How to Control the Rate of Heterogeneous Electron Transfer across the Rim of M6L12 and M12L24 Nanospheres

Catalysis in confined spaces, such as those provided by supramolecular cages, is quickly gaining momentum. It allows for second coordination sphere strategies to control the selectivity and activity of transition metal catalysts, beyond the classical methods like fine-tuning the steric and electroni...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-05, Vol.142 (19), p.8837-8847
Hauptverfasser:	Zaffaroni, Riccardo, Bobylev, Eduard O, Plessius, Raoul, van der Vlugt, Jarl Ivar, Reek, Joost N. H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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