Visible-Light-Driven Rotation of Molecular Motors in a Dual-Function Metal–Organic Framework Enabled by Energy Transfer

The visible-light-driven rotation of an overcrowded alkene-based molecular motor strut in a dual-function metal–organic framework (MOF) is reported. Two types of functional linkers, a palladium–porphyrin photosensitizer and a bispyridine-derived molecular motor, were used to construct the framework...

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Veröffentlicht in:Journal of the American Chemical Society 2020-05, Vol.142 (19), p.9048-9056
Hauptverfasser: Danowski, Wojciech, Castiglioni, Fabio, Sardjan, Andy S, Krause, Simon, Pfeifer, Lukas, Roke, Diederik, Comotti, Angiolina, Browne, Wesley R, Feringa, Ben L
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container_end_page 9056
container_issue 19
container_start_page 9048
container_title Journal of the American Chemical Society
container_volume 142
creator Danowski, Wojciech
Castiglioni, Fabio
Sardjan, Andy S
Krause, Simon
Pfeifer, Lukas
Roke, Diederik
Comotti, Angiolina
Browne, Wesley R
Feringa, Ben L
description The visible-light-driven rotation of an overcrowded alkene-based molecular motor strut in a dual-function metal–organic framework (MOF) is reported. Two types of functional linkers, a palladium–porphyrin photosensitizer and a bispyridine-derived molecular motor, were used to construct the framework capable of harvesting low-energy green light to power the rotary motion. The molecular motor was introduced in the framework using the postsynthetic solvent-assisted linker exchange (SALE) method, and the structure of the material was confirmed by powder (PXRD) and single-crystal X-ray (SC-XRD) diffraction. The large decrease in the phosphorescence lifetime and intensity of the porphyrin in the MOFs upon introduction of the molecular motor pillars confirms efficient triplet-to-triplet energy transfer between the porphyrin linkers and the molecular motor. Near-infrared Raman spectroscopy revealed that the visible light-driven rotation of the molecular motor proceeds in the solid state at rates similar to those observed in solution.
doi_str_mv 10.1021/jacs.0c03063
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title Visible-Light-Driven Rotation of Molecular Motors in a Dual-Function Metal–Organic Framework Enabled by Energy Transfer
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