Phase, Composition and Structure Changes of CoCrNi-Based Concentrated Alloys Resulting from High Temperature Oxidation

In this work, CoCrNi, FeCoCrNi and CoCrFeMnNi concentrated alloys with a Y-Ti oxide particle dispersion were prepared by mechanical alloying and Spark Plasma Sintering. The alloy consists of an FCC Ni-based matrix with a Y-Ti oxide dispersion and additional phases of Cr C and Cr O . The effect of Fe...

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Veröffentlicht in:Materials 2020-05, Vol.13 (10), p.2276
Hauptverfasser: Vilémová, Monika, Hadraba, Hynek, Weiss, Zdeněk, Lukáč, František, Csáki, Štefan, Chlup, Zdeněk, Matějíček, Jiří, Chráska, Tomáš
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container_end_page
container_issue 10
container_start_page 2276
container_title Materials
container_volume 13
creator Vilémová, Monika
Hadraba, Hynek
Weiss, Zdeněk
Lukáč, František
Csáki, Štefan
Chlup, Zdeněk
Matějíček, Jiří
Chráska, Tomáš
description In this work, CoCrNi, FeCoCrNi and CoCrFeMnNi concentrated alloys with a Y-Ti oxide particle dispersion were prepared by mechanical alloying and Spark Plasma Sintering. The alloy consists of an FCC Ni-based matrix with a Y-Ti oxide dispersion and additional phases of Cr C and Cr O . The effect of Fe, Mn, and Y-Ti oxide particles on the formation of oxide scales and the composition of the adjacent CoCrNi and FeCoCrNi alloys was studied. It was found that alloys without Mn in their composition form a protective Cr O scale. The Cr C particles provide an alternative mechanism for balancing the chromium loss during the oxidation. Y and Ti from the oxide particles participate in the formation of the protective oxide scales. Fe promotes Y and especially Ti diffusion through the Cr O scale, resulting in the formation of Ti-depleted regions in the alloy. The findings will serve for the further development of these new materials.
doi_str_mv 10.3390/ma13102276
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source Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central; Free Full-Text Journals in Chemistry
subjects Alloys
Calibration
Chromium oxides
Corrosion resistance
Entropy
Heat resistant alloys
High temperature
Iron
Manganese
Mechanical alloying
Oxidation
Plasma sintering
Scale (corrosion)
Spark plasma sintering
Titanium
title Phase, Composition and Structure Changes of CoCrNi-Based Concentrated Alloys Resulting from High Temperature Oxidation
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