine methacrylate) via atom transfer radical
polymerization from a macroinitiator additive, which is embedded in
the hard phase of the ureido-pyrimidinone-based material. Poly(sulfobetaine
methacrylate) was successfully polymerized from these surfaces, and
the polymerized sulfobetaine content, with corresponding antifouling
properties, depended on both the macroinitiator additive concentration
and polymerization time. Furthermore, the polymerization from the
macroinitiator additive was successfully translated to functional
electrospun scaffolds, showing the potential for this functionalization
strategy in supramolecular material systems.</abstract><pub>American Chemical Society</pub><pmid>32581395</pmid><doi>10.1021/acs.macromol.0c00160</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-6855-0426</orcidid><orcidid>https://orcid.org/0000-0002-8997-181X</orcidid><oa>free_for_read</oa></addata></record> |
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| title | Supramolecular Additive-Initiated Controlled Atom Transfer Radical Polymerization of Zwitterionic Polymers on Ureido-pyrimidinone-Based Biomaterial Surfaces |
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