Relay Cross Metathesis for the Iterative Construction of Terpenoids and Synthesis of a Diterpene-Benzoate Macrolide of Biogenetic Relevance to the Bromophycolides

We report a relay cross metathesis (ReXM) reaction for the construction of terpenoids in an iterative protocol. The protocol features the cross metathesis of a relay-actuated Δ6,7-functionalized C10-monoterpenoid alcohol with C10-monoterpenoid citral to form a C15-sesquiterpene. Subsequent functiona...

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Veröffentlicht in:	Organic letters 2020-04, Vol.22 (8), p.3176-3179
Hauptverfasser:	Bahou, Karim A, Braddock, D. Christopher, Meyer, Adam G, Savage, G. Paul
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols chemical reactions citral Letter macrolides moieties
Online-Zugang:	Volltext
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