Diamond-Graphene Composite Nanostructures

The search for new nanostructural topologies composed of elemental carbon is driven by technological opportunities as well as the need to understand the structure and evolution of carbon materials formed by planetary shock impact events and in laboratory syntheses. We describe two new families of di...

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Veröffentlicht in:	Nano letters 2020-05, Vol.20 (5), p.3611-3619
Hauptverfasser:	Németh, Péter, McColl, Kit, Smith, Rachael L, Murri, Mara, Garvie, Laurence A. J, Alvaro, Matteo, Pécz, Béla, Jones, Adrian P, Corà, Furio, Salzmann, Christoph G, McMillan, Paul F
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creator	Németh, Péter McColl, Kit Smith, Rachael L Murri, Mara Garvie, Laurence A. J Alvaro, Matteo Pécz, Béla Jones, Adrian P Corà, Furio Salzmann, Christoph G McMillan, Paul F
description	The search for new nanostructural topologies composed of elemental carbon is driven by technological opportunities as well as the need to understand the structure and evolution of carbon materials formed by planetary shock impact events and in laboratory syntheses. We describe two new families of diamond-graphene (diaphite) phases constructed from layered and bonded sp3 and sp2 nanostructural units and provide a framework for classifying the members of this new class of materials. The nanocomposite structures are identified within both natural impact diamonds and laboratory-shocked samples and possess diffraction features that have previously been assigned to lonsdaleite and postgraphite phases. The diaphite nanocomposites represent a new class of high-performance carbon materials that are predicted to combine the superhard qualities of diamond with high fracture toughness and ductility enabled by the graphitic units and the atomically defined interfaces between the sp3- and sp2-bonded nanodomains.
doi_str_mv	10.1021/acs.nanolett.0c00556
format	Article
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title	Diamond-Graphene Composite Nanostructures
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